journal article·2020-01

Carbon nanotubes synthesized on the surface of recycled carbon fibers by catalytic chemical vapor deposition for revalorization of degraded composite materials

Saida Mayela García Montes, Rodolfo Morales Ibarra, Antonio Francisco García Loera

Journal of Nanoparticle Research· Volume 22· Issue 1
Publisher page

Abstract

There is a clear need to develop a sustainable use of composite materials; high-performance composite materials like carbon-epoxy systems are of special interest because of their wide range of applications and their high intrinsical value. Even though the technology for recycling thermoset composite materials has been developed, and the recovery of carbon fibers from composite materials is feasible, there is still to some extent, a degradation of the recovered carbon fibers; thus, a revalidation of the recycled carbon fibers with improved properties is highly desirable for a new life cycle in high-performance composites and components; thereupon, revalorization of the recovered carbon fibers by anchorage and growth of carbon nanotubes directly on the surface of the fibers via assembly of graphene-cap mechanism on nickel nanoparticles is an attractive technological approach for integral recycling of composite materials. These revalorized carbon fibers with carbon nanotubes are potential candidates for novel composites with exceptional mechanical, thermal, and electrical properties. In this research, catalytic chemical vapor deposition method was used for the synthesis of carbon nanotubes on the recycled fibers under influence of carbon source, temperature. Carbon nanotubes were produced by decomposing whether ethanol or isopropanol as a carbon source at temperatures ranging from 800 to 600 °C in an inert atmosphere. Fibers used as a substrate in this research are actually recovered carbon fibers from a carbon-epoxy composite component reaching end-of-life via pyrolysis. All experimental results were characterized using scanning electron microscopy corroborating the synthesis and morphology of the carbon nanotubes on the carbon fibers; Raman spectroscopy corroborated synthesis of multiwall carbon nanotubes; pseudo-mechanical testing confirmed that the nanotubes have a good anchorage to the carbon fiber surface, making this novel revalorized fiber a potential reinforcement for new high-performance composite materials.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Carbon Nanotubes in Composites · Graphene research and applications · Fiber-reinforced polymer composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (41)

