journal article·2023-02

Three-dimensional open concave surface-enhanced Raman scattering sensor based on the SiO2/CNTs/AgNPs to detect the phenol red

Jianjun Ding, Li Ye, Tong Su, Naiyu Guo, Linbo Yu, Longxin Miao, Mian Cao, Chao Sun

Journal of Nanoparticle Research· Volume 25· Issue 2
Publisher page

Abstract

Surface-enhanced Raman scattering (SERS) features a unique fingerprint spectrum for fast and highly sensitive non-destructive detection without sample pretreatment. Aiming at the problem of few “hot spot” and uneven distribution of traditional SERS substrate, in this work, a surface-enhanced Raman substrate of silica/carbon nanotubes/silver nanoparticles (SiO2/CNTs/AgNPs) with high on all sides and low in the middle was synthesized by hydrothermal synthesis. The AgNPs were characterized by transmission electron microscopy (TEM), and the average diameter was 38 nm to 63 nm. The substrate exhibited high sensitivity, stability, and uniformity with a detection limit of 10−12 M for rhodamine 6G (R6G). Furthermore, we conducted an in-depth research on the enhancement contribution of the substrate by finite-difference time-domain (FDTD); the simulation results were in good agreement with the experimental results. Finally, the substrate was used for the detection of phenol red in water; the results showed that the Raman intensity was exponentially related to the concentration of phenol red solution with the coefficient of determination R2 = 0.99991, which provided a new method for detecting water pollutants. Graphical Abstract
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Gold and Silver Nanoparticles Synthesis and Applications · Advanced Nanomaterials in Catalysis · Advanced biosensing and bioanalysis techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (50)

Show source-provided references
1. Halomoan I, Yulizar Y, Surya RM, Apriandanu DOB (2022) Facile preparation of CuO-Gd2Ti2O7 using Acmella uliginosa leaf extract for photocatalytic degradation of malachite green. Mater Res Bull 150(Jun.):111726. https://doi.org/10.1016/j.materresbull.2021.11172610.1016/j.materresbull.2021.111726 ↗
2. Hanafi MF, Sapawe N (2020) A review on the water problem associate with organic pollutants derived from phenol, methyl orange, and remazol brilliant blue dyes. Mater Today: Proc 31(12):A141–A150. https://doi.org/10.1016/j.matpr.2021.01.25810.1016/j.matpr.2021.01.258 ↗
3. Burstein E, Chen YJ, Chen CY, Lundquist S, Tosatti E (1979) “Giant” Raman scattering by adsorbed molecules on metal surfaces. Solid State Commun 29(8):567–570. https://doi.org/10.1016/0038-1098(79)90665-310.1016/0038-1098(79)90665-3 ↗
4. Chen CY (1980) Giant Raman scattering by molecules at metal-island films. Phys Rev Lett 45(15):1287–1291. https://doi.org/10.1103/PhysRevLett.45.128710.1103/PhysRevLett.45.1287 ↗
5. Ding SY, You EM, Tian ZQ, Moskovits M (2017) Electromagnetic theories of surface-enhanced Raman spectroscopy. Chem Soc Rev 46(13):4042–4076. https://doi.org/10.1039/C7CS00238F10.1039/C7CS00238F ↗
6. Shan Y, Yang Y, Cao Y, Fu C, Huang Z (2016) Synthesis of wheatear-like ZnO nanoarrays decorated with Ag nanoparticles and its improved SERS performance through hydrogenation. Nanotechnology 27(14):145502. https://doi.org/10.1088/0957-4484/27/14/14550210.1088/0957-4484/27/14/145502 ↗
7. Wei H, Xu H (2013) Hot spots in different metal nanostructures for plasmon-enhanced Raman spectroscopy. Nanoscale 5(22):10794–10805. https://doi.org/10.1039/c3nr02924g10.1039/c3nr02924g ↗
8. Ge J, Li Y, Wang J, Pu Y, Xue W, Liu X (2016) Green synthesis of graphene quantum dots and silver nanoparticles compounds with excellent surface enhanced Raman scattering performance. J Alloy Comp 663:166–171. https://doi.org/10.1016/j.jallcom.2015.12.05510.1016/j.jallcom.2015.12.055 ↗
