journal article·2014-02

Hydrogen-induced Ostwald ripening of cobalt nanoparticles on carbon nanotubes

Marcel Di Vece, Codruta Zoican-Loebick, Lisa D. Pfefferle

Journal of Nanoparticle Research· Volume 16· Issue 2
Publisher page

Abstract

Nanoparticles on carbon nanotubes can be used as a high surface area catalyst or as a means to produce well-defined particles. In this study, cobalt nanoparticles were formed on xxsingle-walled carbon nanotubes during hydrogen exposure at an elevated temperature. The average particle size increased as a function of reaction time ranging from 1.5 to 40 nm, indicating hydrogen-induced Ostwald ripening which is remarkable for a nonhydrogen-absorbing material. Mass abundances and cobalt shells were observed which possibly contained hydrogen. The combination of large surface area, high atomic mobility, and hydrogen-induced Ostwald ripening resulted in a novel method to prepare various cobalt nanoparticle shapes and sizes.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Catalytic Processes in Materials Science · Hydrogen Storage and Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (48)

Show source-provided references
1. Aceto S, Chang CY, Vook RW (1992) Hillock growth on aluminum and aluminum alloy films. Thin Solid Films 219(80):86
2. Barnard AS, Young NP, Kirkland AI, van Huis MA, Xu H (2009) Nanogold: a quantitative phase map. ACS Nano 3:1431–143610.1021/nn900220k ↗
3. Borjesson A, Bolton K (2011) Modeling of Ostwald ripening of metal clusters attached to carbon nanotubes. J Phys Chem C 115:24454–2446210.1021/jp202328w ↗
4. Campbell CT (1997) Ultrathin metal films and particles on oxide surfaces: structural, electronic and chemisorptive properties Surf. Sci. Rep. 27:1–11110.1016/S0167-5729(96)00011-8 ↗
5. Carmo M, Paganin VA, Rosolen JM, Gonzalez ER (2005) Alternative supports for the preparation of catalysts for low-temperature fuel cells: the use of carbon nanotubes. J Power Sources 142:169–17610.1016/j.jpowsour.2004.10.023 ↗
6. Cbaiken J, Casey M, Villarica M (1992) Laser chemistry of organometallics as a general synthetic route to metal clusters. J Phys Chem 96:3185
7. Chen Y, Wei L, Wang B, Lim S, Ciuparu D, Zheng M, Chen J, Zoican C, Yang Y, Haller GL, Pfefferle LD (2007) Low-defect, purified, narrowly (n, m)-dispersed single-walled carbon nanotubes grown from cobalt-incorporated MCM-41. ACS Nano 1:327–33610.1021/nn700106c ↗
8. Choi J-G (1995) Reduction of supported cobalt catalysts by hydrogen. Catal Lett 35:291–29610.1007/BF00807185 ↗
9. Condon JB, Schober T (1993) Hydrogen bubbles in metals. J Nucl Mater 2007:1–2410.1016/0022-3115(93)90244-S ↗
10. Conner WWC, Falconer JL (2005) Spillover in heterogeneous catalysis. Chem Rev 95:759–78810.1021/cr00035a014 ↗
11. Day TM, Unwin PR, Wilson NR, Macpherson JV (2005) Electrochemical templating of metal nanoparticles and nanowires on single-walled carbon nanotube networks. J Am Chem Soc 127:10639–1064710.1021/ja051320r ↗
12. Di Vece M, Grandjean D, Van Bael MJ, Romero CP, Wang X, Decoster S, Vantomme A, Lievens P (2008) Hydrogen-induced Ostwald ripening at room temperature in a Pd nanocluster film. Phys Rev Lett 100:23610510.1103/PhysRevLett.100.236105 ↗
13. Di Vece M, Bals S, Verbeeck J, Lievens P, Van Tendeloo G (2009) Compositional changes of Pd–Au bimetallic nanoclusters upon hydrogenation. Phys Rev B 80:12542010.1103/PhysRevB.80.125420 ↗
14. Dresselhaus MS, Dresselhaus G, Hofmann M (2007) The big picture of Raman scattering in carbon nanotubes. Vib Spec 45:71–8110.1016/j.vibspec.2007.07.004 ↗
15. Fukai Y, Yokota S, Yanagawa J (2006) The phase diagram and superabundant vacancy formation in Co–H alloys. J Alloy Compd 407:16–2410.1016/j.jallcom.2005.06.016 ↗
16. Granqvist CG, Buhrman RA (1976) Ultrafine metal particles. J Appl Phys 47:2200–222210.1063/1.322870 ↗
17. Hull AW (1921) X-ray crystal analysis of thirteen common metals. Phys Rev 17:571–58810.1103/PhysRev.17.571 ↗
18. Iglesia E (1997) Design, synthesis, and use of cobalt-based Fischer–Tropsch synthesis catalysts. Appl Catal A 161:59–7810.1016/S0926-860X(97)00186-5 ↗
19. Jang E, Lim E-K, Choi J, Park J, Huh YJ, Suh JS, Huh YM, Haam S (2012) Br-Assisted Ostwald Ripening of Au nanoparticles under H2O2 Redox. Cryst Growth Des 12:37–3910.1021/cg201243n ↗
20. Johnston RL (2002) Atomic and molecular clusters, 1st edn. Taylor & Francis, London10.1201/9781420055771 ↗
21. Jorio A, Fantini C, de Souza M, Saito R, Samsonidze GG, Dresselhaus G, Dresselhaus MS, Pimenta MA (2004) Raman on carbon nanotubes using a tunable laser and comparison with photoluminescence. In: Kuzmany H, Fink J, Mehring M, Roth S (eds) Electronic Properties of synthetic nanoparticle structures, American Institute of Physics conference proceeding, pp 157–16210.1063/1.1812064 ↗
