Polyol-mediated syntheses of crystalline nanosized manganese oxides
Source abstract
Abstract
Potassium-type birnessite and lithium-containing manganese oxides were prepared by the polyol process. The Mn(III)/Mn(IV) mixed-valencies compounds are obtained through the controlled reduction of potassium permanganate in a basic water–diethylene glycol mixture at moderate temperature and very short reaction time, 70 °C and 10 min, respectively. Both solids are quite well crystallized and display high specific surface areas, 137 and 329 m2 g−1, respectively. Several polyols with variable chain lengths have been used and it is shown that the nature of the polyol has a marked influence on the textural properties of the birnessite-type solid.
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Research context
OpenAlex topics: Geochemistry and Elemental Analysis · Layered Double Hydroxides Synthesis and Applications · Supercapacitor Materials and Fabrication
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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