journal article·2025-11Open access

Magnetic properties of CoFe$$2$$O$$4$$ nanoparticles: experimental characterization and numerical analysis using the Ising model

Luis Abraham García-Hernández, Cuauhtemoc Benixoo Guzmán-Hernández, Goldie Oza

Journal of Nanoparticle Research· Volume 27· Issue 11

Abstract

Abstract In this work, we synthesized superpara-magnetic cobalt ferrite (CoFe $$2$$ O $$4$$ ) magnetic nanoparticles using the co-precipitation method and performed a comprehensive structural and magnetic characterization. Structural characterization techniques, including X-ray diffraction, Raman spectroscopy, and HRTEM, confirmed the formation of an inverse spinel structure with a lattice parameter of $$a = 8.41$$ Å and an average crystallite size of $$D= 17.7\pm 6.5$$ nm. Raman peak fitting revealed broadened modes, consistent with phonon confinement effects. SQUID magnetometry confirmed superparamagnetic-like behavior of the nanoparticles at room temperature, characterized by low coercivity and remanence, with a blocking temperature of 210 K and saturation magnetization of $$Ms=51$$ emu/g. Complementing the experimental work, we implemented a two-dimensional Ising model through Monte Carlo simulations to analyze the magnetic response within the nanoparticle system.
Source: crossref · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Magnetic Properties and Synthesis of Ferrites · Magnetic properties of thin films · Iron oxide chemistry and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (24)

