Characterization of crystalline silica nanorods synthesized via a solvothermal route using polyvinylbutyral as a template
Source abstract
Abstract
The preparation of crystalline silica nanorods is presented. Crystalline silica nanorods were synthesized via a simple solvothermal route using polyvinylbutyral (PVB) as a template in an autoclave with ethylenediamine as a solvent at 180 °C for 25 h. Silica nanorods with diameters in the range of 50–80 nm were obtained. The solvothermal route with a PVB template played affected the crystallization process and the growth of the silica nanorods. The as-synthesized products were characterized using X-ray diffraction, energy dispersive spectrometry, scanning electron microscopy, and transmission electron microscopy.
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Research context
OpenAlex topics: TiO2 Photocatalysis and Solar Cells · Gas Sensing Nanomaterials and Sensors · Conducting polymers and applications
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References (39)
Show source-provided references
1. Chao CH, Lu HY (2002) Stress-induced β→α-cristobalite phase transformation in (Na2O + Al2O3)-codoped silica. Mater Sci Eng A 328:267–27610.1016/S0921-5093(01)01703-8 ↗
2. Chen LJ, Liao JD, Lin SJ, Chuang YJ, Fu YS (2009) Synthesis and characterization of PVB/silica nanofibers by electrospinning process. Polymer 50:3516–352110.1016/j.polymer.2009.05.063 ↗
3. Drees LR, Wilding LP, Smeck NE, Senkayi AL (1995) Silica in soils: quartz and disordered silica polymorphs. In: Dixon JB, Weed SB (eds) Minerals in soil environments, vol 1. SSSA Book Series. Madison, pp 913–975
4. Duan XF, Huang Y, Agarwal R, Lieber CM (2003) Single-nanowire electrically driven lasers. Nature 421:241–24510.1038/nature01353 ↗
5. Feller RL, Curran M, Colaluca V, Bogaard J, Bailie C (2007) Photochemical deterioration of poly(vinylbutyral) in the range of wavelengths from middle ultraviolet to the visible. Polym Degrad Stab 92:920–93110.1016/j.polymdegradstab.2005.11.015 ↗
6. Gao P, Wang ZL (2002) Self-assembled nanowire–nanoribbon junction arrays of ZnO. J Phys Chem B 106:12653–1265810.1021/jp0265485 ↗
7. Harkless JAW, Stillinger DK, Stillinger FH (1996) Structures and energies of SiO2 clusters. J Phys Chem 100:1098–110310.1021/jp950807r ↗
8. Hartmann M, Hierarchical Z (2004) A proven strategy to combine shape selectivity with efficient mass transport. Angew Chem Int Ed 43:5880–588210.1002/anie.200460644 ↗
9. Ilic B, Craighead HG, Krylov S, Senaratne W, Ober C, Neuzil P (2004) Attogram detection using nanoelectromechanical oscillators. J Appl Phys 95:3694–370310.1063/1.1650542 ↗
10. Innocenzi P, Martucci A, Guglielmi M, Bearzotti A, Traversa E, Pivin JC (2001) Mesoporous silica thin films for alcohol sensors. J Eur Ceram Soc 21:1985–198810.1016/S0955-2219(01)00156-X ↗
11. Kameoka J, Scott SV, Haiqing L, Czaplewski DA, Craighead HG (2004) Fabrication of suspended silica glass nanofibers from polymeric materials using a scanned electrospinning source. Nano Lett 4:2105–210810.1021/nl048840p ↗
12. Kim C, Yang KS (2003) Electrochemical properties of carbon nanofiber web as an electrode for supercapacitor prepared by electrospinning. Appl Phys Lett 83:1216–121810.1063/1.1599963 ↗
13. Lao JY, Wen JG, Ren ZF (2002) Hierarchical ZnO nanostructures. Nano Lett 2:1287–129110.1021/nl025753t ↗
14. Lee JS, Choi SC (2004) Crystallization behavior of nano-ceria powders by hydrothermal synthesis using a mixture of H2O2 and NH4OH. Mater Lett 58:390–39310.1016/S0167-577X(03)00508-1 ↗
15. Lee JS, Choi SC (2005) Solvent effect on synthesis of indium tin oxide nano-powders by a solvothermal process. J Eur Ceram Soc 25:3307–331410.1016/j.jeurceramsoc.2004.08.022 ↗
16. Li YD, Liao HW, Ding Y, Qian YT, Yang L, Zhou GE (1998) Nonaqueous synthesis of CdS nanorod semiconductor. Chem Mater 10:2301–230310.1021/cm970789l ↗
