journal article·2013-09

Unusually large magnetic moments in the normal state and superconducting state of Sn nanoparticles

Chi-Hang Hung, Chi-Hung Lee, Chien-Kang Hsu, Chi-Yen Li, Sunil K. Karna, Chin-Wei Wang, Chun-Ming Wu, Wen-Hsien Li

Journal of Nanoparticle Research· Volume 15· Issue 9
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Abstract

We report on the observations of spontaneous magnetic moments in the normal as well as in the superconducting states of a 9 nm Sn nanoparticle assembly, through X-ray diffraction, magnetization, ac magnetic susceptibility, and neutron diffraction measurements. The saturation magnetization reaches an unexpectedly large value of 1.04 emu/g at 5 K, with a temperature profile that can be described by Bloch’s law with an exponent of b = 1.8. A magnetic moment of 〈μ Z〉 = 0.38 μ B develops after cooling from 260 to 4 K. Superconductivity develops below T C = 3.98 K, which is 7 % higher than the T C = 3.72 K of bulk Sn. Surprisingly, an addition magnetic moment of 〈μ Z〉 = 0.05 μ B develops upon entering the superconducting state.
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Research context

OpenAlex topics: Surface and Thin Film Phenomena · Physics of Superconductivity and Magnetism · Quantum and electron transport phenomena

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References (26)

