Synthesis of pure (ligandless) titanium nanoparticles by EB-PVD method
Source abstract
Abstract
Pure (ligandless) nanoparticles of titanium (4–20 nm) in a porous NaCl matrix (29–43 nm) were synthesized by the method of electron beam physical vapor deposition (EB-PVD). Independent electron beams were used to preheat the compacted cylinder from NaCl salt and Ti ingot up to formation of liquid melts. Evaporation of the initial materials from the melt surface, vapor flow mixing, and deposition of the mixed vapor on the surface of the water-cooled copper substrate took place in vacuum. Deposited condensate composition was regulated by the intensity of the vapor flows of evaporated materials. Results of studying the structure (SEM) and element composition of the condensate (EDS), phase composition (XPA), and the size of the nanoparticles (TEM) and crystallites (XPA + Scherrer equation), as well as their thermal stability in NaCl–Ti–O system (TGA), are given. It is shown that the dimensions and phase composition of titanium nanoparticles can be further controlled by heat treatment of the initial NaCl–Ti condensate, produced at low condensation temperatures. Investigations of the kinetics of oxidation of NaCl–Ti condensates in air (TGA) show that breaking of the vacuum in the chamber titanium nanoparticles in the porous NaCl matrix demonstrates high adsorption ability to moisture and oxygen from the air. With temperature increase up to 250–400 °C, practically all the moisture is removed, and further heating activates the process of titanium nanoparticle oxidation. Obtained results are considered from the viewpoint of physical and chemical adsorption.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: nanoparticles nucleation surface interactions · High-Temperature Coating Behaviors · Ion-surface interactions and analysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (48)
Show source-provided references
1. Alzubi FG (2017) Synthesis of titanium nanoparticles with controlled size variation by physical vapor deposition. Advanced Materials: TechConnect Briefs 1:126–129 https://briefs.techconnect.org/wp-content/volumes/TCB2017v1/pdf/524.pdf
2. Bai J, Zhou B (2014) Titanium dioxide nanomaterials for sensor applications. Chem Rev 114:10131–10176. https://doi.org/10.1021/cr400625j10.1021/cr400625j ↗
3. Bundschuh M, Filser J, Lüderwald S, McKee MS, Metreveli G, Schaumann GE, Schulz R, Wagner S (2018) Nanoparticles in the environment: where do we come from, where do we go to? Environ Sci Eur 30:1–17. https://doi.org/10.1186/s12302-018-0132-610.1186/s12302-018-0132-6 ↗
4. Calderón-Jiménez B, Johnson ME, Montoro Bustos AR, Murphy KE, Winchester MR, Vega Baudrit JR (2017) Silver nanoparticles: technological advances, societal impacts, and metrological challenges. Front Chem 5:1–26. https://doi.org/10.3389/fchem.2017.0000610.3389/fchem.2017.00006 ↗
5. Checkman IS, Movchan BA, Zagorodnii MI, Gaponov YV, Kurapov YA, Krushinskaya LA, Kardash MV (2008) Nanosilver: production technologies, pharmacological properties, indications for use. Mistetstvo likuvannya 5:32–34 (in Russian)). http://www.health-medix.com/articles/misteztvo/2008-06-15/32-34.pdf
6. Clemons TD, Kerr RH, Joos A (2018) 3.10. Multifunctional magnetic nanoparticles: design, synthesis, and biomedical applications, 193-210, in: comprehensive Nanoscience and nanotechnology reference work, 2nd edition, editors-in-chief: D.L.Andrews, R.H.Lipson and T.Nann, 1886 p. Elsevier B.V. ISBN: 978-0-12-812296-9, 1-18. https://doi.org/10.1016/B978-0-12-803581-8.10462-X10.1016/B978-0-12-803581-8.10462-X ↗
