journal article·2016-10

Preparation of ordered silver angular nanoparticles array in block copolymer film for surface-enhanced Raman spectroscopy

J. Svanda, M. V. Gromov, Y. Kalachyova, P. S. Postnikov, V. Svorcik, O. Lyutakov

Journal of Nanoparticle Research· Volume 18· Issue 10
Publisher page

Abstract

We report a single-step method of preparation of ordered silver nanoparticles array through template-assisted nanoparticles synthesis in the semidried block copolymer film. Ordered nanoparticles were prepared on different substrates by the proper choice of solvents combination and preparation procedure. In particular, block copolymer and silver nitrate were dissolved in the mix of tetrahydrofuran, toluene, and n-methylpyrolidone. During short spin-coating procedure ordering of block copolymer, evaporation of toluene and preferential silver redistribution into poly(4-vinylpyridine) block occurred. Rapid heating of semidry film initiated silver reduction, removing of residual solvent and creation of ordered silver array. After polymer removing silver nanoparticles array was tested as a suitable candidate for subdiffraction plasmonic application–surface-enhanced Raman scattering. Enhancement factor was calculated and compared with the literature data.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Gold and Silver Nanoparticles Synthesis and Applications · Block Copolymer Self-Assembly · Nanoparticle-Based Drug Delivery

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (28)

