journal article·2023-01

Effect of nanoparticles in dilute and semi-dilute polymer solutions

Mojammel H. Mondal

Journal of Nanoparticle Research· Volume 25· Issue 1
Publisher page

Abstract

Polymer solutions of different concentrations along with their temperature dependence in the presence of nanoparticles have been investigated by dynamic light scattering (DLS) technique. Results show the presence of nanoparticle changes the polymer solutions. Both the dilute and semi-dilute polymer solutions have become nearly identical in the presence of nanoparticles at different temperatures, indicating the fact that the behavior of dilute solution at one temperature is nearly identical to the semi-dilute solution at other temperatures in the presence of nanoparticles. This uniqueness of polymer solutions irrespective of their concentrations upon nanoparticle deposition in turn results from the similar relaxation times at different temperatures. This result is obtained from an overlap region having the same relaxation time, where lower temperature correlation data of dilute composite solution overlap with higher temperature correlation data of semi-dilute composite solution. Also, analysis shows that both the composite solutions above and below the room temperature are more homogeneous, keeping their similar trend at other different temperatures.
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Research context

OpenAlex topics: Material Dynamics and Properties · Surfactants and Colloidal Systems · Electrostatics and Colloid Interactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (42)

Show source-provided references
1. Brown W (1993) in Dynamic light scattering: the method and some applications, ed. W.Brown, Oxford Science Publications, Oxford, pp. 26710.1093/oso/9780198539421.001.0001 ↗
2. Brown W (1996) in Light scattering: principles and development, ed. W.Brown, Oxford Science Publications, Oxford, ch. 8, pp. 255
3. Shibayama M, Suda J, Karino T, Okabe S, Takehisa T, Haraguchi K (2004) Structure and dynamics of poly(N-isopropylacrylamide) clay nanocomposite gels. Macromolecules 37:9606–961210.1021/ma048464v ↗
4. Volden S, Kjniksen AL, Zhu K, Genzer J, Nystrm B, Glomm WR (2010) Temperature-dependent optical properties of gold nanoparticles coated with a charged diblock copolymer and an uncharged triblock copolymer. ACS Nano 4:1187–120110.1021/nn901517u ↗
5. Liang M, Lin IC, Whittaker MR, Minchin RF, Monteiro MJ, Toth I (2010) Cellular uptake of densely packed polymer coatings on gold nanoparticles. ACS Nano 4:403–41310.1021/nn9011237 ↗
6. Wu C, Niu A, Leung LM, Lam TS (1999) Preparation of narrowly distributed stable and soluble polyacetylene block copolymer nanoparticles. J Am Chem Soc 121:1954–195510.1021/ja983587e ↗
7. Kropka JM, Putz KW, Pryamitsyn V, Ganesan V, Green PF (2007) Origin of dynamical properties in PMMA C60 nanocomposites. Macromolecules 40:5424–543210.1021/ma070407p ↗
8. Dong H, Zhu M, Yoon JA, Gao H, Jin R, Matyjaszewski K (2008) One-pot synthesis of robust core/shell gold nanoparticles. J Am Chem Soc 130:12852–1285310.1021/ja8038097 ↗
9. Jordan J, Jacob KI, Tannenbaum R, Sharaf MA, Jasiuk I (2005) Experimental trends in polymer nanocomposites -a review. Mater Sci Eng A 393:1–1110.1016/j.msea.2004.09.044 ↗
10. Lim J, Yeap SP, XinChe H, Low SC (2013) Characterization of magnetic nanoparticle by dynamic light scattering. Nanoscale Res Lett 8:38110.1186/1556-276X-8-381 ↗
11. Xie R, Batchelor-McAuley C, Young N, Compton RG (2019) Electrochemical impacts complement light scattering techniques for in situ nanoparticle sizing. Nanoscale 11:1720–172710.1039/C8NR09172B ↗
12. Athavale R, Sapre N, Rale V, Manna G, Kulkarni A, Shirolkar MM (2022) Tuning the surface charge properties of chitosan nanoparticle. Mater Lett 308:13111410.1016/j.matlet.2021.131114 ↗
13. Mondal MH (2017) Study of autocorrelation function of polymer and polymer nanocomposite solutions using dynamic light scattering method. J Polym Res 24:21810.1007/s10965-017-1368-3 ↗
14. Mondal MH (2018) Study of in-situ structural and chemical changes of ultrathin polymer films. Appl Phys A 124:86410.1007/s00339-018-2285-y ↗
15. Pan C, Maurer W, Lu Z, Lodge TP, Stepanek P, von Meerwal ED, Watanabe H (1995) Dynamic light scattering from dilute, semidilute, and concentrated block copolymer solutions. Macromolecules 28:1643–165310.1021/ma00109a042 ↗
