journal article·2025-11

Fundamentals of two-dimensional Ca2Nb3O10 (CNO)

Nahide Karabulut, Büşra Aydin Demi̇r, Safiye Karaçam, Çağlar Duman, Meltem Gör Bölen

Journal of Nanoparticle Research· Volume 27· Issue 11
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Abstract

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OpenAlex topics: Layered Double Hydroxides Synthesis and Applications · Electronic and Structural Properties of Oxides · Dielectric properties of ceramics

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References (70)

Show source-provided references
1. Schlom DG, Chen LQ, Pan X, Schmehl A, Zurbuchen MA (2008) A thin film approach to engineering functionality into oxides. J Am Ceram Soc 91(8):2429–245410.1111/j.1551-2916.2008.02556.x ↗
2. Aleksandrov KS, Beznosikov VV (1997) Hierarchies of perovskite-like crystals. Phys Solid State 39:695–71510.1134/1.1130120 ↗
3. Novoselov KS, Colombo L, Gellert PR, Schwab MG, Kim KAJN (2012) A roadmap for graphene. Nature 490(7419):192–20010.1038/nature11458 ↗
4. Butler SZ, Hollen SM, Cao L, Cui Y, Gupta JA, Gutiérrez HR, Goldberger JE (2013) Progress, challenges, and opportunities in two-dimensional materials beyond graphene. ACS Nano 7(4):2898–292610.1021/nn400280c ↗
5. Khan K, Tareen AK, Aslam M, Wang R, Zhang Y, Mahmood A, Ouyang Z, Zhang H, Guo Z (2020) Recent developments in emerging two-dimensional materials and their applications. J Mater Chem C 8(2):387–44010.1039/C9TC04187G ↗
6. Schaak RE, Mallouk TE (2000) Self-assembly of tiled perovskite monolayer and multilayer thin films. Chem Mater 12(9):2513–251610.1021/cm0004073 ↗
7. Ziegler C (2015) Two-dimensional transition metal oxide nanosheets for nanoarchitectonics (Doctoral dissertation, Fakultät für Chemie und Pharmazie, Ludwig‑Maximilians‑Universität München, München, Germany). https://doi.org/10.5282/edoc.2032610.5282/edoc.20326 ↗
8. Ma R, Sasaki T (2015) Two-dimensional oxide and hydroxide nanosheets: controllable high-quality exfoliation, molecular assembly, and exploration of functionality. Acc Chem Res 48(1):136–14310.1021/ar500311w ↗
9. Schaak RE, Mallouk TE (2002) Perovskites by design: a toolbox of solid-state reactions. Chem Mater 14(4):1455–147110.1021/cm010689m ↗
10. Knapp MC (2006) Investigations into the structure and properties of ordered perovskites, layered perovskites, and defect pyrochlores (Doctor of Philosophy Dissertation, Graduate School, The Ohio State University, Columbus, Ohio, USA)
11. Schaak RE, Mallouk TE (2000) Prying apart Ruddlesden− Popper phases: exfoliation into sheets and nanotubes for assembly of perovskite thin films. Chem Mater 12(11):3427–343410.1021/cm000495r ↗
12. Moritomo Y, Asamitsu A, Kuwahara H, Tokura Y (1996) Giant magnetoresistance of manganese oxides with a layered perovskite structure. Nature 380(6570):141–14410.1038/380141a0 ↗
13. Hase I, Nishihara Y (1998) Electronic structure of the superconducting layered perovskite niobate. Phys Rev B 58(4):R170710.1103/PhysRevB.58.R1707 ↗
14. Kobayashi Y, Tian M, Eguchi M, Mallouk TE (2009) Ion-exchangeable, electronically conducting layered perovskite oxyfluorides. J Am Chem Soc 131(28):9849–985510.1021/ja9040829 ↗