7. Desai VS, Kowshik M (2009) Antimicrobial activity of titanium dioxide nanoparticles synthesized by sol-gel technique. Res J Microbiol 4:97–103. https://doi.org/10.3923/jm.2009.97.10310.3923/jm.2009.97.103 ↗
8. He X, Deng H, Huey-min H (2019) The current application of nanotechnology in food and agriculture. J Food Drug Anal 27:1–21. https://doi.org/10.1016/j.jfda.2018.12.00210.1016/j.jfda.2018.12.002 ↗
9. Hendren R)CO, Uyar AE, Darby MR, Zucker LG, Wiesner MR (2009) Estimates of upper bounds and trends in Nano_TiO2 production as a basis for exposure assessment. Environ Sci Technol 43:4227–4233. https://doi.org/10.1021/es803254910.1021/es8032549 ↗
10. Hosseini MS, Sadeghi MT, Khazaei M (2018) Improving oleophobicity and hydrophilicity of superhydrophobic surface by TiO2-based coatings. Materials Research Express 5:085010. https://doi.org/10.1088/2053-1591/aad2b810.1088/2053-1591/aad2b8 ↗
11. Howard CJ (1991) Structural and thermal parameters for rutile and anatase. Acta Cryst B 47:462–468. https://doi.org/10.1107/S010876819100335X10.1107/S010876819100335X ↗
12. Huang Y, Mei L, Chen X, Wang Q (2018) Recent developments in food packaging based on nanomaterials. Nanomaterials 8:1–29. https://doi.org/10.3390/nano810083010.3390/nano8100830 ↗
13. Ingle AP, Duran N, Rai M (2013) Bioactivity, mechanism of action, and cytotoxicity of copper-based nanoparticles: a review. Appl Microbiol Biotechnol 98:1001–1009. https://doi.org/10.1007/s00253-013-5422-810.1007/s00253-013-5422-8 ↗
14. Kovinskii IS, Krushinskaya LA, Movchan BA (2011) Structure and some properties of sodium chloride condensates produced by electron beam evaporation with vacuum deposition. Advances in Electrometallurgy 9:44–49 (in Russian). http://pwi-scientists.com/pdf/journals/aiem201101.pdf
15. Kumar M, Parashar KK, Tandi SK, Kumar T, Agarwal DC, Pathak A (2013) Fabrication of Ag:TiO2 nanocomposite thin films by sol-gel followed by Electron beam physical vapour deposition. Technique Journal of Spectroscopy 2013:ID491716, 6 p. https://doi.org/10.1155/2013/491716, 1, 610.1155/2013/491716 ↗
16. Kundu A, Mondal A (2019) Photodegradation of methylene blue under direct sunbeams by synthesized anatase titania nanoparticles. SN Applied Sciences 1:280. https://doi.org/10.1007/s42452-019-0280-310.1007/s42452-019-0280-3 ↗
17. Kurapov YA, Didikin GG, Romanenko SM, Litvin SE (2009a) Magnetite nanoparticles produced by vacuum condensation of molecular beams. Advances in Electrometallurgy 7:170–173 (in Russian). https://patonpublishinghouse.com/sem/pdf/2009/sem200903all.pdf
18. Kurapov YA, Krushyns’ka LA, Gorchev VF, Kardash MV, Lytvyn SE, Stel’makh YA, Didikin GG, Romanenko SM, Movchan BO, Chekman IS (2009b) Analysis of colloidal systems on the basis of nanoparticles Cu−O−H2O and Ag−O−H2O obtained by the method of molecular beams. Reports of the National Academy of Sciences of Ukraine 7:176–181 (in Ukrainian). http://irbis-nbuv.gov.ua/cgi-bin/irbis_nbuv/cgiirbis_64.exe?C21COM=2&I21DBN=UJRN&P21DBN=UJRN&IMAGE_FILE_DOWNLOAD=1&Image_file_name=PDF/dnanu_2009_7_33.pdf
19. Kurapov YA, Movchan BA, Litvin SE, Didikin GG, Romanenko SM (2011) Effect of iron concentration on the adsorptive capacity of iron oxide nanoparticles in the porous NaCl matrix in relation to atmospheric oxygen. Advances in Electrometallurgy 9:29–32 http://pwi-scientists.com/pdf/journals/aiem201101.pdf
20. Kurapov Y, Litvin S, Romanenko S, Didikin G, Belyavina N (2018) Synthesis of copper and silver nanoparticles by molecular beam method. Micro and Nanosystems 10:148–157. https://doi.org/10.2174/187640291166618112810190710.2174/1876402911666181128101907 ↗