Show source-provided references
1. Alonso JA (2000) Electronic and atomic structure, and magnetism of transition-metal clusters. Chem Rev 100:637. doi: 10.1021/cr980391o10.1021/cr980391o ↗
2. Bezryadin A, Lau CN, Tinkham M (2000) Quantum suppression of superconductivity in ultrathin nanowires. Nature 404:971–974. doi: 10.1038/3501006010.1038/35010060 ↗
3. Bose S, Raychaudhuri P, Banerjee R, Vasa P, Ayyub P (2005) Mechanism of the size dependence of the superconducting transition of nanostructured Nb. Phys Rev Lett 95:147003. doi: 10.1103/PhysRevLett.95.14700310.1103/PhysRevLett.95.147003 ↗
4. Bose S, Garcia–Garcia AM, Ugeda MM, Urbina JD, Michaelis CH, Brihuega I, Kern K (2010) Observation of shell effects in superconducting nanoparticles of Sn. Nat Mater 9:550–554. doi: 10.1038/nmat276810.1038/nmat2768 ↗
5. Crespo P, Litrán R, Rojas TC, Multigner M, de la Fuente JM, Sánchez-López JC, García MA, Hernando A, Penadés S, Fernández A (2004) Permanent magnetism, magnetic anisotropy, and hysteresis of thiol-capped gold nanoparticles. Phys Rev Lett 93:087204. doi: 10.1103/PhysRevLett.93.08720410.1103/PhysRevLett.93.087204 ↗
6. DeWames RE, Wolfram T, Lehman GW (1963) Temperature dependence and anisotropy in the Debye–Waller factor for white tin. Phys Rev 131:529. doi: 10.1103/PhysRev.131.52910.1103/PhysRev.131.529 ↗
7. Duffy JA, Hayden SM, Maeno Y, Mao Z, Kulda J, McIntyre GJ (2000) Polarized-neutron scattering study of the cooper-pair moment in Sr2RuO4. Phys Rev Lett 85:5412. doi: 10.1103/PhysRevLett.85.541210.1103/PhysRevLett.85.5412 ↗
8. Guo Y, Zhang YF, Bao X-Y, Han T-Z, Tang Z, Zhang L-X, Zhu W-G, Wang EG, Niu Q, Qiu ZQ, Jia JF, Zhao Z-X, Xue Q-K (2004) Superconductivity modulated by quantum size effects. Science 306:1915–1917. doi: 10.1126/science.110513010.1126/science.1105130 ↗
9. Halperin WP (1986) Quantum size effects in metal particles. Rev Mod Phys 58:533. doi: 10.1103/RevModPhys.58.53310.1103/RevModPhys.58.533 ↗
10. Hendriksen PV, Linderoth S, Lindgård P-A (1992) Finite-size effects in the magnetric properties of ferromagnetic clusters. J Magn Magn Mater 104–107:1577. doi: 10.1016/0304-8853(92)91461-210.1016/0304-8853(92)91461-2 ↗
11. Hernando A, Crespo P, García MA (2006) Origin of orbital ferromagnetism and giant magnetic anisotropy at the nanoscale. Phys Rev Lett 96:057206. doi: 10.1103/PhysRevLett.96.05720610.1103/PhysRevLett.96.057206 ↗
12. Hori H, Yamamoto Y, Iwamoto T, Miura T, Teranishi T, Miyake M (2004) Diameter dependence of ferromagnetic spin moment in Au nanocrystals. Phys Rev B 69:174411. doi: 10.1103/PhysRevB.69.17441110.1103/PhysRevB.69.174411 ↗
13. Isabelle ML, Châtelain A, de Heer WA (1994) Magnetism from the atom to the bulk in iron, cobalt, and nickel clusters. Science 265:1682. doi: 10.1126/science.265.5179.168210.1126/science.265.5179.1682 ↗
14. Karna SK, Li C-Y, Wu C-M, Hsu C-K, Wang C-W, Li W-H (2011) Observations of large magnetic moments in icosahedral Pb nanoparticles. J Phys Chem C 115:8906. doi: 10.1021/jp111821210.1021/jp1118212 ↗
15. Khanna SN, Linderoth S (1991) Magnetic behavior of clusters of ferromagnetic transition metals. Phys Rev Lett 67:742. doi: 10.1103/PhysRevLett.67.74210.1103/PhysRevLett.67.742 ↗
16. Kittel C (1996) Introduction to solid state physics, 7th edn. Wiley, NewYork, pp 446–448
17. Larson AC, Von Dreele RB (1990) General structure analysis system. Los Alamos National Laboratory Report LAUR-86-748
18. LeClair P, Moodera JS, Philip J, Heiman D (2005) Coexistence of ferromagnetism and superconductivity in Ni/Bi bilayers. Phys Rev Lett 94:037006. doi: 10.1103/PhysRevLett.94.03700610.1103/PhysRevLett.94.037006 ↗
19. Li W-H, Yang CC, Tsao FC, Lee KC (2003) Quantum size effects on the superconducting parameters of zero-dimensional Pb nanoparticles. Phys Rev B 68:184507. doi: 10.1103/PhysRevB.68.18450710.1103/PhysRevB.68.184507 ↗
20. Li W-H, Yang CC, Tsao FC, Wu SY, Huang PJ, Chung MK, Yao YD (2005) Enhancement of superconductivity by the small size effect in In nanoparticles. Phys Rev B 72:214516. doi: 10.1103/PhysRevB.72.21451610.1103/PhysRevB.72.214516 ↗
21. Li W-H, Wang C-W, Li C-Y, Hsu CK, Yang CC, Wu C-M (2008) Coexistence of ferromagnetism and superconductivity in Sn nanoparticles. Phys Rev B 77:094508. doi: 10.1103/PhysRevB.77.09450810.1103/PhysRevB.77.094508 ↗
22. Liu S-B, Chen C-T, Wu C-M, Wang C-W, Wang C-J, Karna SK, Li W-H (2011) Suppression of superconductivity by interparticle interactions in Al nanoparticle assembly. J Appl Phys 109:07E153. doi: 10.1063/1.356493610.1063/1.3564936 ↗
23. Mühlschlegel B, Scalapino DJ, Dento R (1972) Thermodynamic properties of small superconducting particles. Phys Rev B 6:1767. doi: 10.1103/PhysRevB.6.176710.1103/PhysRevB.6.1767 ↗
24. Reich S, Leitus G, Popovitz-Biro R, Schechter M (2003) Magnetization of small lead particles. Phys Rev Lett 91:147001. doi: 10.1103/PhysRevLett.91.14700110.1103/PhysRevLett.91.147001 ↗
25. Wu C-M, Li C-Y, Kuo Y-T, Wang C-W, Wu S-Y, Li W-H (2010) Quantum spins in Mackay icosahedral gold nanoparticles. J Nanopart Res 12:177–185. doi: 10.1007/s11051-009-9592-310.1007/s11051-009-9592-3 ↗
26. Yamamoto Y, Miura T, Suzuki M, Kawamura N, Miyagawa H, Nakamura T, Kobayashi K, Teranishi T, Hori H (2004) Direct observation of ferromagnetic spin polarization in gold nanoparticles. Phys Rev Lett 93:116801. doi: 10.1103/PhysRevLett.93.11680110.1103/PhysRevLett.93.116801 ↗