15. Osada M, Sasaki T (2015) Nanosheet architectonics: a hierarchically structured assembly for tailored fusion materials. Polym J 47(2):89–9810.1038/pj.2014.111 ↗
16. Ebina Y, Sasaki T, Watanabe M (2002) Study on exfoliation of layered perovskite-type niobates. Solid State Ionics 151(1–4):177–18210.1016/S0167-2738(02)00707-5 ↗
17. Zhang Y, Li S, Li Z, Liu H, Liu X, Chen J, Fang X (2020) High-performance two-dimensional perovskite Ca2Nb3O10 UV photodetectors. Nano Lett 21(1):382–38810.1021/acs.nanolett.0c03759 ↗
18. Li K, Liu X, Zhang Y, Li X, Lian H, Lin J (2015) Host-sensitized luminescence properties in CaNb2O6: Ln3+ (Ln3+= Eu3+/Tb3+/Dy3+/Sm3+) phosphors with abundant colors. Inorg Chem 54(1):323–33310.1021/ic502493c ↗
19. Okamoto Y, Ida S, Hyodo J, Hagiwara H, Ishihara T (2011) Synthesis and photocatalytic activity of rhodium-doped calcium niobate nanosheets for hydrogen production from a water/methanol system without cocatalyst loading. J Am Chem Soc 133(45):18034–1803710.1021/ja207103j ↗
20. Ohisa S, Hikichi T, Pu YJ, Chiba T, Kido J ((2018)) Two-dimensional Ca2Nb3O10 perovskite nanosheets for electron injection layers in organic light-emitting devices. ACS Appl Mater Interfaces 10(33):27885–2789310.1021/acsami.8b05759 ↗
21. Ziegler C, Werner S, Bugnet M, Wörsching M, Duppel V, Botton GA, Scheu C, Lotsch BV (2013) Artificial solids by design: assembly and electron microscopy study of nanosheet-derived heterostructures. Chem Mater 25(24):4892–490010.1021/cm402950b ↗
22. Xu FF, Ebina Y, Bando Y, Sasaki T (2003) Structural characterization of (TBA, H) Ca2Nb3O10 nanosheets formed by delamination of a precursor-layered perovskite. J Phys Chem B 107(36):9638–964510.1021/jp030136u ↗
23. Dion M, Ganne M, Tournoux M (1981) Nouvelles familles de phases MIMII2Nb3O10 a feuillets “perovskites.” Mater Res Bull 16(11):1429–143510.1016/0025-5408(81)90063-5 ↗
24. Liu X, Li S, Li Z, Zhang Y, Yang W, Li Z, Liu H, Shtansky DV, Fang X (2021) Boosted responsivity and tunable spectral response in B-site substituted 2D Ca2Nb3− xTaxO10 perovskite photodetectors. Adv Funct Mater 31(20):210148010.1002/adfm.202101480 ↗
25. Chen X, Chen S, Shen P, Chen Y, Wang K, He S, Xu Qi, Xi X (2025) A visible light-driven 3D/2D ZnIn2S4/H+ Ti2NbO7− system for hydrogen evolution: interface effects and photocatalytic mechanisms. J Mater Sci. https://doi.org/10.1007/s10853-025-10893-810.1007/s10853-025-10893-8 ↗
26. Compton OC, Carroll EC, Kim JY, Larsen DS, Osterloh FE (2007) Calcium niobate semiconductor nanosheets as catalysts for photochemical hydrogen evolution from water. J Phys Chem C Nanomater Interfaces 111(40):14589–1459210.1021/jp0751155 ↗
27. Akatsuka K, Takanashi G, Ebina Y, Haga MA, Sasaki T (2012) Electronic band structure of exfoliated titanium-and/or niobium-based oxide nanosheets probed by electrochemical and photoelectrochemical measurements. J Phys Chem C Nanomater Interfaces 116(23):12426–1243310.1021/jp302417a ↗
