Controlled synthesis of Y2O3 nanoplates with improved performance
Source abstract
Abstract
Y2O3 nanoplates composed of nanoparticles with both low-energy and high-energy facets exposed have been synthesized via a facile hydrothermal approach and subsequent calcination treatment. The pH value of the reaction solution was observed to play a key role for the formation and even the size- and thickness-control of the nanoplate-like precursor. On calcination at 900 °C for 4 h, the precursors were decomposed into Y2O3 with well-maintained flake-like morphology. These Y2O3 nanoplates showed obviously improved catalytic CO oxidation activities than commercial and synthesized nanorod Y2O3. Under the UV excitation, flake-like Y2O3:Eu3+ phosphors exhibit strong red photoluminescence emissions, and nanoplates with the reaction temperature of 180 °C, reaction time of 36 h, as well as pH value of 7.4 showed the strongest photoluminescence intensity. This precursor-induced path provided not only a meaningful reference for dimension and size controlled synthesis, but also a potential way to achieve high-active facet exposed materials.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Luminescence Properties of Advanced Materials · Catalytic Processes in Materials Science · Advanced Photocatalysis Techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (32)
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1. Alahrache L, Deschamps M, Lambert J et al (2011) Crystallization of Y2O3–Al2O3 rich glasses: synthesis of YAG glass–ceramics. J Phys Chem C 115:20499–2050610.1021/jp207516w ↗
2. Atabave T, Jin O, Lee J et al (2012) Facile synthesis of bifunctional silica-coated core–shell Y2O3:Eu3+, Co2+ composite particles for biomedical applications. RSC Adv 2:9495–950110.1039/c2ra21332j ↗
3. Bai X, Song H, Yu L et al (2005) Luminescent properties of pure cubic phase Y2O3/Eu3+ nanotubes/nanowires prepared by a hydrothermal method. J Phys Chem B 109:15236–1524210.1021/jp050652f ↗
4. Capobianco J, Vetrone F, Boyer J (2002) Enhancement of red emission (4F9/2–4I15/2) via upconversion in bulk and nanocrystalline cubic Y2O3:Er3+. J Phys Chem B 106:1181–118710.1021/jp0129582 ↗
5. Costa L, Silva A, Borges L et al (2008) Partial oxidation of ethanol over Pd/CeO2 and Pd/Y2O3 catalysts. Catal Today 138:147–15110.1016/j.cattod.2008.05.003 ↗
6. Devaraju M, Yin S, Sato T (2011) Eu3+: Y2O3 microspheres and microcubes: a supercritical synthesis and characterization. Inorg Chem 50:4698–470410.1021/ic101496b ↗
7. Fang Y, Xu A, You L et al (2003) Hydrothermal synthesis of rare earth (Tb, Y) hydroxide and oxide nanotubes. Adv Funct Mater 13:955–96010.1002/adfm.200304470 ↗
8. Fu L, Liu Z, Liu Y, Han B (2004) Coating carbon nanotubes with rare earth oxide multiwalled nanotubes. Adv Mater 16:350–35210.1002/adma.200306213 ↗
9. Glaspell G, Anderson J, Wilkins J, El-Shall M (2008) Vapor phase synthesis of upconverting Y2O3 nanocrystals doped with Yb3+, Er3+, Ho3+, and Tm3+ to generate red, green, blue, and white light. J Phys Chem C 112:11527–1153110.1021/jp801597u ↗
10. Guzman J, Carrettin S, Fierro-Gonzalez J et al (2005) CO oxidation catalyzed by supported gold: cooperation between gold and nanocrystalline rare-earth supports forms reactive surface superoxide and peroxide species. Angew Chem Int Ed 44:4778–478110.1002/anie.200500659 ↗
11. Hu J, Odom T, Lieber C (1999) Chemistry and physics in one dimension: synthesis and properties of nanowires and nanotubes. Acc Chem Res 32:435–44510.1021/ar9700365 ↗
12. Jia G, Yang M, Song Y et al (2009) General and facile method to prepare uniform Y2O3:Eu hollow microspheres. Cryst Growth Des 9:301–30710.1021/cg8004823 ↗
