Effect of monobutylether ethylene glycol on Mg/Al layered double hydroxide: a physicochemical and conductivity study
Source abstract
Abstract
Mg–Al hydrotalcite-like compounds with OH− ions intercalated in the gallery and modified with monobutylether ethylene glycol (mbeeg) were prepared from Mg6Al2(CO3)(OH)16·4H2O by the reconstruction method. The effect of the ethylene glycol, a moderate surfactant, on the textural properties and on the vapor water sorption of the layered double hydroxides was investigated by transmission electron microscopy and nitrogen and water sorption techniques. The ion conductivity of the samples was measured at 98 % RH up to 180 °C. The compounds are formed by nanoplatelets with a lateral size inferior to 20 nm. The addition of the ethylene glycol was found to increase the specific surface area, total pore volume, and water sorption capacity of the Mg–Al layered double hydroxide. However, it also decreased the average pore diameter, and the ion conductivity of the ethylene glycol modified layered double hydroxide was lower than expected based on the samples’ specific surface area and water content.
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Research context
OpenAlex topics: Layered Double Hydroxides Synthesis and Applications · Magnesium Oxide Properties and Applications · Supercapacitor Materials and Fabrication
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References (61)
Show source-provided references
1. Agmon N (2000) Mechanism of hydroxide mobility. Chem Phys Lett 319:247–252. doi: 10.1016/S0009-2614(00)00136-610.1016/S0009-2614(00)00136-6 ↗
2. Alberti G, Casciola M, Massinelli L, Bauer B (2001) Polymeric proton conducting membranes for medium temperature fuel cells (110–160°C). J Membr Sci 185:73–81. doi: 10.1016/S0376-7388(00)00635-910.1016/S0376-7388(00)00635-9 ↗
3. Allmann R (1968) The crystal structure of pyroaurite. Acta Crystallogr B24:972–977. doi: 10.1107/S056774086800351110.1107/S0567740868003511 ↗
4. Allmann R (1970) Double layer structures with brucite-like ions [M(II)1−xM(III)x(OH)2x+]. Chimia 24:99–108
5. Aramendia MA, Avilés Y, Benitez JA, Borau V, Jiménez C, Marinas JM, Ruiz JR, Urbano FJ (1999) Comparative study of Mg/Al and Mg/Ga layered double hydroxides. Microporous Mesoporous Mater 29:319–328. doi: 10.1016/S1387-1811(98)00345-X10.1016/S1387-1811(98)00345-X ↗
6. Béres A, Pálinkó I, Kiricsi I, Nagy JB, Kiyozumi Y, Mizukami F (1999) Layered double hydroxides and their pillared derivatives–materials for solid base catalysis; synthesis and characterization. Appl Catal A 182:237–247. doi: 10.1016/S0926-860X(99)00009-510.1016/S0926-860X(99)00009-5 ↗
7. Borgohain MM, Joykumar T, Bhat SV (2010) Studies on nanocomposite solid polymer electrolyte with hydrotalcite as a filler. Solid State Ion 181:964–970. doi: 10.1016/j.ssi.2010.05.04010.1016/j.ssi.2010.05.040 ↗
8. Bröcker FJ, Kainer L (1970) German Patent 2,024,282 to BASF AG
9. Casciola M, Marmottini F, Peraio A (1993) AC conductivity of a-layered zirconium phosphate in the presence of water vapour at 100–200°C. Solid State Ionics 61:125–129. doi: 10.1016/0167-2738(93)90344-310.1016/0167-2738(93)90344-3 ↗
10. Cavani F, Trifiro F, Vaccari A (1991) Hydrotalcite-type anionic clays: preparation, properties and applications. Catal Today 11:173–301. doi: 10.1016/0920-5861(91)80068-K10.1016/0920-5861(91)80068-K ↗
11. Cho MS, Shin B, Choi SD, Lee Y, Song KG (2004) Gel polymer electrolyte nanocomposites PEGDA with Mg–Al layered double hydroxides. Electrochim Acta 50:331–334. doi: 10.1016/j.electacta.2004.03.05010.1016/j.electacta.2004.03.050 ↗
12. Colomer MT, Anderson MA (2001) High porosity silica xerogels prepared by a particulate sol–gel route: pore structure and proton conductivity. J Non Cryst Solids 290:93–104. doi: 10.1016/S0022-3093(01)00815-810.1016/S0022-3093(01)00815-8 ↗
