journal article·2020-06

Li2CoTi3O8 and its composite nanofibers as high performance and long cycle lithium ion electrode materials

Yuzhou Liu, Shuiping Huang, Chao Wang, Nan Gao, Xiaoyang Qiu, Xing Li

Journal of Nanoparticle Research· Volume 22· Issue 6
Publisher page

Abstract

In this work, Li2CoTi3O8 nanofibers and Li2CoTi3O8·CoTiO3·TiO2 (LCT) composite nanofibers as anode materials in lithium-ion batteries (LIBs) were successfully prepared by a traditional electrospinning technology, and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), energy-dispersive spectrometer (EDS), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), and mappings. XRD confirms that the composite materials lattice planes well correspond to the patterns of Li2CoTi3O8, CoTiO3, and TiO2, respectively. SEM and TEM exhibits the fabricated composites are one-dimensional nanofibers with the diameter of 250~300 nm and 150~200 nm after annealing, respectively. The electrochemical properties of the materials for LIBs are investigated to indicate that the (LCT) composite nanofibers hold high reversible capacity of 201.68 mAh g−1 after 120 cycles and high rate capability at different current densities.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Extraction and Separation Processes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (41)

Show source-provided references
1. Ahn D, Xiao XC (2011) Extended lithium titanate cycling potential window with near zero capacity loss. Electrochem Commun 13:796–79910.1016/j.elecom.2011.05.005 ↗
2. Bhardwaj N, Kundu SC (2010) Electrospinning: a fascinating fiber fabrication technique. Biotechnol Adv 28:325–34710.1016/j.biotechadv.2010.01.004 ↗
3. Cheng Z, Hu Y, Wu K, Xing Y, Pan P, Jiang L, Mao J, Ni C, Wang Z, Zhang M, Zhang Y, Gu X, Zhang X (2020) Si/TiO2/Ti2O3 composite carbon nanofiber by one-step heat treatment with highly enhanced ion/electron diffusion rates for next-generation lithium-ion batteries. Electrochim Acta 337:13578910.1016/j.electacta.2020.135789 ↗
4. Cusenza M, Bobba S, Ardente F, Cellura M, Persio F (2019) Energy and environmental assessment of a traction lithium-ion battery pack for plug-in hybrid electric vehicles. J Clean Prod 215:634–64910.1016/j.jclepro.2019.01.056 ↗
5. Goriparti S, Miele E, Angelis F, Fabrizio E, Zaccaria P, Capigliaa C (2014) Review on recent progress of nanostructured anode materials for Li-ion batteries. J Power Sources 257:421–44310.1016/j.jpowsour.2013.11.103 ↗
6. Han Y, Huang GY, Xu SM (2019) Structural reorganization-based nanomaterials as anodes for lithium-ion batteries: design, preparation, and performance. Small 16:190284110.1002/smll.201902841 ↗
7. He ZX, Jiang YQ, Zhu J, Li YH, Jiang Z, Zhou HZ, Meng W, Wang L, Dai L (2017) Boosting the performance of LiTi2(PO4)3/C anode for aqueous lithium ion battery by Sn doping on Ti sites. J Alloys Compd 731:32–3810.1016/j.jallcom.2017.10.038 ↗
8. Hou L, Qin X, Gao XJ, Guo T, Li X, Li J (2018) Zr−doped Li4Ti5O12 anode materials with high specific capacity for lithium-ion batteries. J Alloys Compd 774:38–4510.1016/j.jallcom.2018.09.364 ↗
9. Huang B, Pan Z, Su X, An L (2018) Recycling of lithium-ion batteries: recent advances and perspectives. J Power Sources 399:274–28610.1016/j.jpowsour.2018.07.116 ↗