21. Kurapov YA, Vazhnichaya EM, Litvin SE, Romanenko SM, Didikin GG, Devyatkina TA, Mokliak YV, Oranskaya EI (2019) Physical synthesis of iron oxide nanoparticles and their biological activity in vivo. SN Applied Sciences 1:102. https://doi.org/10.1007/s42452-018-0110-z10.1007/s42452-018-0110-z ↗
22. Lampé I, Beke D, Biri S, Csarnovics I, Csik A, Dombrádi Z, Hajdu P, Hegedűs V, Rácz R, Varga I, Hegedűs C (2019) Investigation of silver nanoparticles on titanium surface created by ion implantation technology. Int J Nanomedicine 14:4709. https://doi.org/10.2147/IJN.S19778210.2147/IJN.S197782 ↗
23. Luchinskii GP (1971) Chemistry of titanium, M., “Khimia” Publ. House 472 p. https://www.twirpx.com/file/415404/
24. Mamniashvili G, Gegechkori T, Оkrosashvili M, Kutelia E, Аkhalkatsi A, Gavasheli T, Daraselia D, Djaparidze D, Shengelaya A, Peikrishvili A, Lesuer D (2015) Production of cobalt nanopowders by electron-beam technology and their NMR and magnetometry study. J Magn Magn Mater 373:177–182. https://doi.org/10.1016/j.jmmm.2014.03.05810.1016/j.jmmm.2014.03.058 ↗
25. Mangrola MH, Joshi VG (2017) Synthesis, characterization and study of influence of pure TiO2 nanoparticles thin film developed by e-beam evaporation. Materials Today: Proceedings A 4:3832–3841. https://doi.org/10.1016/j.matpr.2017.02.28110.1016/j.matpr.2017.02.281 ↗
26. McNeil SE (2018) Characterization of nanoparticles intended for drug delivery, Second edn. Humana Press. https://doi.org/10.1007/978-1-4939-7352-110.1007/978-1-4939-7352-1 ↗
27. Moskalenko VF, Movchan BO, Chekman IS, Kurapov Yu A, Krushinskaya LA, Kardash MV, Zagorodnii MI (2008) Nanotechnology, nanomedicine, nanopharmacology: state of research, prospects for introduction of new nanopreparations into practical medicine. XII congress of world Federation of Ukrainian Doctors’ societies. Ivano-Frankivsk-Kyiv-Chicago. Abstracts of papers. September 25-28, #842, 451 (in Ukrainian). http://sfult.org/xii_tezu.pdf
28. Movchan BA (2004) Electron beam technology of evaporation and deposition from the vapour phase of inorganic materials with amorphous, nano- and microstructure, in: nanosystems, nanomaterials, nanotechnologies (trans.), Kyiv. Akademperiodika 2:1103–1126 (in Russian). https://www.imp.kiev.ua/nanosys/en/articles/index.html
29. Movchan BA (2006) Inorganic materials and coatings produced by EBPVD. Surf Eng 22:35–45. https://doi.org/10.1179/174329406X8502910.1179/174329406X85029 ↗
30. Movchan BA (2007) Electron beam nanotechnology and new materials in medicine – first steps. Visnik farmacologii ta farmacii 12:5–13 (in Russian). https://visnikfarmacii.ucoz.ua/publ/arkhiv_poperednikh_nomeriv_2007_roku/12_2007_roku/2-1-0-16
31. Movchan BA, Demchishin AV (1969) Investigations of the structure and properties of thick vacuum condensates of nickel, titanium, tungsten, aluminium oxide and zirconium oxide. Fiz Met Metalloved 28:653–660 (in Russian). http://impo.imp.uran.ru/fmm/electron/vol28_4/abstract10.pdf
32. Movchan BA, Kurapov YA, Didikin GG, Litvin SG, Romanenko SM (2011) Control of the composition and structure of Fe-O nanoparticles during Fe3O4 electron beam evaporation. Powder Metallurgy and Metal Ceramics 50:167–172. https://doi.org/10.1007/s11106-011-9314-010.1007/s11106-011-9314-0 ↗
33. Nepomniashchaia EK, Aksenov ET, Bogomaz TA, Velichko EN (2015) Use of laser correlation spectroscopy to investigate the parameters of biological suspensions. J Opt Technol 82:162–165. https://doi.org/10.1364/JOT.82.00016210.1364/JOT.82.000162 ↗
