Nitrilimine cycloadditions catalyzed by iron oxide nanoparticles
Source abstract
Abstract
Nitrilimine cycloadditions to ethylenes, acetylenes, and activated nitriles have been exploited in the presence of catalytic amounts of oleic-acid-coated iron oxide nanoparticles (diameter = 11.9 +/- 1.0 nm). The reactions were fully regioselective with monosubstituted ethylenes and ethyl cyanoformiate, while mixtures of cycloadducts were obtained in the presence of methyl propiolate. The intervention of iron oxide nanoparticles allowed carrying out the cycloadditions at milder conditions compared to the metal-free thermal processes. A labile intermediate has been proposed to explain this behavior.
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Research context
OpenAlex topics: Nanomaterials for catalytic reactions · Molecular Junctions and Nanostructures · Click Chemistry and Applications
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