10. Huff L, Tavassol H, Esbenshade J, Xing WT, Chiang YM, Gewirth A (2016) Identification of Li-ion battery SEI compounds through 7Li and 13C solid-state MAS NMR spectroscopy and MALDI-TOF mass spectrometry. ACS Appl Mater Interfaces 8:371–38010.1021/acsami.5b08902 ↗
11. Jeong J, Junge D, Shin E, Oh E (2014) Boron-doped TiO2 anode materials for high-rate lithium ion batteries. J Alloys Compd 604:226–23210.1016/j.jallcom.2014.03.069 ↗
12. Jung JW, Lee C, Yu S, Kim I (2015) Electrospun nanofibers as a platform for advanced secondary batteries: a comprehensive review. J Mater Chem A 10:703–750
13. Kamali A, Fray D (2015) Electrochemical interaction between graphite and molten salts to produce nanotubes, nanoparticles, graphene and nanodiamonds. J Mater Sci 51:569–57610.1007/s10853-015-9340-2 ↗
14. Lao MM, Qian SS, Yu HX, Yan L, Li P, Lin XT, Long NB, Shui M, Shu J (2016) Enhanced electrochemical properties of Mg2+ doped Li2Na2Ti6O14 anode material for lithium-ion batteries. Electrochim Acta 2016(196):642–65210.1016/j.electacta.2016.03.035 ↗
15. Leng MZ, Bi JQ, Wang WL, Liu R, Xia C (2019) Synthesis and characterization of Ru doped NaNi0.5Mn0.3Ti0.2O2 cathode material with improved electrochemical performance for sodium-ion batteries. Ionics 25:1105–111510.1007/s11581-018-2830-x ↗
16. Liu SY, Fan CY, Wang HC, Zhang JP, Wu XL (2017) Electrochemical in situ formation of a stable Ti-based skeleton for improved Li-storage properties: a case study of porous CoTiO3 nanofibers. Chem Eur J 23:8712–871810.1002/chem.201700984 ↗
17. Liu H, Wu XN, Guo EY, Lu QF (2019a) Tailored synthesis of coral-like CoTiO3/Co3O4/TiO2 nanobelts with superior Lithium storage capability. Energy Technol 8:190077410.1002/ente.201900774 ↗
18. Liu HD, Zhu ZY, Huang J, He X, Chen Y, Zhang R, Lin RQ, Li YJ, Yu S, Xing X, Yan QZ, Li XG, Frost M, An K, Feng J, Kostecki R, Xin HL, Ong S, Liu P (2019b) Elucidating the limit of Li insertion into the spinel Li4Ti5O12. ACS Mater Lett 1:96–10210.1021/acsmaterialslett.9b00099 ↗
19. Ouyang CY, Zhong ZY, Lei MS (2007) Ab initio studies of structural and electronic properties of Li4Ti5O12 spinel. Electrochem Commun 9:1107–111210.1016/j.elecom.2007.01.013 ↗
20. Railey P, Song Y, Liu TY (2017) Metal organic frameworks with immobilized nanoparticles: synthesis and applications in photocatalytic hydrogen generation and energy storage. Mater Res Bull 96:385–39410.1016/j.materresbull.2017.04.020 ↗
21. Sandhya C, John P, Gouri C (2014) Lithium titanate as anode material for lithium-ion cells: a review. Ionics 20:601–62010.1007/s11581-014-1113-4 ↗
22. Serife E, Stojanovska E, Simon B, Kilic A (2015) A review of nanofibrous structures in lithium ion batteries. J Power Sources 300:199–21510.1016/j.jpowsour.2015.09.059 ↗
23. Shi JM, Liu GZ, Weng W, Cai LT, Zhang Q, Wu JH, Xu XX, Yao XY (2020) Co3S4@Li7P3S11 hexagonal platelets as cathodes with superior interfacial contact for all-solid-state lithium batteries. ACS Appl Mater Interfaces 12:14079–1408610.1021/acsami.0c02085 ↗
24. Simon G, Goswami T (2011) Improving anodes for lithium ion batteries. Metall Mater Trans A 42:231–23810.1007/s11661-010-0438-5 ↗
25. Tian BB, Xiang HF, Zhang L, Wang HH (2012) Effect of Nb-doping on electrochemical stability of Li4Ti5O12 discharged to 0 V. J Solid State Electrochem 16:205–21110.1007/s10008-011-1305-z ↗