13. Li X, Li Q, Xia Z et al (2006) Growth and characterization of single-crystal Y2O3:Eu nanobelts prepared with a simple technique. Cryst Growth Des 6:2193–219610.1021/cg0600400 ↗
14. Li L, Tsung C, Yang Z et al (2008) Rare-earth-doped nanocrystalline titania microspheres emitting luminescence via energy transfer. Adv Mater 20:903–90810.1002/adma.200701507 ↗
15. Li N, Yanagisawa K, Kumada N (2009a) Facile hydrothermal synthesis of yttrium hydroxide nanowires. Cryst Growth Des 9:978–98110.1021/cg8007798 ↗
16. Li P, Peng Q, Li Y (2009b) Dual-mode luminescent colloidal spheres from monodisperse rare-earth fluoride nanocrystals. Adv Mater 21:1945–194810.1002/adma.200803228 ↗
17. Mamontov E, Egami T (2000) Lattice defects and oxygen storage capacity of nanocrystalline ceria and ceria–zirconia. J Phys Chem B 104:11110–1111610.1021/jp0023011 ↗
18. Mao Y, Huang J, Ostroumov R, Wang K et al (2008) Synthesis and luminescence properties of erbium-doped Y2O3 nanotubes. J Phys Chem C 112:2278–228510.1021/jp0773738 ↗
19. Schubert M, Hackenberg S, Veen A et al (2001) CO oxidation over supported gold catalysts—“inert” and “active” support materials and their role for the oxygen supply during reaction. J Catal 197:113–12210.1006/jcat.2000.3069 ↗
20. Silver J, Martinez-Rubio M, Ireland T et al (2001) The effect of particle morphology and crystallite size on the upconversion luminescence properties of erbium and ytterbium co-doped yttrium oxide phosphors. J Phys Chem B 105:948–95310.1021/jp002778c ↗
21. Sotiriou G, Schneider M, Pratsinis S (2012) Green, silica-coated monoclinic Y2O3:Tb3+ nanophosphors: flame synthesis and characterization. J Phys Chem C 116:4493–449910.1021/jp211722z ↗
22. Sugimoto T (1987) Preparation of monodispersed colloidal particles. Adv Colloid Interface Sci 28:65–10810.1016/0001-8686(87)80009-X ↗
23. Wang Z (2000) Transmission electron microscopy of shape-controlled nanocrystals and their assemblies. J Phys Chem B 104:1153–117510.1021/jp993593c ↗
24. Wang X, Li Y (2002) Synthesis and characterization of lanthanide hydroxide single-crystal nanowires. Angew Chem Int Ed 41:4790–479310.1002/anie.200290049 ↗
25. Wang J, Tanner P (2010) Upconversion for white light generation by a single compound. J Am Chem Soc 132:947–94910.1021/ja909254u ↗
26. Wang H, Uehara M, Nakamura H et al (2005) Synthesis of well-dispersed Y2O3:Eu nanocrystals and self-assembled nanodisks using a simple non-hydrolytic route. Adv Mater 17:2506–250910.1002/adma.200500503 ↗
27. Wu H, Xu H, Su Q et al (2003) Size- and shape-tailored hydrothermal synthesis of YVO4 crystals inultra-wide pH range conditions. J Mater Chem 13:1223–122810.1039/b210713a ↗
28. Yan XC, Yu RB et al (2011) Facile solvothermal synthesis of gear-shaped submicrostructured Y2O3:Eu3+ phosphor. Solid State Sci 13(2011):1060–106410.1016/j.solidstatesciences.2011.01.019 ↗
29. Yang J, Quan Z, Kong D et al (2007) Y2O3:Eu3+ microspheres: solvothermal synthesis and luminescence properties. Cryst Growth Des 7:730–73510.1021/cg060717j ↗
30. Zahir M, Suzuki T, Fujishiro Y et al (2009) Synthesis and characterization of Sm3+-doped Y(OH)3 and Y2O3 nanowires and their NO reduction activity. J Alloys Compd 476:335–34010.1016/j.jallcom.2008.08.047 ↗
31. Zhang N, Liu X, Yi R (2008) Selective and controlled synthesis of single-crystalline yttrium hydroxide/oxide. nanosheets and nanotubes. J Phys Chem C 112:17788–1779510.1021/jp803831g ↗
32. Zhao Q, You H et al (2013) Dendritic Y4O(OH)9NO3:Eu3+/Y2O3:Eu3+ hierarchical structures: controlled synthesis, growth mechanism, and luminescence properties. CrystEngComm 15:4844–485110.1039/c3ce40460a ↗