28. Jiang D, Zhang Q, Chen D, Wen B, Song Q, Zhou C, Li D (2021) KCa2Nb3O10/ZnIn2S4 nanosheet heterojunctions with improved charge separation efficiency for efficient photocatalytic CO2 reduction. J Alloys Compd 865:15883610.1016/j.jallcom.2021.158836 ↗
29. Kim JW, Kim A (2021) Absolute work function measurement by using photoelectron spectroscopy. Curr Appl Phys 31:52–5910.1016/j.cap.2021.07.018 ↗
30. Kahn A (2016) Fermi level, work function and vacuum level. Mater Horiz 3(1):7–1010.1039/C5MH00160A ↗
31. Freeouf JL, Woodall JM (1988) Schottky barriers: An effective work function model. Electronic Structure of Semiconductor Heterojunctions. Springer, Netherlands, Dordrecht, pp 177–17910.1007/978-94-009-3073-5_14 ↗
32. Greiner MT, Lu ZH (2013) Thin-film metal oxides in organic semiconductor devices: their electronic structures, work functions and interfaces. NPG Asia Mater 5(7):e55–e5510.1038/am.2013.29 ↗
33. Sasaki T, Hasegawa M, Inagaki K, Ito H, Suzuki K, Oono T, Fukagawa H (2021) Unravelling the electron injection/transport mechanism in organic light-emitting diodes. Nat Commun 12(1):270610.1038/s41467-021-23067-2 ↗
34. Chitrakar R, Makita Y, Sonoda A (2013) Cesium ion decontamination by layered perovskite HCa2Nb3O10· 1.5 H2O. Bull Chem Soc Jpn 86(12):1419–142510.1246/bcsj.20130201 ↗
35. Kikuta K, Noda K, Okumura S, Yamaguchi T, Hirano SI (2007) Orientation control of perovskite thin films on glass substrates by the application of a seed layer prepared from oxide nanosheets. J Sol-Gel Sci Technol 42:381–38710.1007/s10971-006-0200-z ↗
36. Fu S, Zhang B, Miao Z, Li Z, Tu R, Zhang S, Li BW (2022) The dispersion and coagulation of negatively charged Ca2Nb3O10 perovskite nanosheets in sodium alginate dispersion. Nanomaterials 12(15):259110.3390/nano12152591 ↗
37. Rabin NN, Ida S, Karim MR, Islam MS, Ohtani R, Nakamura M, Koinuma M, Lindoy LF, Hayami S (2018) Super dielectric materials of two-dimensional TiO2 or Ca2Nb3O10 nanosheet hybrids with reduced graphene oxide. ACS Omega 3(2):2074–208310.1021/acsomega.7b01764 ↗
38. Sakaki M, Feng YQ, Kajiyoshi K (2019) Ultrasonic-assisted exfoliation of Ca2Nb3O10− nano-sheets. J Solid State Chem 277:253–25910.1016/j.jssc.2019.06.018 ↗
39. Mei L, Sun M, Yang R, Zhang Y, Zhang Y, Zhang Z, Zheng L, Chen Ye, Zhang Q, Zhou J, Zhu Ye, Leung KMY, Zhang W, Fan J, Huang B, Zeng XC, Shin HS, Tang CY, Gu L, Voiry D, Zeng Z (2024) Metallic 1T/1T′ phase TMD nanosheets with enhanced chemisorption sites for ultrahigh-efficiency lead removal. Nat Commun 15(1):777010.1038/s41467-024-52078-y ↗
40. Mei L, Gao Z, Yang R, Zhang Z, Sun M, Liang X ... Zeng Z (2025) Phase-switchable preparation of solution-processable WS2 mono-or bilayers. Nat Synth 4(3):303–31310.1038/s44160-024-00679-2 ↗
41. Zhu H, Chen L, Sun B, Wang M, Li H, Stoddart JF, Huang F (2023) Applications of macrocycle-based solid-state host–guest chemistry. Nat Rev Chem 7(11):768–78210.1038/s41570-023-00531-9 ↗
42. Zhang T, Yu J, Deng Y, Tian N, Gao P (2015) Fast response ultraviolet photodetectors based on solution-processed ZnO nanocrystals. Sci China Technol Sci 58(8):1328–133210.1007/s11431-015-5870-8 ↗
43. Salih EY (2024) Opto-electrical evaluation of visible blind fast-response nanostructured SnO 2/Si photodetector. RSC Adv 14(38):27733–2774010.1039/D4RA05303F ↗