26. Tojo T, Kawashiri S, Tsuda T, Kadowaki M, Inada R, Sakuraib Y (2019) Electrochemical performance of single Li4Ti5O12 particle for lithium ion battery anode. J Electroanal Chem 836:24–2910.1016/j.jelechem.2019.01.061 ↗
27. Trong L, Thao T, Dinh N (2015) Characterization of the Li-ionic conductivity of La(2/3−x)Li3xTiO3 ceramics used for all-solid-state batteries. Solid State Ionics 278:228–23210.1016/j.ssi.2015.05.027 ↗
28. Wang L, Xiao QZ, Li ZH, Lei GT, Wu LJ, Zhang P, Mao J (2012) Synthesis of Li2CoTi3O8 fibers and their application to lithium-ion batteries. Electrochim Acta 77:77–8210.1016/j.electacta.2012.05.072 ↗
29. Wang J, Zhao HL, Shen YN, Du ZH, Chen XM, Xia Q (2013) Structure, stoichiometry, and electrochemical performance of Li2CoTi3O8 as an anode material for lithium-ion batteries. Chempluschem 78:1530–153510.1002/cplu.201300235 ↗
30. Wang J, Shen LF, Li HS, Ding B, Nie P, Dou H, Zhang XG (2014) Mesoporous Li4Ti5O12/carbon nanofibers for high-rate lithium-ion batteries. J Alloys Compd 587:171–17610.1016/j.jallcom.2013.10.134 ↗
31. Wang ZY, Xiong FY, Tao HZ, Yue YZ (2020) Revealing the role of the amorphous phase in Na0.74CoO2/C/N composite cathode. J Alloys Compd 815:15261610.1016/j.jallcom.2019.152616 ↗
32. Xu JQ, Thomas H, Francis R, Lum K, Wang JW, Liang B (2007) A review of processes and technologies for the recycling of lithium-ion secondary batteries. J Power Sources 177:512–52710.1016/j.jpowsour.2007.11.074 ↗
33. Xu HH, Sun YM, Luo W, Chen CJ, Liu Y, Huang YH (2014) Highly porous Li4Ti5O 12/C nanofibers for ultrafast electrochemical energy storage. Nano Energy 10:163–17110.1016/j.nanoen.2014.09.003 ↗
34. Xu M, Han L, Han YJ, Yu Y, Zhai JF, Dong SJ (2015) Porous CoP concave polyhedron electrocatalysts synthesized from metal-organic frameworks with enhanced electrochemical properties for hydrogen evolution. J Mater Chem A 3:21471–2147710.1039/C5TA05018A ↗
35. Yi TF, Yang SY, Li XY, Yao JH, Zhu YR, Zhu RS (2014a) Sub-micrometric Li4−xNaxTi5O12 (0≤x≤0.2) spinel as anode material exhibiting high rate capability. J Power Sources 246:505–51110.1016/j.jpowsour.2013.08.005 ↗
36. Yi TF, Yang SY, Zhu YR, Ye M, Xie Y, Zhu RS (2014b) Enhanced rate performance of Li4Ti5O12 anode material by ethanol-assisted hydrothermal synthesis for lithium-ion battery. Ceram Int 40:9853–985810.1016/j.ceramint.2014.02.077 ↗
37. Yuan T, Yu X, Cai R, Zhou YK, Shao ZP (2010) Synthesis of pristine and carbon-coated Li4Ti5O12 and their low-temperature electrochemical performance. J Power Sources 195:4997–500410.1016/j.jpowsour.2010.02.020 ↗
38. Zeng LC, Qiu L, Cheng HM (2019) Towards the practical use of flexible lithium ion batteries. Energy Storage Mater 23:434–43810.1016/j.ensm.2019.04.019 ↗
39. Zhang QY, Lu HS, Zhong HX, Yan XD, Ouyang CY, Zhang LZ (2015) W6+ & Br− codoped Li4Ti5O12 anode with super rate performances for Li-ion batteries. J Mater Chem A 3:13706–1371610.1039/C5TA02784E ↗
40. Zhang PC, Yuan T, Pang YP, Peng CX, Yang JH, Ma ZF, Zheng SY (2019) Influence of current density on graphite anode failure in lithium-ion batteries. J Electrochem Soc 166:A5489–A549510.1149/2.0701903jes ↗
41. Zhao Z, Xu YL, Ji MD, Zhang H (2013) Synthesis and electrochemical performance of F− doped Li4Ti5O12 for lithium-ion batteries. Electrochim Acta 109:645–65010.1016/j.electacta.2013.07.164 ↗