journal article·2023-10

CNT grown in situ from iron ore tailings: simple dispersion and environmental sustainability

Glauber Zerbini Costal, Bianca Rafaela da Silva Calderón-Morales, Jaqueline do Carmo Lima Carvalho, Edelma Eleto da Silva, Evandro Augusto de Morais, Lílian Fernandes Machado, Carlos Augusto de Souza Oliveira, Francisco Moura Filho, Viviany Geraldo

Journal of Nanoparticle Research· Volume 25· Issue 10
Publisher page

Abstract

Applications for carbon nanotubes (CNT) and the reuse of iron ore tailings (IOT) have been explored in the literature about nanostructured cementitious materials. Reinforced iron ore tailings (R-IOT) was produced growing CNT from an external catalyst directly on particles of IOT, regardless of its iron content. In this work, analyses by infrared spectroscopy detail the chemical bonds between IOT grains and the external catalyst. Also, different in situ CNT concentrations (0.05%, 0.2%, and 0.8%) in R-IOT were used for preparing a mortar which 25% of its aggregate’s composition is reused IOT. R-IOT increased flexural strength (up to 29% with 0.8% CNT) and delivered better reinforcement efficiency (up to 60%) when compared to functionalized CNT. The electrical conductivity of the nanostructured composites was also higher (up to 370%) when compared nanostructured mortar to the mortar prepared from plain IOT. Contrary to the chemical CNT functionalization process to dispersion, the use of R-IOT to produce mortar is an easy and simple process that does not require additives, admixtures, surfactants, or any other additional chemical procedure. In terms of circular economy, the process combines innovation and sustainability since it reinserts IOT in the productive flow, representing an efficient application for this residue of mining activities. Graphical abstract
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Smart Materials for Construction · Concrete and Cement Materials Research · Innovative concrete reinforcement materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (48)

Show source-provided references
1. Ferreira H, Leite MGP (2015) A Life Cycle Assessment study of iron ore mining. J Clean Prod 108:1081–1091. https://doi.org/10.1016/j.jclepro.2015.05.14010.1016/j.jclepro.2015.05.140 ↗
2. Mendes Protasio FN, Ribeiro de Avillez R, Letichevsky S, de Andrade SF (2021) The use of iron ore tailings obtained from the Germano dam in the production of a sustainable concrete. J Clean Prod 278:123929. https://doi.org/10.1016/j.jclepro.2020.12392910.1016/j.jclepro.2020.123929 ↗
3. Carmignano O, Vieira S, Teixeira AP et al (2021) Iron ore tailings: characterization and applications. J Braz Chem Soc. https://doi.org/10.21577/0103-5053.2021010010.21577/0103-5053.20210100 ↗
4. Kinnunen PH-M, Kaksonen AH (2019) Towards circular economy in mining: opportunities and bottlenecks for tailings valorization. J Clean Prod 228:153–160. https://doi.org/10.1016/j.jclepro.2019.04.17110.1016/j.jclepro.2019.04.171 ↗
5. Tang C, Li K, Ni W, Fan D (2019) Recovering iron from iron ore tailings and preparing concrete composite admixtures. Minerals 9:232. https://doi.org/10.3390/min904023210.3390/min9040232 ↗
6. Lèbre É, Corder G, Golev A (2017) The role of the mining industry in a circular economy: a framework for resource management at the mine site level. J Ind Ecol 21:662–672. https://doi.org/10.1111/jiec.1259610.1111/jiec.12596 ↗