13. Condon JB (2006) Surface area and porosity determinations by physisorption, measurements and theory. Elsevier, The Netherlands
14. Crupi MP, Jannelli S, Magazu G, Maisano D, Majolino P, Migliardo D, Sirna D (1995) Rayleigh wing and Fourier transform infrared studies of intermolecular and intramolecular hydrogen bonds in liquid ethylene glycol. Mol Phys 84:645–652. doi: 10.1080/0026897950010043110.1080/00268979500100431 ↗
15. Crupi MP, Jannelli S, Magazu G, Maisano D, Majolino P, Migliardo P, Ponterio R (1996) Raman spectroscopic study of water in the poly(ethylene glycol) hydration shell. J Mol Struct 381:207–212. doi: 10.1016/0022-2860(96)09308-810.1016/0022-2860(96)09308-8 ↗
16. De Roy A, Besse JP (1989) Conductivité ionique de composées de type hydrotalcite. Solid State Ion 35:35–43. doi: 10.1016/0167-2738(89)90009-X10.1016/0167-2738(89)90009-X ↗
17. De Roy A, Besse JP (1991) Evolution of protonic conduction in some synthetic anionic clays. Solid State Ion 46:95–101. doi: 10.1016/0167-2738(91)90135-X10.1016/0167-2738(91)90135-X ↗
18. De Roy A, Besse JP, Bondot P (1985) Structural approach and conductivity of lamellar hydroxides Zn2Cr(OH)6X·nH2O (x = anion) by xanes, exafs and X-ray diffraction. Mater Res Bull 20:1091–1098. doi: 10.1016/0025-5408(85)90209-010.1016/0025-5408(85)90209-0 ↗
19. Evans DG, Slade RCT (2006) Structural aspects of layered double hydroxides. Struct Bond 119:1–87. doi: 10.1007/430_005
20. Felice V, Tavares AC (2011) Faujasite zeolites as solid electrolyte for low temperature fuel cells. Solid State Ion 194:53–61. doi: 10.1016/j.ssi.2011.05.00610.1016/j.ssi.2011.05.006 ↗
21. Feng YJ, Li DQ, Li CX, Wang ZH, Evans DG, Duan X (2003) Synthesis of Cu-containing layered double hydroxides with a narrow crystallite-size distribution. Clays Clay Miner 51:566–569. doi: 10.1346/CCMN.2003.051051010.1346/CCMN.2003.0510510 ↗
22. Furukawa Y, Tadanaga K, Hayashi A, Tatsumisago M (2011) Evaluation of ionic conductivity for Mg–Al layered double hydroxide intercalated with inorganic anions. Solid State Ion 192:185–187. doi: 10.1016/j.ssi.2010.05.03210.1016/j.ssi.2010.05.032 ↗
23. Gusmano G, Nunziante P, Traversa E, Chiozzini G (1991) Study of the thermal behaviour of hydroxide mixtures aimed at the preparation of Mg–Al spinels. J Therm Anal Calorim 37:1697–1707. doi: 10.1007/BF0191219910.1007/BF01912199 ↗
24. Hickner MA (2010) Ion-containing polymers: functional materials for new energy and clean water. Mater Today 13:34–41. doi: 10.1016/S1369-7021(10)70082-110.1016/S1369-7021(10)70082-1 ↗
25. Hou X, Bish DL, Wang SL, Johnston CT, Kirkpatrick RJ (2003) Hydration, expansion, structure, and dynamics of layered double hydroxides. Am Miner 88:167–16910.2138/am-2003-0120 ↗
26. Hussein MZ, Hwa TK (2000) Synthesis and properties of layered organic–inorganic hybrid material: Zn–Al layered double hydroxide–dioctyl sulfosuccinate nanocomposite. J Nanopart Res 2:293–298. doi: 10.1023/A:101001320139110.1023/A:1010013201391 ↗
27. Kim HS, Yamazaki Y, Kim JD, Kudo T, Honma I (2010) High ionic conductivity of Mg–Al layered double hydroxides at intermediate temperature (100–200°C) under saturated humidity condition (100% RH). Solid State Ion 181:883–888. doi: 10.1016/j.ssi.2010.04.03710.1016/j.ssi.2010.04.037 ↗
28. Lal M, Howe AT (1980) High proton conductivity in pressed pellets of zinc–chromium hydroxide. J Chem Soc Chem Commun 1980:737–738. doi: 10.1039/C3980000073710.1039/C39800000737 ↗
29. Lal M, Howe AT (1981) Studies of zinc–chromium hydroxy salts. II. Composite anion conductors of pressed disks of [Zn2Cr(OH)6]X·nH2O, where X−=F−, Cl−, Br−, I−, NO3 −, and CO3 2−. J Solid State Chem 39:377–386. doi: 10.1016/0022-4596(81)90273-510.1016/0022-4596(81)90273-5 ↗