16. Jian T, Anastasiadis SH, Semenov AN, Fytas G, Adachi K, Kotaka T (1994) Dynamics of composition fluctuations in diblock copolymer solutions far from and near to the ordering transition. Macromolecules 27:4762–477310.1021/ma00095a017 ↗
17. Stepanek P, Tuzar Z, Kadlec P, Kriz J (2007) A dynamic light scattering study of fast relaxations in polymer solutions. Macromolecules 40:2165–217110.1021/ma0620518 ↗
18. Borsali R, Giebel L, Fischer EW, Meier G (1991) Dynamic light scattering from ternary mixtures of two homopolymers in solution. J Non-Cryst Solids 131:816–82210.1016/0022-3093(91)90687-2 ↗
19. Berne BJ and Pecora R (2000) in Dynamic light scattering, Dover Publications, New York, ch. 8, pp. 194
20. Stepanek P, Brown W (1998) Multiple relaxations of concentration fluctuations in entangled polymer solutions. Macromolecules 31:1889–189710.1021/ma970458u ↗
21. Adam M, Delsanti M (1985) Dynamical behavior of semidilute polymer solutions in a.THETA. solvent: quasi-elastic light scattering experiments. Macromolecules 18:1760–177010.1021/ma00151a020 ↗
22. Brown W (1996) In Light scattering: principles and development, Brown, W., Ed.; Oxford Science Publications: Oxford, ch. 11, pp. 352
23. Stepanek P, Lodge TP (1996) Dynamic light scattering from block copolymer melts near the order disorder transition. Macromolecules 29:1244–125110.1021/ma9509772 ↗
24. Semenov AN (1990) Dynamical correlation function of polymer density fluctuations in concentrated solutions. Physica A 166:263–28710.1016/0378-4371(90)90016-L ↗
25. Boudenne N, Anastasiadis SH, Fytas G, Xenidou M, Hadjichristidis N, Semenov AN, Fleischer G (1996) Thermodynamic effects on internal relaxation in diblock copolymers. Phys Rev Lett 77:506–50910.1103/PhysRevLett.77.506 ↗
26. Floudas G, Stepanek P (1998) Structure and dynamics of poly(n-decyl methacrylate) below and above the glass transition. Macromolecules 31:6951–695710.1021/ma9804601 ↗
27. Floudas G, Placke P, Stepanek P, Brown W, Fytas G, Ngai K (1995) Dynamics of the “strong” polymer of n-lauryl methacrylate below and above the glass transition. Macromolecules 28:6799–680710.1021/ma00124a015 ↗
28. Berne BJ, Pecora R (1976) in Dynamic light scattering. Wiley, New York
29. Chu B (1991) Laser light scattering, 2nd edn. Academic Press, New York
30. Kohlrausch R (1847) Ueber dus Dellrnannsche Elektrometer. Pogg Ann Phys Chem 72:35310.1002/andp.18471481102 ↗
31. Williams G, Watts DC (1970) Non-symmetrical dielectric relaxation behaviour arising from a simple empirical decay function. Trans Faraday Soc 66:80–8510.1039/tf9706600080 ↗
32. Ngai T, Chi W (2003) Effect of cross-linking on dynamics of semidilute copolymer solutions: poly(methyl methacrylate-co-7-acryloyloxy-4-methylcoumarin) in chloroform. Macromolecules 36:848–85410.1021/ma021580i ↗
33. Ngai T, Chi W, Chen Y (2004) Effects of temperature and swelling on chain dynamics during the sol gel transition. Macromolecules 37:987–99310.1021/ma030421b ↗
34. Chen H, Ye X, Zhang G, Zhang Q (2006) Dynamics of thermoresponsive PNIPAM-g-PEO copolymer chains in semi-dilute solution. Polymer 47:8367–837310.1016/j.polymer.2006.09.062 ↗
35. Shibayama M, Norisuye T (2002) Gel formation analyses by dynamic light scattering. Bull Chem Soc Jpn 75:641–65910.1246/bcsj.75.641 ↗
36. Adam M, Delsanti M, Munch JP, Durand D (1988) Dynamical studies of polymeric cluster solutions obtained near the gelation threshold: glasslike behavior. Phys Rev Lett 61:706–70910.1103/PhysRevLett.61.706 ↗
37. Martin JE, Wilcoxon J (1988) Critical dynamics of the sol-gel transition. Phys Rev Lett 61:373–37610.1103/PhysRevLett.61.373 ↗
38. Martin JE, Wilcoxon J, Odinek J (1991) Decay of density fluctuations in gels. Phys Rev A 43:858–87210.1103/PhysRevA.43.858 ↗
39. Adam M, Delsanti M (1977) Dynamical properties of polymer solutions in good solvent by Rayleigh scattering experiments. Macromolecules 10:1229–123710.1021/ma60060a014 ↗
40. Doi M and Edwards SF (1986) In The theory of polymer dynamics, Clarendon Press, Oxford, ch. 3, pp. 49
41. Nicolai T, Brown W, Johnsen RM, Stepanek P (1990) Dynamic behavior of .THETA. solutions of polystyrene investigated by dynamic light scattering. Macromolecules 23:1165–117410.1021/ma00206a040 ↗
42. Phillips JC (1996) Stretched exponential relaxation in molecular and electronic glasses. Rep Prog Phys 59:1133–120710.1088/0034-4885/59/9/003 ↗