7. Yao G, Wang Q, Wang Z et al (2020) Activation of hydration properties of iron ore tailings and their application as supplementary cementitious materials in cement. Powder Technol 360:863–871. https://doi.org/10.1016/j.powtec.2019.11.00210.1016/j.powtec.2019.11.002 ↗
8. Zhao J, Ni K, Su Y, Shi Y (2021) An evaluation of iron ore tailings characteristics and iron ore tailings concrete properties. Constr Build Mater 286:122968. https://doi.org/10.1016/j.conbuildmat.2021.12296810.1016/j.conbuildmat.2021.122968 ↗
9. Zhang N, Tang B, Liu X (2021) Cementitious activity of iron ore tailing and its utilization in cementitious materials, bricks and concrete. Constr Build Mater 288:123022. https://doi.org/10.1016/j.conbuildmat.2021.12302210.1016/j.conbuildmat.2021.123022 ↗
10. Magalhães LF, França S, Oliveira M et al (2020) Iron ore tailings as a supplementary cementitious material in the production of pigmented cements. J Clean Prod 274:123260. https://doi.org/10.1016/j.jclepro.2020.12326010.1016/j.jclepro.2020.123260 ↗
11. Vilaça ASI, Simão L, Montedo ORK et al (2022) Waste valorization of iron ore tailings in Brazil: assessment metrics from a circular economy perspective. Resour Policy 75:102477. https://doi.org/10.1016/j.resourpol.2021.10247710.1016/j.resourpol.2021.102477 ↗
12. Fontes WC, Franco de Carvalho JM, Andrade LCR et al (2019) Assessment of the use potential of iron ore tailings in the manufacture of ceramic tiles: from tailings-dams to “brown porcelain”. Constr Build Mater 206:111–121. https://doi.org/10.1016/j.conbuildmat.2019.02.05210.1016/j.conbuildmat.2019.02.052 ↗
13. Konsta-Gdoutos MS, Aza CA (2014) Self sensing carbon nanotube (CNT) and nanofiber (CNF) cementitious composites for real time damage assessment in smart structures. Cem Concr Compos 53:162–169. https://doi.org/10.1016/j.cemconcomp.2014.07.00310.1016/j.cemconcomp.2014.07.003 ↗
14. Elaqra HA, Elmasry IH, Tabasi AM et al (2021) Effect of water-to-cement ratio and soaking time of waste glass powder on the behaviour of green concrete. Constr Build Mater 299:124285. https://doi.org/10.1016/j.conbuildmat.2021.12428510.1016/j.conbuildmat.2021.124285 ↗
15. Carneiro LRS, Garcia DCS, Costa MCF et al (2018) Evaluation of the pozzolanicity of nanostructured sol-gel silica and silica fume by electrical conductivity measurement. Constr Build Mater 160:252–257. https://doi.org/10.1016/j.conbuildmat.2017.11.04210.1016/j.conbuildmat.2017.11.042 ↗
16. Sun S, Yu X, Han B, Ou J (2013) In situ growth of carbon nanotubes/carbon nanofibers on cement/mineral admixture particles: a review. Constr Build Mater 49:835–840. https://doi.org/10.1016/j.conbuildmat.2013.09.01110.1016/j.conbuildmat.2013.09.011 ↗
17. Feng P, Kong Y, Liu M et al (2021) Dispersion strategies for low-dimensional nanomaterials and their application in biopolymer implants. Mater Today Nano 15:100127. https://doi.org/10.1016/j.mtnano.2021.10012710.1016/j.mtnano.2021.100127 ↗
18. Ramezani M, Dehghani A, Sherif MM (2022) Carbon nanotube reinforced cementitious composites: a comprehensive review. Constr Build Mater 315:125100. https://doi.org/10.1016/j.conbuildmat.2021.12510010.1016/j.conbuildmat.2021.125100 ↗
19. Mudimela PR, Nasibulina LI, Nasibulin AG et al (2009) Synthesis of carbon nanotubes and nanofibers on silica and cement matrix materials. J Nanomater 2009:1–4. https://doi.org/10.1155/2009/52612810.1155/2009/526128 ↗