44. Yang R, Fan Y, Mei L, Shin HS, Voiry D, Lu Q, Li Ju, Zeng Z (2023) Synthesis of atomically thin sheets by the intercalation-based exfoliation of layered materials. Nat Synth 2(2):101–11810.1038/s44160-022-00232-z ↗
45. Chang L, Holmes MA, Waller M, Osterloh FE, Moulé AJ (2012) Calcium niobate nanosheets as a novel electron transport material for solution-processed multi-junction polymer solar cells. J Mater Chem 22(38):20443–2045010.1039/c2jm33351a ↗
46. Liang X, Zhang Y, Li D, Wen B, Jiang D, Chen M (2019) 2D/2D BiOCl/K+ Ca2Nb3O10− heterostructure with Z-scheme charge carrier transfer pathways for tetracycline degradation under simulated solar light. Appl Surf Sci 466:863–87310.1016/j.apsusc.2018.10.057 ↗
47. Ariga K, Yamauchi Y, Mori T, Hill JP (2013) 25th anniversary article: what can be done with the Langmuir-Blodgett method? Recent developments and its critical role in materials science. Adv Mater 25(45):6477–651210.1002/adma.201302283 ↗
48. Maleček T, Agnus G, Maroutian T, Horák L, Machovec P, Demange V ... Veis M (2023) Magneto-optical properties of textured La2/3 Sr1/3MnO3 thin films integrated on silicon via a Ca2Nb30 nanosheet layer. https://doi.org/10.48550/arXiv.2310.1645610.48550/arXiv.2310.16456 ↗
49. Chen J, Liu X, Zhu Q, Fang X, Xu W (2024) 2D Ca2Nb3O10 optoelectronic neuromorphic device for ultrasensitive UV‐C vision and encrypted communication. Adv Funct Mater. https://doi.org/10.1002/adfm.20240268410.1002/adfm.202402684 ↗
50. Sakai N, Sasaki T (2022) Guidelines for arranging 2D nanosheets into neatly tiled monolayer films by a spin-coating process. Langmuir 38(40):12399–1240710.1021/acs.langmuir.2c02211 ↗
51. Yano H, Sakai N, Ebina Y, Ma R, Osada M, Fujimoto K, Sasaki T (2021) Construction of multilayer films and superlattice-and mosaic-like heterostructures of 2D metal oxide nanosheets via a facile spin-coating process. ACS Appl Mater Interfaces 13(36):43258–4326510.1021/acsami.1c11463 ↗
52. Yang R, Mei L, Zhang Q, Fan Y, Shin HS, Voiry D, Zeng Z (2022) High-yield production of mono-or few-layer transition metal dichalcogenide nanosheets by an electrochemical lithium ion intercalation-based exfoliation method. Nat Protoc 17(2):358–37710.1038/s41596-021-00643-w ↗
53. Yang R, Mei L, Lin Z, Fan Y, Lim J, Guo J, Liu Y, Shin HS, Voiry D, Lu Q, Li Ju, Zeng Z (2024) Intercalation in 2D materials and in situ studies. Nat Rev Chem 8(6):410–43210.1038/s41570-024-00605-2 ↗
54. Matsuba K, Wang C, Saruwatari K, Uesusuki Y, Akatsuka K, Osada M, Ebina Y, Ma R, Sasaki T (2017) Neat monolayer tiling of molecularly thin two-dimensional materials in 1 min. Sci Adv 3(6):e170041410.1126/sciadv.1700414 ↗
55. Georgakilas V, Tiwari JN, Kemp KC, Perman JA, Bourlinos AB, Kim KS, Zboril R (2016) Noncovalent functionalization of graphene and graphene oxide for energy materials, biosensing, catalytic, and biomedical applications. Chem Rev 116(9):5464–551910.1021/acs.chemrev.5b00620 ↗
56. Zheng Y, Wang Y, Li Z, Yuan Z, Guo S, Lou Z, Han W, Shen G, Wang L (2023) MXene quantum dots/perovskite heterostructure enabling highly specific ultraviolet detection for skin prevention. Matter 6(2):506–52010.1016/j.matt.2022.11.020 ↗