17. Li D, Wang Y, Xia Y (2004) Electrospinning nanofibers as uniaxially aligned arrays and layer-by-layer stacked films. Adv Mater 16:361–36610.1002/adma.200306226 ↗
18. Li X, Wu Y, Li Y (2007) Surfactant-assisted synthesis of helical silica. Inorg Chem Acta 360:241–24510.1016/j.ica.2006.07.038 ↗
19. Liu H, Kameoka J, Czaplewski DA, Craighead HG (2004) Polymeric nanowire chemical sensor. Nano Lett 4:671–67510.1021/nl049826f ↗
20. Matijevi E (1993) Preparation and properties of uniform size colloids. Chem Mater 5:412–42610.1021/cm00028a004 ↗
21. Mitchell BD (1975) Oxides and hydrous oxides of silicon. In: Gieseking JE (ed) Soil components, vol 2. Springer-Verlag, New York, pp 395–43210.1007/978-3-642-65917-1_11 ↗
22. Nagano T, Fujisaki S, Sato K, Hataya K, Iwamoto Y, Nomura M, Nakao SI (2008) Relationship between the mesoporous intermediate layer structure and the gas permeation property of an amorphous silica membrane synthesized by counter diffusion chemical vapor deposition. J Am Ceram Soc 91:71–7610.1111/j.1551-2916.2007.02073.x ↗
23. Ogihara H, Masahiro SM, Nodasaka Y, Ueda W (2006a) Shape-controlled synthesis of ZrO2, Al2O3, and SiO2 nanotubes using carbon nanofibers as templates. Chem Mater 18:4981–498310.1021/cm061266t ↗
24. Ogihara H, Takenaka S, Yamanaka I, Tanabe E, Genseki A, Otsuka K (2006b) Synthesis of SiO2 nanotubes and their application as nanoscale reactors. Chem Mater 18:996–100010.1021/cm051727v ↗
25. Peng Z, Kong LX, Li SD, Chen Y, Huang MF (2007) Self-assembled natural rubber/silica nanocomposites: its preparation and characterization. Compos Sci Technol 67:3130–313910.1016/j.compscitech.2007.04.016 ↗
26. Piticescu RR, Monty C, Taloi D, Motoc A, Axinte S (2001) Hydrothermal synthesis of zirconia nanomaterials. J Eur Ceram Soc 21:2057–206010.1016/S0955-2219(01)00171-6 ↗
27. Ruenraroengsak P, Florence AT (2005) The diffusion of latex nanospheres and the effective (microscopic) viscosity of HPMC gels. Int J Pharm 298:361–36610.1016/j.ijpharm.2005.01.044 ↗
28. Sigma MB, Korgel BA (2005) Solventless synthesis of Bi2S3 (bismuthinite) nanorods, nanowires, and nanofabric. Chem Mater 17:1655–166010.1021/cm0478733 ↗
29. Tang KB, Qian YT, Zeng JH, Yang XG (2003) Solvothermal route to semiconductor nanowires. Adv Mater 15:448–45010.1002/adma.200390104 ↗
30. Wagner RS, Elhs WC (1964) Vapor–liquid–solid mechanism of single crystal growth. Appl Phys Lett 4:89–9010.1063/1.1753975 ↗
31. Wang ZL (2000) Characterizing the structure and properties of individual wire-like nanoentities. Adv Mater 12:1295–129810.1002/1521-4095(200009)12:17<1295::AID-ADMA1295>3.0.CO;2-B ↗
32. Wang W, Poudel B, Yang J, Wang DZ, Ren ZF (2005) High-yield synthesis of single-crystalline antimony telluride hexagonal nanoplates using a solvothermal approach. J Am Chem Soc 127:13792–1379310.1021/ja054861p ↗
33. Yang PD, Lieber CM (1996) Nanorod-superconductor composites: a pathway to materials with high critical current densities. Science 273:1836–184010.1126/science.273.5283.1836 ↗
34. Yang YX, Qu XP, Chen YR, Jia XC, Zhang JB, Liu XN (2007) Effect of counterions on synthesis of mesoporous silica by the route of template. J Am Chem Soc 90:2050–2056
35. Yazawa M, Koguchi M, Hiruma K (1993) Semiconductor nanowhiskers. Adv Mater 5:577–58010.1002/adma.19930050715 ↗
36. Yoshimoto Y, Shin YM, Rerai H, Cacanti JP, Jin HJ (2003) A biodegradable nanofiber scaffold by electrospinning and its potential for bone tissue engineering. Biomaterials 24:2077–208210.1016/S0142-9612(02)00635-X ↗
37. You Y, Min BM, Lee JS, Lee TS, Park WH (2005) In vitro degradation behavior of electrospun polyglycolide, polylactide, and poly(lactide-co-glycolide). J Appl Polym Sci 95:193–20010.1002/app.21116 ↗
38. Yu SH (2001) Hydrothermal/solvothermal processing of advanced ceramic materials. J Ceram Soc Jpn 109:S65–S7510.2109/jcersj.109.1269_S65 ↗
39. Zhang J, Sun L, Yin J, Su H, Liao C, Yan C (2002) Control of ZnO morphology via a simple solution route. Chem Mater 14:4172–417710.1021/cm020077h ↗