9. Tong L, Xu H, Kaell M (2014) Nanogaps for SERS applications. Mrs. Bulletin 39(2):163–168. https://doi.org/10.1557/mrs.2014.210.1557/mrs.2014.2 ↗
10. Cao W, Jiang L, Hu J, Wang A, Li X, Lu Y (2018) Optical field enhancement in Au nanoparticle-decorated nanorod arrays prepared by femtosecond laser and their tunable surface-enhanced Raman scattering applications. ACS Appl Mater Interfaces 10(1):1297–1305. https://doi.org/10.1021/acsami.7b1324110.1021/acsami.7b13241 ↗
11. Chen B, Meng G, Huang Q, Huang Z, Xu Q, Zhu C, Qian Y, Ding Y (2014) Green synthesis of large-scale highly ordered Core@Shell nanoporous Au@Ag nanorod arrays as sensitive and reproducible 3D SERS substrates. Acs Appl Mater Interfaces 6(18):15667–15675. https://doi.org/10.1021/am505474n10.1021/am505474n ↗
12. Ru ECL, Etchegoin PG (2019) Principles of surface-enhanced Raman spectroscopy. Elsevier Sci, Holland. https://doi.org/10.1016/B978-0-444-52779-0.00024-610.1016/B978-0-444-52779-0.00024-6 ↗
13. Kim H, Kosuda KM, Duyne RPV, Stair PC (2010) Resonance Raman and surface- and tip-enhanced Raman spectroscopy methods to study solid catalysts and heterogeneous catalytic reactions. Chem Soc Rev 39(12):4820–4844. https://doi.org/10.1002/chin.20111527410.1002/chin.201115274 ↗
14. Li H, Yin H, Dai H, Lee HK, Cui Y, Sun F, Zhang Y, An Q (2021) Enriching surface-enhanced Raman Spectral signatures in combined static and plasmonic electrical fields in self-powered substrates. Nano Energy 92:106737. https://doi.org/10.1016/j.nanoen.2021.10673710.1016/j.nanoen.2021.106737 ↗
15. Wang Q, Lian S, Guo C, Gao X, Dou Y, Song C, Lin J (2022) The chemical adsorption effect of surface enhanced Raman spectroscopy of nitrobenzene and aniline using the density functional theory. Spectrochim Acta A Mol Biomol Spectrosc 279:121428. https://doi.org/10.1016/j.saa.2022.12142810.1016/j.saa.2022.121428 ↗
16. Brown RJC, Wang J, Tantra RE, Yardley RE, Milton MJT (2006) Electromagnetic modelling of Raman enhancement from nanoscale substrates: a route to estimation of the magnitude of the chemical enhancement mechanism in SERS. Faraday Discuss 132(2):201–213. https://doi.org/10.1039/B506751K10.1039/B506751K ↗
17. Huang S, He B, Yan X, Khan I, Wang J, Gao M, Lan J, Li S, Kang J (2018) Hierarchical ZnO/Si nanowire arrays as an effective substrate for surface-enhanced Raman scattering application. Sens Actuators B-Chem 273:48–55. https://doi.org/10.1016/j.snb.2018.06.00310.1016/j.snb.2018.06.003 ↗
18. Zhang X, Zheng Y, Liu X, Lu W, Dai J, Lei D, MacFarlane DR (2015) Hierarchical porous plasmonic metamaterials for reproducible ultrasensitive surface-enhanced Raman spectroscopy. Adv Mater 27(6):1090–1096. https://doi.org/10.1002/adma.20140410710.1002/adma.201404107 ↗
19. Macias-Montero M, Peláez RJ, RicoVJ SZ, Midgley P, Afonso CN, González-Elipe AR, Borras A (2015) Laser treatment of Ag@ZnO nanorods as long-life-span SERS surfaces. Acs Appl Mater Interfaces 7(4):2331–2339. https://doi.org/10.1021/am506622x10.1021/am506622x ↗
20. Ogundare SA, Zyl WEV (2019) A review of cellulose-based substrates for SERS: fundamentals, design principles, applications. Cellulose 26(11):6489–6528. https://doi.org/10.1007/s10570-019-02580-010.1007/s10570-019-02580-0 ↗
21. Restaino SM, White IM (2019) A critical review of flexible and porous SERS sensors for analytical chemistry at the point-of-sample. Anal Chim Acta 1060:17–29. https://doi.org/10.1016/j.aca.2018.11.05710.1016/j.aca.2018.11.057 ↗
22. Wang Y, Li M, Wang D, Han C, Xu K (2020) Fabrication of highly uniform Ag nanoparticle-TiO2 nanosheets array hybrid as reusable SERS substrates. Colloids Interface Sci Commun 39:100324. https://doi.org/10.1016/j.colcom.2020.10032410.1016/j.colcom.2020.100324 ↗