57. Shen D, Jin Y, Zhang Z, Song R, Liu M, Li W, Duan X (2024) Recent advances in spin-coating precursor mediated chemical vapor deposition of two-dimensional transition metal dichalcogenides. Precision Chemistry 2(7):282–29910.1021/prechem.3c00115 ↗
58. Le PT, Ten Elshof JE, Koster G (2020) Shape control of Ca2Nb3O10 nanosheets: paving the way for monolithic integration of functional oxides with CMOS. ACS Appl Nano Mater 3(9):9487–949310.1021/acsanm.0c02137 ↗
59. Manguele JJ, Baudouin F, Cibert C, Domengès B, Demange V, Guilloux-Viry M, Poullain G (2020) Highly textured Pt thin film grown at very low temperature using Ca 2 Nb 3 O 10 nanosheets as seed layer. SN Appl Sci 2:1–1010.1007/s42452-020-2271-9 ↗
60. Nunnenkamp M et al (2024) Using a perovskite oxide buffer layer on Ca2Nb3O10 nanosheets for the epitaxial growth of Pb(Zr0.52Ti0.48)O3 for electrode-free thin films. Thin Solid Films 790:14019010.1016/j.tsf.2023.140190 ↗
61. Kurnosenko SA, Voytovich VV, Silyukov OI, Rodionov IA, Malygina EN, Zvereva IA (2023) Influence of HB2Nb3O10-based nanosheet photocatalysts (B= Ca, Sr) preparation method on hydrogen production efficiency. Catalysts 13(3):61410.3390/catal13030614 ↗
62. Hakamizadeh M, Afshar S, Tadjarodi A, Khajavian R, Fadaie MR, Bozorgi B (2014) Improving hydrogen production via water splitting over Pt/TiO2/activated carbon nanocomposite. Int J Hydrogen Energy 39(14):7262–726910.1016/j.ijhydene.2014.03.048 ↗
63. Ferreira CG, Sansierra C, Bernal-Texca F, Zhang M, Ros C, Martorell J (2024) Bias-free solar-to-hydrogen conversion in a BiVO4/PM6: Y6 compact tandem with optically balanced light absorption. ENERGY & ENVIRONMENTAL MATERIALS 7(4):e1267910.1002/eem2.12679 ↗
64. Xia L, Li J, Bai J, Li L, Chen S, Zhou B (2018) BiVO4 photoanode with exposed (040) facets for enhanced photoelectrochemical performance. Nano-Micro Lett 10(1):1110.1007/s40820-017-0163-3 ↗
65. Li L (2020) Porphyrins, graphitic carbon nitride and their hybrids for photocatalytic solar fuel generation.10.1039/D0NH00046A ↗
66. Maeda K, Mallouk TE (2009) Comparison of two-and three-layer restacked Dion-Jacobson phase niobate nanosheets as catalysts for photochemical hydrogen evolution. J Mater Chem 19(27):4813–481810.1039/b903692j ↗
67. Zhou Y, Wen T, Guo Y, Yang B, Wang Y (2016) Controllable doping of nitrogen and tetravalent niobium affords yellow and black calcium niobate nanosheets for enhanced photocatalytic hydrogen evolution. RSC Adv 6(69):64930–6493610.1039/C6RA11407E ↗
68. Sun Y, Wen B, Jiang D, Li D (2018) CdS nanoparticles decorated K+ Ca2Nb3O10− nanosheets with enhanced photocatalytic activity. Mater Lett 229:236–23910.1016/j.matlet.2018.07.026 ↗
69. Yim H, Yu SH, Yoo SY, Sung YE, Choi JW (2015) Li storage of calcium niobates for lithium ion batteries. J Nanosci Nanotechnol 15(10):8103–810710.1166/jnn.2015.11291 ↗
70. Torren AJVD, Yuan H, Liao Z, Elshof JET, Koster G, Huijben M, ... Aarts J (2019) Growing a LaAlO3/SrTiO3 heterostructure on Ca2Nb3O10 nanosheets. Sci Rep 9(1):1761710.1038/s41598-019-53438-1 ↗