20. Nasibulin AG, Koltsova T, Nasibulina LI et al (2013) A novel approach to composite preparation by direct synthesis of carbon nanomaterial on matrix or filler particles. Acta Mater 61:1862–1871. https://doi.org/10.1016/j.actamat.2012.12.00710.1016/j.actamat.2012.12.007 ↗
21. Ding S, Xiang Y, Ni Y-Q et al (2022) In-situ synthesizing carbon nanotubes on cement to develop self-sensing cementitious composites for smart high-speed rail infrastructures. Nano Today 43:101438. https://doi.org/10.1016/j.nantod.2022.10143810.1016/j.nantod.2022.101438 ↗
22. Shaijumon MM, Bejoy N, Ramaprabhu S (2005) Catalytic growth of carbon nanotubes over Ni/Cr hydrotalcite-type anionic clay and their hydrogen storage properties. Appl Surf Sci 242:192–198. https://doi.org/10.1016/j.apsusc.2004.08.01410.1016/j.apsusc.2004.08.014 ↗
23. García Montes SM, Morales Ibarra R, García Loera AF (2020) Carbon nanotubes synthesized on the surface of recycled carbon fibers by catalytic chemical vapor deposition for revalorization of degraded composite materials. J Nanopart Res 22:21. https://doi.org/10.1007/s11051-019-4743-710.1007/s11051-019-4743-7 ↗
24. Dasgupta K, Venugopalan R, Dey GK, Sathiyamoorthy D (2008) Novel catalytic route to bulk production of high purity carbon nanotube. J Nanopart Res 10:69–76. https://doi.org/10.1007/s11051-007-9219-510.1007/s11051-007-9219-5 ↗
25. Shamoradi F, Panjepour M, Emadi R, Ghiaci M (2022) Study of fabrication and CNT growth mechanisms of hybrid CFF/CNT composites. J Nanopart Res 24:192. https://doi.org/10.1007/s11051-022-05575-410.1007/s11051-022-05575-4 ↗
26. Geraldo V, Oliveira S, Silva EE et al (2020) Synthesis of carbon nanotubes on sand grains for mortar reinforcement. Constr Build Mater 252:119044. https://doi.org/10.1016/j.conbuildmat.2020.11904410.1016/j.conbuildmat.2020.119044 ↗
27. Costal GZ, Oliveira CEM, Morais EA de, et al (2021) High-yield synthesis of carbon nanotubes in-situ on iron ore tailing. Carbon Trends 5:100098. https://doi.org/10.1016/j.cartre.2021.10009810.1016/j.cartre.2021.100098 ↗
28. Silva K, Filippov LO, Piçarra A et al (2021) New perspectives in iron ore flotation: use of collector reagents without depressants in reverse cationic flotation of quartz. Miner Eng 170:107004. https://doi.org/10.1016/j.mineng.2021.10700410.1016/j.mineng.2021.107004 ↗
29. Gomes MA, Pereira CA, Peres AEC (2011) Caracterização tecnológica de rejeito de minério de ferro. Rem: Revista Escola de Minas 64:233–236. https://doi.org/10.1590/S0370-4467201100020001610.1590/S0370-44672011000200016 ↗
30. Zahir MH, Rahman MM, Irshad K, Rahman MM (2019) Shape-stabilized phase change materials for solar energy storage: MgO and Mg(OH)2 mixed with polyethylene glycol. Nanomaterials 9:1773. https://doi.org/10.3390/nano912177310.3390/nano9121773 ↗
31. Li R, Zhou D, Luo J et al (2017) The urchin-like sphere arrays Co3O4 as a bifunctional catalyst for hydrogen evolution reaction and oxygen evolution reaction. J Power Sources 341:250–256. https://doi.org/10.1016/j.jpowsour.2016.10.09610.1016/j.jpowsour.2016.10.096 ↗
32. Khot VM, Salunkhe AB, Phadatare MR, Pawar SH (2012) Formation, microstructure and magnetic properties of nanocrystalline MgFe2O4. Mater Chem Phys 132:782–787. https://doi.org/10.1016/j.matchemphys.2011.12.01210.1016/j.matchemphys.2011.12.012 ↗
33. Tüysüz H, Salabaş EL, Weidenthaler C, Schüth F (2008) Synthesis and magnetic investigation of ordered mesoporous two-line ferrihydrite. J Am Chem Soc 130:280–287. https://doi.org/10.1021/ja075528j10.1021/ja075528j ↗