23. Luo X, Liu W, Chen C, Jiang G, Zhong M (2021) Femtosecond laser micro-nano structured Ag SERS substrates with unique sensitivity, uniformity and stability for food safety evaluation. Opt Laser Technol 139(7):106969. https://doi.org/10.1016/j.optlastec.2021.10696910.1016/j.optlastec.2021.106969 ↗
24. Tran TH, Nguyen TMA, Dao VPT, Sai CD, Bach TC, Pham NH, Ngac AB, Pham VT, Tran TKC, Cheong H, Nguyen VT (2022) Highly sensitive characteristic of surface enhanced Raman scattering for CuO/Au core/shell nanowires substrate. Ceram Inte 48(3):3199–3205. https://doi.org/10.1016/j.ceramint.2021.10.09310.1016/j.ceramint.2021.10.093 ↗
25. Qian XM, Nie SM (2008) Single-molecule and single-nanoparticle SERS: from fundamental mechanisms to biomedical applications. Chem Soc Rev 37(5):912–920. https://doi.org/10.1039/B708839f10.1039/B708839f ↗
26. Tódor IS, Szabó L, Marisca OT, Chis V, Leopold N (2014) Gold nanoparticle assemblies of controllable size obtained by hydroxylamine reduction at room temperature. J Nanopart Res 16(12):1–8. https://doi.org/10.1007/s11051-014-2740-410.1007/s11051-014-2740-4 ↗
27. Du CL, You Y, Shen ZX (2011) Polarized SERS study of an individual Ag nanowire with bulb humps. Opt Commun 284(24):5844–5846. https://doi.org/10.1016/j.optcom.2011.08.07210.1016/j.optcom.2011.08.072 ↗
28. Fromm DP, Sundaramurthy A, Kinkhabwala A, Schuck PJ, Kino GS, Moerner WE (2006) Exploring the chemical enhancement for surface-enhanced Raman scattering with Au bowtie nanoantennas. J Chem Phys 124(6):61101. https://doi.org/10.1063/1.216764910.1063/1.2167649 ↗
29. Zhou J, Zhang W, Poe D, Qin J, Fornara A, Zhang Y, Ramadan UA, Muhammed M, Pyykkö I (2010) MRI manifestation of novel superparamagnetic iron oxide nanoparticles in the rat inner ear. Nanomedicine 5(5):739–754. https://doi.org/10.2217/nnm.10.4510.2217/nnm.10.45 ↗
30. Chen M, Phang IY, Lee MR, Yang JKW, Ling XY (2013) Layer-by-layer assembly of Ag nanowires into 3D woodpile-like structures to achieve high density “hot spots” for surface-enhanced Raman scattering. Langmuir 29(23):7061–7069. https://doi.org/10.1021/la401210810.1021/la4012108 ↗
31. Udayabhaskararao T, Altantzis T, Houben L, Coronado-Puchau M, Langer J, Popovitz-Biro R, Liz-Marzán LM, Vuković L, Král P, Bals S, Klajn R (2017) Tunable porous nanoallotropes prepared by post-assembly etching of binary nanoparticle superlattices. Science 358(6362):514–518. https://doi.org/10.1126/science.aan604610.1126/science.aan6046 ↗
32. Tao Q, Li S, Zhang QY, Kang DW, Yang JS, Qiu WW, Liu K (2014) Controlled growth of ZnO nanorods on textured silicon wafer and the application for highly effective and recyclable SERS substrate by decorating Ag nanoparticles. Mater Res Bull 54(jun.):6–12. https://doi.org/10.1016/j.materresbull.2014.02.02710.1016/j.materresbull.2014.02.027 ↗
33. Kaushik V, Kagdada HK, Singh DK, Pathak S (2022) Enhancement of SERS effect in graphene-silver hybrids. Appl Surf Sci 574:151724. https://doi.org/10.1016/j.apsusc.2021.15172410.1016/j.apsusc.2021.151724 ↗
34. Wang J, Zhao Y, Huang H, Cong T, Zhang H, Liu K, Pan L (2020) Facile synthesis of hybrid silver/porous carbon black substrate for surface-enhanced Raman scattering. Appl Surf Sci 527(18):146948. https://doi.org/10.1016/j.apsusc.2020.14694810.1016/j.apsusc.2020.146948 ↗
35. Li H, Wang J, Wang X, Yu H, Ji L, Zhou T, Liu C, Che G, Wang D (2022) A high-performance SERS imprinted membrane based on Ag/CNTs for selective detection of spiramycin. Spectrochim Acta A Mol Biomol 281:121587. https://doi.org/10.1016/j.saa.2022.12158710.1016/j.saa.2022.121587 ↗
36. Jiang WF, Zhang YF, Wang YS, Xu L, Li XJ (2011) SERS activity of Au nanoparticles coated on an array of carbon nanotube nested into silicon nanoporous pillar. Appl Surf Sci 258(5):1662–1665. https://doi.org/10.1016/j.apsusc.2011.09.11410.1016/j.apsusc.2011.09.114 ↗
