journal article·2008-02

Bar-shaped nanoparticles of iron(II) hydroxide

Andrei A. Zagorodni, German Salazar-Alvarez, Mamoun Muhammed

Journal of Nanoparticle Research· Volume 10· Issue 2
Publisher page

Abstract

Formation of elongated nanoparticles was observed when (hbox{Fe}3hbox{O}4) was precipitated from solutions containing excess of Fe2+. The average diameter of the particles was 23 nm; the length to diameter ratio was up to 14. This shape was an unexpected phenomenon because bar- or needle-like nanoparticles have been earlier reported only for Fe(III)-based materials. Chemical analysis revealed Fe(OH)2 nature of the obtained particles. In addition, this conclusion was verified with a new simple method for quantitative evaluation of the particle morphology. Application of this method to the mixed (hbox{Fe(OH)}2/hbox{Fe}3hbox{O}4) samples allowed to distinguish between the two different compounds and to attribute different morphologies to Fe(OH)2 or (hbox{Fe}3hbox{O}4.) Results indicate that bars are frequent shapes of nano-sized iron oxides/hydroxides.
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Research context

OpenAlex topics: Iron oxide chemistry and applications · Minerals Flotation and Separation Techniques · Magnetic Properties and Synthesis of Ferrites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (13)

Show source-provided references
1. Bate G (1981) The present and future of magnetic recording media. In: Proceedings of 3rd international conference on ferrites (Kyoto, Japan, Sept–Oct 1980). Watanabe H, Iida S, Sugimoto M (eds) Center for Academic Publications, Tokyo, p 509
2. Campbell JS, Craven P, Young PW (1970) Removal of carbon monoxide. In: Twygg MV (ed) Catalyst handbook. Wolfe Scientific Books, London, p 97
3. Cornell RM, Schwertmann U (2003) The iron oxides: structure, properties, reactions, occurrences and uses. Wiley-VCH, Weinheim10.1002/3527602097 ↗
4. Diamandescu L, Mihaila-Tarabasanu D, Popescu-Pogrion N, Totovina A, Bibicu I (1999) Hydrothermal synthesis and characterization of some polycrystalline alpha-iron oxides. Ceram Int 25:68910.1016/S0272-8842(99)00002-4 ↗
5. Hafeli U, Schutt W, Teller J, Zborowski M (1997) Scientific and clinical applications of magnetic carriers. Plenum Press, New York10.1007/978-1-4757-6482-6 ↗
6. Javadi HS (1995) Microwave materials. In: Koryu T (ed) Handbook of microwave technology. vol 2 Applications. Academic Press, San Diego, p 60510.1016/B978-012374695-5/50038-9 ↗
7. Kim DK, Mikhaylova M, Zhang Y, Muhammed M (2003a) Protective coating of superparamagnetic iron oxide nanoparticles. Chem Mater 15:161710.1021/cm021349j ↗
8. Kim DK, Mikhaylova M, Wang FH, Kehr J, Bjelke B, Zhang Y, Tsakalakos T, Muhammed M (2003b) Starch-coated superparamagnetic nanoparticles as MR contrast agents. Chem Mater 15:434310.1021/cm031104m ↗
9. Raj K, Moskowitz RJ (1990) Commercial applications of ferrofluids. Magn Magn Mater 85:23310.1016/0304-8853(90)90058-X ↗
10. Salazar-Alvarez G, Muhammed M, Zagorodni AA (2006) Novel flowinjection synthesis of iron oxide nanoparticles with narrowsize distribution. Chem Eng Sci 61:462510.1016/j.ces.2006.02.032 ↗
11. Salazar-Alvarez G, Muhammed M (2007) Synthesis of highly crystalline iron oxide nanoparticles and its controlled silica coating. Manuscript in preparation
12. Tillotson TM, Gash AE, Simpson RL, Hrubesh LW, Satcher JH Jr, Poco JFJ (2001) Nanostructured energetic materials using sol–gel methodologies. Non-Cryst Solids 285:33810.1016/S0022-3093(01)00477-X ↗
13. Zhou Z, Wang J, Liu X, Chan HJ (2001) Synthesis of Fe3O4 nanoparticles from emulsions. J Mater Chem 11:170410.1039/b100758k ↗