34. Xu H, Wang M, Liu Q et al (2011) Stability of the compounds obtained by intercalating potassium acetate molecules into kaolinite from coal measures. J Phys Chem Solids 72:24–28. https://doi.org/10.1016/j.jpcs.2010.10.01910.1016/j.jpcs.2010.10.019 ↗
35. Salama W, El Aref M, Gaupp R (2015) Spectroscopic characterization of iron ores formed in different geological environments using FTIR, XPS, Mössbauer spectroscopy and thermoanalyses. Spectrochim Acta A Mol Biomol Spectrosc 136:1816–1826. https://doi.org/10.1016/j.saa.2014.10.09010.1016/j.saa.2014.10.090 ↗
36. Almeida CA, Oliveira AF, Pacheco AA et al (2018) Characterization and evaluation of sorption potential of the iron mine waste after Samarco dam disaster in Doce River basin – Brazil. Chemosphere 209:411–420. https://doi.org/10.1016/j.chemosphere.2018.06.07110.1016/j.chemosphere.2018.06.071 ↗
37. Oliveira CEM, da Silva EE, de Morais EA, Geraldo V (2021) Carbon nanotube research developments: published scientific documents and patents, synthesis, and production. In: Handbook of carbon nanotubes. Springer International Publishing, Cham, pp 1–38
38. Saito Y, Yoshikawa T, Bandow S et al (1993) Interlayer spacings in carbon nanotubes. Phys Rev B 48:1907–1909. https://doi.org/10.1103/PhysRevB.48.190710.1103/PhysRevB.48.1907 ↗
39. Nadiv R, Shtein M, Refaeli M et al (2016) The critical role of nanotube shape in cement composites. Cem Concr Compos 71:166–174. https://doi.org/10.1016/j.cemconcomp.2016.05.01210.1016/j.cemconcomp.2016.05.012 ↗
40. Vaisman L, Wagner HD, Marom G (2006) The role of surfactants in dispersion of carbon nanotubes. Adv Colloid Interface Sci 128–130:37–46. https://doi.org/10.1016/j.cis.2006.11.00710.1016/j.cis.2006.11.007 ↗
41. Han Z, Fina A (2011) Thermal conductivity of carbon nanotubes and their polymer nanocomposites: a review. Prog Polym Sci 36:914–944. https://doi.org/10.1016/j.progpolymsci.2010.11.00410.1016/j.progpolymsci.2010.11.004 ↗
42. Cerro-Prada E, Pacheco-Torres R, Varela F (2020) Effect of multi-walled carbon nanotubes on strength and electrical properties of cement mortar. Materials 14:79. https://doi.org/10.3390/ma1401007910.3390/ma14010079 ↗
43. García VJ, Márquez CO, Zúñiga-Suárez AR et al (2021) Mechanical and electrical properties of MWCNTs - high early strength cement - mortars composite: dispersion of CNTs and effect of chemical admixtures. An Acad Bras Cienc 93. https://doi.org/10.1590/0001-376520212020092410.1590/0001-3765202120200924 ↗
44. Mehta PK, Monteiro PJM (2014) Concrete: Microstructure, Properties, and Materials, 4th edn. MC Graw Hill Education
45. Sobolev K, Flores I, Hermosillo R, Torres-Martinez LM (2008) Nanomaterials and nanotechnology for high-performance cement composites. ACI Symposium Publication 254. https://doi.org/10.14359/2021310.14359/20213 ↗
46. Silvestro L, Jean Paul Gleize P (2020) Effect of carbon nanotubes on compressive, flexural and tensile strengths of Portland cement-based materials: a systematic literature review. Constr Build Mater 264:120237. https://doi.org/10.1016/j.conbuildmat.2020.12023710.1016/j.conbuildmat.2020.120237 ↗
47. Choi H, Kang D, Seo GS, Chung W (2015) Effect of some parameters on the compressive strength of MWCNT-cement composites. Adv Mater Sci Eng 2015:1–8. https://doi.org/10.1155/2015/34080810.1155/2015/340808 ↗
48. Isaia GC (2011) Concreto: Ciência e tecnologia. IBRACON, São Paulo