37. Liu H, Li Y, Dykes J, Gilliam T, Burnham K, Chopra N (2018) Manipulating the functionalization surface of graphene-encapsulated gold nanoparticles with single-walled carbon nanotubes for SERS sensing. Carbon 140:306–313. https://doi.org/10.1016/j.carbon.2018.08.06810.1016/j.carbon.2018.08.068 ↗
38. Mei H, Zhao X, Bai S, Li Q, Xia J, Bai H, Cheng L (2018) Tuning SERS properties of pattern-based MWNTs-AuNPs substrates by adjustment of the pattern spacings. Carbon 136:38–45. https://doi.org/10.1016/j.carbon.2018.04.05410.1016/j.carbon.2018.04.054 ↗
39. Liu C, Wang L, Guo Y, Gao X, Xu Y, Wei Q, Man B, Yang C (2019) Suspended 3D AgNPs/CNT nanohybrids for the SERS application. Appl Surf Sci 487:1077–1083. https://doi.org/10.1016/j.apsusc.2019.05.17910.1016/j.apsusc.2019.05.179 ↗
40. Yu D, Xu L, Zhang H, Li J, Wang W, Yang L, Jiang X, Zhao B (2022) A new semiconductor-based SERS substrate with enhanced charge collection and improved carrier separation: CuO/TiO2 p-n heterojunction. Chin Chem Lett 107771. https://doi.org/10.1016/j.cclet.2022.10777110.1016/j.cclet.2022.107771 ↗
41. Shao Q, Zhang X, Liang P, Chen Q, Qi X, Zou M (2022) Fabrication of magnetic Au/Fe3O4/MIL-101(Cr) (AF-MIL) as sensitive surface-enhanced Raman spectroscopy (SERS) platform for trace detection of antibiotics residue. Appl Surf Sci 596:153550. https://doi.org/10.1016/j.apsusc.2022.15355010.1016/j.apsusc.2022.153550 ↗
42. Cui X, Dong L, Zhang W, Wu W, Tang Y, Erni D (2010) Numerical investigations of a multi-walled carbon nanotube-based multi-segmented optical antenna. Appl Phys B 101(3):601–609. https://doi.org/10.1007/s00340-010-4220-610.1007/s00340-010-4220-6 ↗
43. Vernon KC, Davis TJ, Scholes FH, Gómez DE, Lau D (2010) Physical mechanisms behind the SERS enhancement of pyramidal pit substrates. J Raman Spectrosc 41(10):1106–1111. https://doi.org/10.1002/jrs.255710.1002/jrs.2557 ↗
44. Makaryan T, Esconjauregui S, Goncalves M, Yang J, Sugime H, Nille D, Renganathan PR, Goldberg-Oppenheimer P, Robertson J (2014) Hybrids of carbon nanotube forests and gold nanoparticles for improved surface plasmon manipulation. ACS Appl Material 6(8):5344–5349. https://doi.org/10.1021/am501863g10.1021/am501863g ↗
45. Durairaj V, Wester N, Etula J, Laurila T, Lehtonen J, Rojas OJ, Pahimanolis N, Koskinen J (2019) Multi-walled carbon nanotubes/nanofibrillar cellulose/Nafion composite-modified tetrahedral amorphous carbon electrodes for selective dopamine detection. J Phys Chem C 123(40):24826–24836. https://doi.org/10.1021/acs.jpcc.9b0553710.1021/acs.jpcc.9b05537 ↗
46. Ma Q, Wang Y, Jia J, Xiang Y (2018) Colorimetric aptasensors for determination of tobramycin in milk and chicken eggs based on DNA and gold nanoparticles. Food Chem 249(2018):98–103. https://doi.org/10.1016/j.foodchem.2018.01.02210.1016/j.foodchem.2018.01.022 ↗
47. Liu J, Jiang P, He C, Jiang X, Lu L (2018) Preparation and characterization of Ag@C composites with hexagon silver core and controllable carbon shell for surface-enhanced Raman scattering. J Mater Sci 53:3443–3454. https://doi.org/10.1007/s10853-017-1801-310.1007/s10853-017-1801-3 ↗
48. Tsai YC, Hsu PC, Lin YW, Wu TM (2009) Silver nanoparticles in multiwalled carbon nanotube-Nafion for surface-enhanced Raman scattering chemical sensor. Sensor Actuat B-Chem 138(1):5–8. https://doi.org/10.1016/j.snb.2009.01.00910.1016/j.snb.2009.01.009 ↗
49. Lee MK, Seo J, Cho SJ, Jo Y, Kim S, Kang Y, Lee H (2012) Novel 3D arrays of gold nanostructures on suspended platinum-coated carbon nanotubes as surface-enhanced Raman scattering substrates. Mater 81(3):9–12. https://doi.org/10.1016/j.matlet.2012.04.12410.1016/j.matlet.2012.04.124 ↗
50. Zhang J, Zhang X, Chen S, Gong T, Zhu Y (2016) Surface-enhanced Raman scattering properties of multi-walled carbon nanotubes arrays-Ag nanoparticles. Carbon 100:395–407. https://doi.org/10.1016/j.carbon.2016.01.02510.1016/j.carbon.2016.01.025 ↗