journal article·2012-08

Versatile and biomass synthesis of iron-based nanoparticles supported on carbon matrix with high iron content and tunable reactivity

Dongmao Zhang, Sheldon Q. Shi, Charles U. Pittman, Dongping Jiang, Wen Che, Zheng Gai, Jane Y. Howe, Karren L. More, Arockiasamy Antonyraj

Journal of Nanoparticle Research· Volume 14· Issue 8
Publisher page

Abstract

Iron-based nanoparticles supported on carbon (FeNPs@C) have enormous potential for environmental applications. Reported is a biomass-based method for FeNP@C synthesis that involves pyrolysis of bleached wood fiber pre-mixed with Fe3O4 nanoparticles. This method allows synthesis of iron-based nanoparticles with tunable chemical reactivity by changing the pyrolysis temperature. The FeNP@C synthesized at a pyrolysis temperature of 500 °C (FeNP@C-500) reacts violently (pyrophoric) when exposed to air, while FeNP@C prepared at 800 °C (FeNP@C-800) remains stable in ambient condition for at least 3 months. The FeNPs in FeNP@C-800 are mostly below 50 nm in diameter and are surrounded by carbon. The immediate carbon layer (within 5–15 nm radius) on the FeNPs is graphitized. Proof-of-concept environmental applications of FeNPs@C-800 were demonstrated by Rhodamine 6G and arsenate (V) removal from water. This biomass-based method provides an effective way for iron-based nanoparticle fabrication and biomass utilization.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Environmental remediation with nanomaterials · Nanomaterials for catalytic reactions · Nanoparticles: synthesis and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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