Show source-provided references
1. Acharya H, Sung J, Sohn BH, Kim DH, Tamada K, Park C (2009) Tunable surface plasmon band of position selective ag and au nanoparticles in thin block copolymer micelle films. Chem Mater 21:4248–4255. doi: 10.1021/cm901245g10.1021/cm901245g ↗
2. Aizawa M, Buriak JM (2007) Block copolymer templated chemistry for the formation of metallic nanoparticle arrays on semiconductor surfaces. Chem Mater 19:5090–5101. doi: 10.1021/cm071382b10.1021/cm071382b ↗
3. Chen CM, Liu CM, Wie KH, Jeng US, Su CH (2012) Non-volatile organic field-effect transistor memory comprising sequestered metal nanoparticles in a diblock copolymer film. J Mater Chem 22:454–461. doi: 10.1039/c1jm13936c10.1039/c1jm13936c ↗
4. Chen CM, Huang YJ, Wie KH (2014) Structural development of gold and silver nanoparticles within hexagonally ordered spherical micellar diblock copolymer thin films. Nanoscale 6:5999–6008. doi: 10.1039/c4nr00020j10.1039/c4nr00020j ↗
5. Etxeberria H, Fernandez R, Zalakain I, Mondragon I, Eceiza A, Kortaberria G (2014) Effect of CdSe nanoparticle addition on nanostructuring of PS-b-P4VP copolymer via solvent vapor exposure. J Colloid Interface Sci 416:25–29. doi: 10.1016/j.jcis.2013.10.02910.1016/j.jcis.2013.10.029 ↗
6. Horechyy A, Nandan B, Zafeiropoulos NE, Jehnichen D, Göbel M, Stamm M, Pospiech D (2014) Nanoparticle directed domain orientation in thin films of asymmetric block copolymers. Colloid Polym Sci 292:2249–2260. doi: 10.1007/s00396-014-3251-710.1007/s00396-014-3251-7 ↗
7. Jang YH, Kochuveedu ST, Jang YJ, Shin HY, Yoon S, Steinhart M, Kim DH (2011) The fabrication of graphitic thin films with highly dispersed noble metal nanoparticles by direct carbonization of block copolymer inverse micelle templates. Carbon 49:2120–2126. doi: 10.1016/j.carbon.2011.01.04910.1016/j.carbon.2011.01.049 ↗
8. Jeon SH, Xu P, Mack NH, Chiang LY, Brown L, Wang HL (2010) Understanding and controlled growth of silver nanoparticles using oxidized n-methyl-pyrrolidone as a reducing agent. J Phys Chem C 114:36–40. doi: 10.1021/jp907757u10.1021/jp907757u ↗
9. Kalachyova Y, Mares D, Lyutakov O, Kostejn M, Lapcak L, Svorcik V (2015) Surface plasmon polaritons on silver gratings for optimal SERS response. J Phys Chem C 119:9506–9512. doi: 10.1021/acs.jpcc.5b0179310.1021/acs.jpcc.5b01793 ↗
10. Kalachyova Y, Mares D, Jerabek V, Zaruba K, Ulbrich P, Lapcak L, Svorcik V, Lyutakov O (2016) The effect of silver grating and nanoparticles grafting for LSP–SPP coupling and SERS response intensification. J Phys Chem C 120:10569–10577. doi: 10.1021/acs.jpcc.6b0158710.1021/acs.jpcc.6b01587 ↗
11. Kneipp K, Moskovits M, Kneipp H (2006) Surface-enhanced Raman scattering. Springer, Heidelberg10.1007/3-540-33567-6 ↗
12. Lee W, Lee SY, Zhang X, Rabin O, Briber RM (2013) Hexagonally ordered nanoparticles templated using a block copolymer film through Coulombic interactions. Nanotechnology 24:045305. doi: 10.1088/0957-4484/24/4/04530510.1088/0957-4484/24/4/045305 ↗
13. Li CP, Wu CH, Wei KH, Sheu JT, Huang JY, Jeng US, Liang KS (2007) The effect of nanoscale confinement on the collective electron transport behavior in an nanoparticles self-assembled in a nanostructured polystyrene-block-poly(4-vinylpyridine) diblock copolymer ultra-thin film. Adv Funct Mater 17:2283–2290. doi: 10.1002/adfm.20060063710.1002/adfm.200600637 ↗
14. Lu J, Chamberlin D, Rider DA, Liu M, Manners I, Russell TP (2006) Using a ferrocenylsilane-based block copolymer as a template to produce nanotextured Ag surfaces: uniformly enhanced surface enhanced Raman scattering active substrates. Nanotechnology 17:5792–5797. doi: 10.1088/0957-4484/17/23/01410.1088/0957-4484/17/23/014 ↗
15. Lyutakov O, Hejna O, Solovyev A, Kalachyova Y, Svorcik V (2014) Polymethylmethacrylate doped with porphyrin and silver nanoparticles as light-activated antimicrobial material. RSC Adv 4:50624–50630. doi: 10.1039/c4ra08385g10.1039/c4ra08385g ↗
16. Lyutakov O, Kalachyova Y, Solovyev A, Vytykacova S, Svanda J, Siegel J, Ulbrich P, Svorcik V (2015) J Nanopart Res 17:120–131. doi: 10.1007/s11051-015-2935-310.1007/s11051-015-2935-3 ↗
17. Menezes WG, Zielasek V, Dzhardimalieva GI, Pomogailo SI, Thiel K, Wohrle D, Hartwig A, Baumer M (2012) Synthesis of stable AuAg bimetallic nanoparticles encapsulated by diblock copolymer micelles. Nanoscale 4:1658–1664. doi: 10.1039/c2nr11082b10.1039/c2nr11082b ↗
18. Menezes WG, Zielasek V, Thiel K, Hartwig A, Bäumer M (2013) Effects of particle size, composition, and support on catalytic activity of AuAg nanoparticles prepared in reverse block copolymer micelles as nanoreactors. J Catal 299:222–231. doi: 10.1016/j.jcat.2012.12.00610.1016/j.jcat.2012.12.006 ↗
19. Mistark PA, Park S, Yalcin SE, Lee DH, Yavuzcetin O, Tuominen MT, Russel TP, Achermann M (2009) Block-copolymer-based plasmonic nanostructures. ACS Nano 3:3987–3992. doi: 10.1021/nn901245w10.1021/nn901245w ↗
20. Noro A, Higuchi K, Sageshima Y, Matsushita Y (2012) Preparation and morphology of hybrids composed of a block copolymer and semiconductor nanoparticles via hydrogen bonding. Macromolecules 45:8013–8020. doi: 10.1021/ma301665e10.1021/ma301665e ↗
21. Osinkina L, Lohmuller T, Jackel F, Feldmann J (2013) Synthesis of gold nanostar arrays as reliable, large-scale, homogeneous substrates for surface-enhanced Raman scattering imaging and spectroscopy. J Phys Chem C 117:22198–22202. doi: 10.1021/jp312149d10.1021/jp312149d ↗
22. Shin DO, Lee DH, Moon HS, Jeong SJ, Kim JY, Mun JH, Cho H, Park S, Kim SO (2011) Sub-nanometer level size tuning of a monodisperse nanoparticle array via block copolymer lithography. Adv Funct Mater 21:250–254. doi: 10.1002/adfm.20100139610.1002/adfm.201001396 ↗
23. Song L, Lam YM (2007) Nanopattern formation using a chemically modified PS-P4VP diblock copolymer. Nanotechnology 18:075304. doi: 10.1088/0957-4484/18/7/07530410.1088/0957-4484/18/7/075304 ↗
24. Song L, Lam YM, Boothroyd C, Teo PW (2007) One-step synthesis of titania nanoparticles from PS-P4VP diblock copolymer solution. Nanotechnology 18:135605. doi: 10.1088/0957-4484/18/13/13560510.1088/0957-4484/18/13/135605 ↗
25. Song JB, Duan B, Wang CX, Zhou JJ, Pu L, Fang Z, Wang P, Lim TT, Duan HW (2014) SERS-encoded nanogapped plasmonic nanoparticles: growth of metallic nanoshell by templating redox-active polymer brushes. J Am Chem Soc 136:6838–6841. doi: 10.1021/ja502024d10.1021/ja502024d ↗
26. Svanda J, Lyutakov O, Vosmanska V, Svorcik V (2015) Combination of temperature and saturated vapor annealing for phase separation of block copolymer. J Appl Polym Sci 132:41853–41861. doi: 10.1002/app.4185310.1002/app.41853 ↗
27. Svanda J, Kalachyova Y, Slepicka P, Svorcik V, Lyutakov O (2016) Smart component for switching of plasmon resonance by external electric field. ACS Appl Mater Interfaces 8:225–231. doi: 10.1021/acsami.5b0833410.1021/acsami.5b08334 ↗
28. Yang J, Zhang J (2011) Subwavelength quarter-waveplate composed of L-shaped metal nanoparticles. Plasmonics 6:251–254. doi: 10.1007/s11468-010-9196-x10.1007/s11468-010-9196-x ↗