22. Kitakami O, Sato H, Shimada Y, Sato F, Tanaka M (1997) Size effect on the crystal phase of cobalt fine particles. Phys Rev B 56:13849–1385410.1103/PhysRevB.56.13849 ↗
23. Knight WD, Clemenger K, de Heer WA, Saunders WA, Chou MY, Cohen ML (1984) Electronic shell structure and abundances of sodium clusters. Rev Lett 52:2141–214310.1103/PhysRevLett.52.2141 ↗
24. Lai MY, Wang YL (1998) Direct observation of two dimensional magic clusters. Phys Rev Lett 81:164–16710.1103/PhysRevLett.81.164 ↗
25. Lim S, Li N, Fang F, Pinault M, Zoican C, Wang C, Fadel T, Pfefferle LD, Haller GL (2008) High-yield single-walled carbon nanotubes synthesized on the small-pore (C10) Co-MCM-41 catalyst. J Phys Chem C 112:12442–1245410.1021/jp710805u ↗
26. Lu Y, Li J, Han J, Ng HT, Binder C, Partridge C, Meyyappan M (2004) Room temperature methane detection using palladium loaded single-walled carbon nanotube sensors. Chem Phys Lett 391:344–34810.1016/j.cplett.2004.05.029 ↗
27. Martin TP, Bergmann T, Gohlich H, Lange T (1990) Observation of electronic shells of atoms in large Na clusters. Chem Phys Lett 172:209–21310.1016/0009-2614(90)85389-T ↗
28. Maruyama S, Anderson LR, Smalley RE (1990) Direct injection supersonic cluster beam source for FT-ICR studies of clusters. Rev Sci Instrum 61:3686–369310.1063/1.1141536 ↗
29. Milani P, de Heer WA (1990) Improved pulsed laser vaporization source for production of intense beams of neutral and ionized clusters. Rev Sci Instrum 61:1835–183810.1063/1.1141103 ↗
30. Milcius DD, Pranevicius LL, Templier C (2005) Hydrogen storage in the bubbles formed by high-flux ion implantation in thin Al films. J Alloys Compd 398:203–20710.1016/j.jallcom.2005.02.003 ↗
31. Natl. Bur. Stand. (US) (1960) Circulation 539:9–28
32. Nayak SK, Jena P, Stepanyuk VS, Hergert W, Wildberger K (1997) Magic numbers in supported metal clusters. Phys Rev B 56:6952–695710.1103/PhysRevB.56.6952 ↗
33. Ostwald W (1900) On the assumed isomerism of red and yellow mercury oxide and the surface-tension of solid bodies. Z Phys Chem (Leipzig) 34:495–50310.1515/zpch-1900-3431 ↗
34. Palasantzas G, Koch SA, Vystavel T, De Hosson JTM (2005) Nano-sized cobalt cluster films: structure and functionality. Adv Eng Mater 7:21–2510.1002/adem.200400150 ↗
35. Pan GZ, Tu KN, Prussin A (1996) Size-distribution and annealing behavior of end-of-range dislocation loops in silicon-implanted silicon. J Appl Phys 81:1
36. Patterson AL (1939) The Scherrer formula for x-ray particle size determination. Phys Rev Lett 56:978–982
37. Peng X, Chen J, Misewich JA, Wong SS (2009) Carbon nanotube-nanocrystal heterostructures. Chem Soc Rev 38:1076–109810.1039/b811424m ↗
38. Sato H, Kitakami O, Sakurai T, Shimada Y, Otani Y, Fukamichi K (1997) Structure and magnetism of hcp-Co fine particles. J Appl Phys 81:1858–186210.1063/1.364041 ↗
39. Schober T, Bechthold PS (1994) Hydrogen blisters on beta-NbD after laser pulse heating. J Appl Phys 76:2093–209610.1063/1.357619 ↗
40. Smigelskas AD, Kirkendall EO (1947) Zinc diffusion in alpha-brass. Trans AIME 171:130–142
41. Solliard C, Flueli M (1985) Surface stress and size effect on the lattice parameter in small particles of gold and platinum. Surf Sci 156:487–49410.1016/0039-6028(85)90610-7 ↗
42. Tian N, Zhou ZY, Sun SG, Ding Y, Wang ZL (2007) Synthesis of tetrahexahedral platinum nanocrystals with high-index facets and high electro-oxidation activity. Science 316:732–73510.1126/science.1140484 ↗
43. Visintin A, Canullo JC, Tracia WE (1988) Changes in real surface area, crystallographic orientation and morphology of platinum-electrodes caused by periodic potential treatments-phenomenological approach Arvia. J Electroanal Chem 239:6710.1016/0022-0728(88)80270-5 ↗
44. Voorhees PW (1985) The theory of Ostwald ripening. J Stat Phys 38:23110.1007/BF01017860 ↗
45. Winter BJ, Klots TD, Parks EK, Riley SJ (1991) Chemical-identification of icosahedral structure for cobalt and nickel clusters. Z Phys D 19:375–38010.1007/BF01448332 ↗
46. Yao JH, Yao Elder KR, Guo H, Grant M (1993) Theory and simulation of Ostwald ripening. Phys Rev B 47(2):14110
47. Yin Y, Rioux RM, Erdonmez CK, Hughes S, Somorjai GA, Alivisatos AP (2004) Formation of hollow nanocrystals through the nanoscale Kirkendall effect. Science 304:711–71410.1126/science.1096566 ↗
48. Yoo E, Gao L, Komatsu T, Yagai N, Arai K, Yamazaki T, Matsuishi, Matsumoto T, Nakamura J (2004) Atomic hydrogen storage in carbon nanotubes promoted by metal catalystsJ. Phys Chem B 108:18903–1890710.1021/jp047056q ↗