Show source-provided references
1. Coutinho TC, Malafatti JOD, Paris EC, Tardioli PW, Farinas CS (2020) Hydroxyapatite-$$\text{ CoFe}_2\text{ O}_4$$ magnetic nanoparticle composites for industrial enzyme immobilization, use, and recovery. ACS Appl Nano Mater 3(12):12334–12345. https://doi.org/10.1021/acsanm.0c0281110.1021/acsanm.0c02811 ↗
2. Materón EM, Miyazaki CM, Carr O, Joshi N, Picciani PH, Dalmaschio CJ, Davis F, Shimizu FM (2021) Magnetic nanoparticles in biomedical applications: a review. Appl Surface Sci Adv 6:100163. https://doi.org/10.1016/j.apsadv.2021.10016310.1016/j.apsadv.2021.100163 ↗
3. Moosavi S, Zakaria S, Chia CH, Gan S, Azahari NA, Kaco H (2017) Hydrothermal synthesis, magnetic properties and characterization of $$\text{ CoFe}2\text{ O}4$$ nanocrystals. Ceram Int 43(10):7889–7894. https://doi.org/10.1016/j.ceramint.2017.03.11010.1016/j.ceramint.2017.03.110 ↗
4. Moya C, Fraile Rodríguez A, Escoda-Torroella M, García del Muro M, Avula SRV, Piamonteze C, Batlle X, Labarta A (2020) Crucial role of the Co cations on the destabilization of the ferrimagnetic alignment in Co-ferrite nanoparticles with tunable structural defects. J Phys Chem C 125(1):691–701. https://doi.org/10.1021/acs.jpcc.0c0665710.1021/acs.jpcc.0c06657 ↗
5. Moya C, Morales MdP, Batlle X, Labarta A (2015) Tuning the magnetic properties of Co-ferrite nanoparticles through the 1,2-hexadecanediol concentration in the reaction mixture. Phys Chem Chem Phys 17(19):13143–13149. https://doi.org/10.1039/c5cp01052g10.1039/c5cp01052g ↗
6. Moya C, Salas G, Morales MdP, Batlle X, Labarta A (2015) Inducing glassy magnetism in Co-ferrite nanoparticles through crystalline nanostructure. J Mater Chem C 3(17):4522–4529. https://doi.org/10.1039/c4tc02889a10.1039/c4tc02889a ↗
7. García Hernández LA (2020) Light scattering and plasmonic response of Au–$$\text{ Fe}3\text{ O}4$$ nanoparticles. SN Appl Sci 2(11). https://doi.org/10.1007/s42452-020-03646-610.1007/s42452-020-03646-6 ↗
8. Briceño S, Brämer-Escamilla W, Silva P, Delgado GE, Plaza E, Palacios J, Cañizales E (2012) Effects of synthesis variables on the magnetic properties of $$\text{ CoFe}2\text{ O}4$$ nanoparticles. J Magn Magn Mater 324(18):2926–2931. https://doi.org/10.1016/j.jmmm.2012.04.05110.1016/j.jmmm.2012.04.051 ↗
9. Ai L, Jiang J (2010) Influence of annealing temperature on the formation, microstructure and magnetic properties of spinel nanocrystalline cobalt ferrites. Curr Appl Phys 10(1):284–288. https://doi.org/10.1016/j.cap.2009.06.00710.1016/j.cap.2009.06.007 ↗
10. Aghrich K, Abdellaoui M, Mamouni N, Bellaouchou A, Fekhaoui M, Hlil EK, Mounkachi O (2020) Experimental and first-principles study of the origin of the magnetic properties of $$\text{ CoFe}2\text{ O}4$$ spinel ferrite. Appl Phys A 126(12). https://doi.org/10.1007/s00339-020-04114-z10.1007/s00339-020-04114-z ↗
11. Naeinian N, Imani M, Tadjarodi A (2024) Mechanochemical synthesis of $$\text{ CoFe}2\text{ O}4/\text{Bi}2\text{ MoO}6$$ mixed metal oxide and study of its photocatalytic behavior. Mater Lett 355:135512. https://doi.org/10.1016/j.matlet.2023.13551210.1016/j.matlet.2023.135512 ↗
12. Anchal, Sarita, Palsaniya K, Priya, Kumari N, Dolia S, Alvi P, Choudhary B (2024) Tailoring quantum dots through citric acid modulation of $$\text{ CoFe}2\text{ O}4$$ ferrite. Mater Chem Phys 313:128820. https://doi.org/10.1016/j.matchemphys.2023.12882010.1016/j.matchemphys.2023.128820 ↗
13. Sarita, Anchal, Priya, Choudhary SR, Rulaniya MS, Kumar A, Dolia SN, Alvi PA, Choudhary BL (2024) Studies of structural, optical, and Raman analysis of Ni-substituted $$\text{ CoFe}2\text{ O}4$$. Phys Status Solidi A 221(18). https://doi.org/10.1002/pssa.20240008310.1002/pssa.202400083 ↗
14. Kumar CSSR (ed) Raman spectroscopy for nanomaterials characterization. Springer Berlin Heidelberg (2012). https://doi.org/10.1007/978-3-642-20620-710.1007/978-3-642-20620-7 ↗
15. Kurtan U, Topkaya R, Baykal A, Toprak M (2013) Temperature dependent magnetic properties of $$\text{ CoFe}2\text{ O}4/\text{CTAB }$$ nanocomposite synthesized by sol–gel auto-combustion technique. Ceram Int 39(6):6551–6558. https://doi.org/10.1016/j.ceramint.2013.01.08810.1016/j.ceramint.2013.01.088 ↗
16. Muscas G, Congiu F, Concas G, Cannas C, Mameli V, Yaacoub N, Hassan RS, Fiorani D, Slimani S, Peddis D (2022) The boundary between volume and surface-driven magnetic properties in spinel iron oxide nanoparticles. Nanoscale Res Lett 17(1). https://doi.org/10.1186/s11671-022-03737-w10.1186/s11671-022-03737-w ↗
17. Mund H, Ahuja B (2017) Structural and magnetic properties of Mg doped cobalt ferrite nano particles prepared by sol-gel method. Mater Res Bull 85:228–233. https://doi.org/10.1016/j.materresbull.2016.09.02710.1016/j.materresbull.2016.09.027 ↗
18. Sánchez EH, Vasilakaki M, Lee SS, Normile PS, Muscas G, Murgia M, Andersson MS, Singh G, Mathieu R, Nordblad P, Ricci PC, Peddis D, Trohidou KN, Nogués J, De Toro JA (2020) Simultaneous individual and dipolar collective properties in binary assemblies of magnetic nanoparticles. Chem Mater 32(3):969–981. https://doi.org/10.1021/acs.chemmater.9b0326810.1021/acs.chemmater.9b03268 ↗
19. Han F (2012) A modern course in the quantum theory of solids. World Scientific. https://doi.org/10.1142/855610.1142/8556 ↗
20. Xiao Y, Du J (2020) Superparamagnetic nanoparticles for biomedical applications. J Mater Chem B 8(3):354–367. https://doi.org/10.1039/c9tb01955c10.1039/c9tb01955c ↗
21. Peierls R (1936) On Ising’s model of ferromagnetism. Math Proc Cambridge Philos Soc 32(3):477–481. https://doi.org/10.1017/s030500410001917410.1017/s0305004100019174 ↗
22. Blundell SJ, Blundell KM (2009) Concepts in thermal physics. Oxford University PressOxford. https://doi.org/10.1093/acprof:oso/9780199562091.001.000110.1093/acprof:oso/9780199562091.001.0001 ↗
23. Coey JMD (2001) Magnetism and magnetic materials. Cambridge University Press. https://doi.org/10.1017/cbo978051184500010.1017/cbo9780511845000 ↗
24. Fan H, Li B, Shi Z, Zhao L, Wang K, Qiu D (2018) A fibrous morphology silica-$$\text{ CoFe}2\text{ O}4$$ nanocarrier for anti-cancer drug delivery. Ceram Int 44(2):2345–2350. https://doi.org/10.1016/j.ceramint.2017.10.20110.1016/j.ceramint.2017.10.201 ↗