34. Pathak PD, Vasavada NG (1970) Thermal expansion of NaCl, KCl and CsBr by X-ray diffraction and the law of corresponding states. Acta Cryst A 26:655–658. https://doi.org/10.1107/S056773947000160210.1107/S0567739470001602 ↗
35. Prasad K, Bazaka O, Chua M, Rochford M, Fedrick L, Spoor J, Symes R, Tieppo M, Collins C, Cao A, Markwell D, Ostrikov K(K), Bazaka K (2017) Metallic biomaterials: current challenges and opportunities. Materials (Basel) 10:1–33. https://doi.org/10.3390/ma1008088410.3390/ma10080884 ↗
36. Reyes-Coronado D, Rodríguez-Gattorno G, Espinosa-Pesqueira ME, Cab C, de Coss R, Oskam G (2008) Phase-pure TiO2 nanoparticles: anatase, brookite and rutile. Nanotechnology 19:145605, 10pp. https://doi.org/10.1088/0957-4484/19/14/14560510.1088/0957-4484/19/14/145605 ↗
37. Rezić I, Haramina T, Rezic T (2017) Metal nanoparticles and carbon nanotubes-perfect antimicrobial nano-fillers in polymer-based food packaging materials. Food Packaging:497–532. https://doi.org/10.1016/B978-0-12-804302-8.00015-710.1016/B978-0-12-804302-8.00015-7 ↗
38. Scheffel B, Modes N, Metzner C (2016) Reactive high-rate deposition of titanium oxide coatings using electron beam evaporation, spotless arc and dual crucible. Surf Coat Technol 287:138–144. https://doi.org/10.1016/j.surfcoat.2015.12.06110.1016/j.surfcoat.2015.12.061 ↗
39. Sergeyev GB (2007) Nanochemistry: manual, 2nd edn. Moscow University Publ. House, p 336 (in Russian). http://padabum.com/d.php?id=122281
40. Shafyei H, Ashiri R (2019) Electron beam assisted physical vapor deposition of very hard TiCN coating with nanoscale characters. Ceram Int 45:14821–14828. https://doi.org/10.1016/j.ceramint.2019.04.21310.1016/j.ceramint.2019.04.213 ↗
41. Singh J, Wolfe DE (2005a) Nano and macro-structured component fabrication by Electron beam-physical vapor deposition (EB-PVD). J Mater Sci 40:1–26. https://doi.org/10.1007/s10853-005-5682-510.1007/s10853-005-5682-5 ↗
42. Singh J, Wolfe DE (2005b) Nanostructured component fabrication by electron beam-physical vapor deposition. J Mater Eng Perform 14:448–459. https://doi.org/10.1361/105994905X5622310.1361/105994905X56223 ↗
43. Springer Handbook of Nanomaterials (2013) by editors Vajtai R, Springer-Verlag Berlin Heidelberg 1234 p. https://doi.org/10.1007/978-3-642-20595-810.1007/978-3-642-20595-8 ↗
44. Stagon SP, Huang H, Kevin Baldwin J, Misra A (2012) Anomaly of film porosity dependence on deposition rate. Appl. Phys. Lett. 100:061601-061601-3. https://doi.org/10.1063/1.368354210.1063/1.3683542 ↗
45. Synthesis of Inorganic Nanomaterials (2018) Advances and key technologies, a volume in micro and nano technologies edited by: Bhagyaraj SM, Oluwafemi OS, Kalarikkal N, Thomas S, 312 p. Elsevier Ltd https://doi.org/10.1016/C2016-0-01718-710.1016/C2016-0-01718-7 ↗
46. Tuchina ES, Tuchin VV (2010) TiO2 nanoparticle enhanced photodynamic inhibition of pathogens. Laser Phys Lett 7:607–612. https://doi.org/10.1002/lapl.20101003010.1002/lapl.201010030 ↗
47. Winkler HC, Notter T, Meyer U, Naegeli H (2018) Critical review of the safety assessment of titanium dioxide additives in food. J Nanobiotechnology 16:1–19. https://doi.org/10.1186/s12951-018-0376-810.1186/s12951-018-0376-8 ↗
48. Zemtsova EG, Orehhov JV, Arbenin AY, Valiev RZ, Smirnov VM (2016) The creation of nanocoatings of various morphology on the basis of titanium dioxide on a titanium matrix for bone implant. Mater Phys Mech 29:138–144 (in Russian). http://www.ipme.ru/e-journals/MPM/no_22916/MPM229_05_zemtsova.pdf