30. Lee K, Nam JD (2006) Optimum ionic conductivity and diffusion coefficient of ion-exchange membranes at high methanol feed concentrations in a direct methanol fuel cell. J Power Sources 157:201–206. doi: 10.1016/j.jpowsour.2005.07.05910.1016/j.jpowsour.2005.07.059 ↗
31. Lee K, Nam JH, Lee JH, Lee Y, Cho SM, Jung CH, Choi HG, Chang YY, Kwon YU, Nam JD (2005) Methanol and proton transport control by using layered double hydroxide nanoplatelets for direct methanol fuel cell. Electrochem Commun 7:113–118. doi: 10.1016/j.elecom.2004.11.01110.1016/j.elecom.2004.11.011 ↗
32. Li XD, Yang WS, Li F, Evans DG, Duan X (2006) Stoichiometric synthesis of pure NiFe2O4 spinel from layered double hydroxide precursors for use as the anode material in lithium-ion batteries. J Phys Chem Solids 67:1286–1290. doi: 10.1016/j.jpcs.2006.01.09610.1016/j.jpcs.2006.01.096 ↗
33. Liao CS, Ye WB (2003) Enhanced ionic conductivity in poly(ethylene oxide)/layered double hydroxide nanocomposite electrolytes. J Polym Res 10:241–246. doi: 10.1023/b:jpol.0000004619.00197.7a10.1023/B:JPOL.0000004619.00197.7a ↗
34. Mikhailenko S, Desplantier-Giscard D, Danumah C, Kaliaguine S (2002) Solid electrolyte properties of sulfonic acid functionalized mesostructured porous silica. Microporous Mesoporous Mater 52:29–37. doi: 10.1016/S1387-1811(02)00275-510.1016/S1387-1811(02)00275-5 ↗
35. Miyata S (1975) The syntheses of hydrotalcite-like compounds and their structures and physico-chemical properties. Clays Clay Miner 23:369–375. doi: 10.1346/CCMN.1975.023050810.1346/CCMN.1975.0230508 ↗
36. Miyata S (1983) Anion-exchange properties of hydrotalcite-like compounds. Clays Clay Miner 31:305–311. doi: 10.1346/CCMN.1983.031040910.1346/CCMN.1983.0310409 ↗
37. Miyata S, Okada A (1977) Synthesis of hydrotalcite-like compounds and their physicochemical properties—the systems Mg2+–Al3+–SO4 2− and Mg2+–Al3+–CrO4 2−. Clays Clay Miner 25:14–18. doi: 10.1346/CCMN.1977.025010310.1346/CCMN.1977.0250103 ↗
38. Miyazaki K, Abe T, Nishio K, Nakanishi H, Ogumi Z (2010) Use of layered double hydroxides to improve the triple phase boundary in anion-exchange membrane fuel cells. J Power Sources 195:6500–6503. doi: 10.1016/j.jpowsour.2010.04.02310.1016/j.jpowsour.2010.04.023 ↗
39. Mokhtar M, Inayat A, Ofili J, Schwieger W (2010) Thermal decomposition, gas phase hydration and liquid phase reconstruction in the system Mg/Al hydrotalcite/mixed oxide: a comparative study. Appl Clay Sci 50:176–181. doi: 10.1016/j.clay.2010.07.01910.1016/j.clay.2010.07.019 ↗
40. Moneyron JE, De Roy A, Besse JP (1991) Protonic conductivity of hydrotalcite-type compound thick films: application to a humidity sensor. Solid State Ion 46:175–181. doi: 10.1016/0167-2738(91)90147-410.1016/0167-2738(91)90147-4 ↗
41. Muksing N, Magaraphan R, Coiai S, Passaglia E (2011) Effect of surfactant alkyl chain length on the dispersion, and thermal and dynamic mechanical properties of LDPE/organo-LDH composites. Express Polym Lett 5:428–448. doi: 10.3144/expresspolymlett.2011.4210.3144/expresspolymlett.2011.42 ↗
42. Nguyen TT, Raupach M, Janik LJ (1987) Fourier-transform infrared study of ethylene glycol monoethyl ether adsorbed on montmorillonite; implications for surface area measurements of clays. Clays Clay Miner 35:60–67. doi: 10.1346/CCMN.1987.035010810.1346/CCMN.1987.0350108 ↗
43. Olfs HW, Torres-Dorante LO, Eckelt R, Kosslick H (2009) Comparison of different synthesis routes for Mg–Al layered double hydroxides (LDH): characterization of the structural phases and anion exchange properties. Appl Clay Sci 43:459–464. doi: 10.1016/j.clay.2008.10.00910.1016/j.clay.2008.10.009 ↗
44. Ookubo A, Ooi K, Hayashi H (1993) Preparation and phosphate ion-exchange properties of a hydrotalcite-like compound. Langmuir 9:1418–1422. doi: 10.1021/la00029a04210.1021/la00029a042 ↗
45. Paulo MJ, Tavares AC (2011) Novel hydrotalcite composites membranes for alkaline fuel cells. ECS Trans 35(31):21. doi: 10.1149/1.364785010.1149/1.3647850 ↗
46. Pernice P, Marino O, Masoolo G (1988) Influence of temperature and humidity on ionic conduction of mixed metal hydroxides. Thermochim Acta 13:87–92. doi: 10.1016/0040-6031(88)87141-710.1016/0040-6031(88)87141-7 ↗
47. Philippova OE, Kuchanov SI, Topchieva IN, Kabanov VA (1985) Hydrogen bonds in dilute solutions of poly(ethylene glycol). Macromolecules 18:1628–1633. doi: 10.1021/ma00150a01810.1021/ma00150a018 ↗
48. Reeves V (2001) Layered double hydroxides: present and future. Nova Science, New York, p 140
49. Reichle WT (1986) Synthesis of anionic clay minerals (mixed metal hydroxides, hydrotalcite). Solid State Ion 22:135–141. doi: 10.1016/0167-2738(86)90067-610.1016/0167-2738(86)90067-6 ↗
50. Rozenberg M, Loewenschuss A, Marcus Y (1998) IR spectra and hydration of short-chain polyethyleneglycol. Spectrochim Acta A 54:1819–1826. doi: 10.1016/S1386-1425(98)00062-610.1016/S1386-1425(98)00062-6 ↗
51. Stygar J, Zukowska G, Wieczorek W (2005) Study of association in alkali metal perchlorate–poly(ethylene glycol) monomethyl ether solutions by FT-IR spectroscopy and conductivity measurements. Solid State Ion 176:2645–2652. doi: 10.1016/j.ssi.2005.07.00610.1016/j.ssi.2005.07.006 ↗
52. Tadanaga K, Furukawa Y, Hayashi A, Tatsumisago M (2010) Direct ethanol fuel cell using hydrotalcite clay as a hydroxide ion conductive electrolyte. Adv Mater 22:4401–4404. doi: 10.1002/adma.20100176610.1002/adma.201001766 ↗
53. Tamaki T, Nakanishi N, Ohashi H, Yamaguchi T (2012) The effect of particle size and surface area on the ion conductivity of layered double hydroxide. Electrochem Comm 25:50–53. doi: 10.1016/j.elecom.2012.09.00310.1016/j.elecom.2012.09.003 ↗
54. Tichit D, Lhouty MH, Guida A, Chiche BH, Figueras F, Auroux A, Bartalini D, Garrone E (1995) Textural properties and catalytic activity of hydrotalcites. J Catal 151:50–59. doi: 10.1006/jcat.1995.100710.1006/jcat.1995.1007 ↗
55. Traversa E, Nunziante P, Chiozzini P (1992a) Thermal decomposition of Mg–Al hydroxides coprecipitated in the presence of oxalate ions. Thermochim Acta 199:25–33. doi: 10.1016/0040-6031(92)80247-T10.1016/0040-6031(92)80247-T ↗
56. Traversa E, Montesperelli G, Nunziante P, Chiozzini G (1992b) The thermal behaviour of the hydroxide mixtures used for the synthesis of MgFe2O4 spinel. J Therm Anal Calorim 38:2583–2592. doi: 10.1007/BF0197973410.1007/BF01979734 ↗
57. Trikeriotis M, Ghanotakis DF (2007) Intercalation of hydrophilic and hydrophobic antibiotics in layered double hydroxides. Int J Pharm 332:176–184. doi: 10.1016/j.ijpharm.2006.09.03110.1016/j.ijpharm.2006.09.031 ↗
58. Valente JS, Sanchez-Cantu M, Lima E, Figueras F (2009) Method for large-scale production of multimetallic layered double hydroxides: formation mechanism discernment. Chem Mater 21:5809–5818. doi: 10.1021/cm902377p10.1021/cm902377p ↗
59. Varcoe JR, Slade RC (2005) Prospects for alkaline anion-exchange membranes in low temperature fuel cells. Fuel Cells 5:187–200. doi: 10.1002/fuce.20040004510.1002/fuce.200400045 ↗
60. Yang W, Kim Y, Liu PKT, Sahimi M, Tsotsis TT (2002) A study by in situ techniques of the thermal evolution of the structure of a Mg–Al–CO3 layered double hydroxide. Chem Eng Sci 57:2945–2953. doi: 10.1016/S0009-2509(02)00185-910.1016/S0009-2509(02)00185-9 ↗
61. Yun SK, Pinnavaia TJ (1995) Water content and particle texture of synthetic hydrotalcite-like layered double hydroxides. Chem Mater 7:348–354. doi: 10.1021/cm00050a01710.1021/cm00050a017 ↗