Show source-provided references
1. Agnihotri P, Basu S, Kar KK (2011) Effect of carbon nanotube length and density on the properties of carbon nanotube-coated carbon fiber/polyester composites. Carbon N Y 49:3098–3106. https://doi.org/10.1016/j.carbon.2011.03.03210.1016/j.carbon.2011.03.032 ↗
2. Bekyarova E, Thostenson ET, Yu A et al (2007a) Multiscale carbon nanotube-carbon fiber reinforcement for advanced epoxy composites. Langmuir. https://doi.org/10.1021/la062743p10.1021/la062743p ↗
3. Bekyarova E, Thostenson ET, Yu A et al (2007b) Functionalized single-walled carbon nanotubes for carbon fiber-epoxy composites. J Phys Chem C. https://doi.org/10.1021/jp071329a10.1021/jp071329a ↗
4. Blazsó M (2006) Composition of liquid fuels derived from the pyrolysis of plastics. In: Feedstock recycling and pyrolysis of waste plastics: converting waste plastics into diesel and other fuels10.1002/0470021543.ch12 ↗
5. Cunliffe AM, Jones N, Williams PT (2003) Recycling of fibre-reinforced polymeric waste by pyrolysis: thermo-gravimetric and bench-scale investigations. J Anal Appl Pyrolysis. https://doi.org/10.1016/S0165-2370(02)00161-410.1016/S0165-2370(02)00161-4 ↗
6. De Greef N, Zhang L, Magrez A et al (2015) Direct growth of carbon nanotubes on carbon fibers: effect of the CVD parameters on the degradation of mechanical properties of carbon fibers. Diam Relat Mater 51:39–48. https://doi.org/10.1016/j.diamond.2014.11.00210.1016/j.diamond.2014.11.002 ↗
7. De Riccardis MF, Carbone D, Makris TD et al (2006) Anchorage of carbon nanotubes grown on carbon fibres. Carbon N Y 44:671–674. https://doi.org/10.1016/j.carbon.2005.09.02410.1016/j.carbon.2005.09.024 ↗
8. Deck CP, Vecchio K (2005) Growth mechanism of vapor phase CVD-grown multi-walled carbon nanotubes. Carbon N Y 43:2608–2617. https://doi.org/10.1016/j.carbon.2005.05.01210.1016/j.carbon.2005.05.012 ↗
9. Dey NK, Hong EM, Choi KH et al (2012) Growth of carbon nanotubes on carbon fiber by thermal CVD using Ni nanoparticles as catalysts. Procedia Engineering, In, pp 556–561
10. El Mel AA, Gautron E, Angleraud B et al (2011) Synthesis of nickel-filled carbon nanotubes at 350 °c. Carbon N. Y. 49:4595–459810.1016/j.carbon.2011.06.001 ↗
11. Fan W, Wang Y, Wang C et al (2016) High efficient preparation of carbon nanotube-grafted carbon fibers with the improved tensile strength. Appl Surf Sci 364:539–551. https://doi.org/10.1016/j.apsusc.2015.12.18910.1016/j.apsusc.2015.12.189 ↗
12. Fang C, Wang J, Zhang T (2014) Interlaminar improvement of carbon fiber/epoxy composites via depositing mixture of carbon nanotubes and sizing agent. Appl Surf Sci 321:1–9. https://doi.org/10.1016/j.apsusc.2014.09.17010.1016/j.apsusc.2014.09.170 ↗
13. Godara A, Mezzo L, Luizi F et al (2009) Influence of carbon nanotube reinforcement on the processing and the mechanical behaviour of carbon fiber/epoxy composites. Carbon N Y 47:2914–2923. https://doi.org/10.1016/j.carbon.2009.06.03910.1016/j.carbon.2009.06.039 ↗
14. Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354:56–58. https://doi.org/10.1038/354056a010.1038/354056a0 ↗
15. Iijima S, Ichihashi T (1993) Single-shell carbon nanotubes of 1-nm diameter. Nature 363:603–605. https://doi.org/10.1038/363603a010.1038/363603a0 ↗
16. Jiang L, Ulven CA, Gutschmidt D et al (2015) Recycling carbon fiber composites using microwave irradiation: reinforcement study of the recycled fiber in new composites. J Appl Polym Sci. https://doi.org/10.1002/app.4265810.1002/app.42658 ↗
17. Jourdain V, Bichara C (2013) Current understanding of the growth of carbon nanotubes in catalytic chemical vapour deposition. Carbon N Y 58:2–3910.1016/j.carbon.2013.02.046 ↗
18. Kar KK, Rahaman A, Agnihotri P, Sathiyamoorthy D (2009) Synthesis of carbon nanotubes on the surface of carbon fiber/fabric by catalytic chemical vapor deposition and their characterization. Fullerenes Nanotub Carbon Nanostructures 17:209–229. https://doi.org/10.1080/1536383090277971810.1080/15363830902779718 ↗
19. Kim SW, Kim T, Kim YS et al (2012) Surface modifications for the effective dispersion of carbon nanotubes in solvents and polymers. Carbon, In, pp 3–33
20. Lee G, Ko KD, Yu YC et al (2015) A facile method for preparing CNT-grafted carbon fibers and improved tensile strength of their composites. Compos Part A Appl Sci Manuf 69:132–138. https://doi.org/10.1016/j.compositesa.2014.11.01510.1016/j.compositesa.2014.11.015 ↗
21. Lee G, Sung M, Youk JH et al (2019) Improved tensile strength of carbon nanotube-grafted carbon fiber reinforced composites. Compos Struct. https://doi.org/10.1016/j.compstruct.2019.04.03710.1016/j.compstruct.2019.04.037 ↗
22. Lester E, Kingman S, Wong KH et al (2004) Microwave heating as a means for carbon fibre recovery from polymer composites: a technical feasibility study. Mater Res Bull 39:1549–1556. https://doi.org/10.1016/j.materresbull.2004.04.03110.1016/j.materresbull.2004.04.031 ↗
23. Li M, Gu Y, Liu Y et al (2013) Interfacial improvement of carbon fiber/epoxy composites using a simple process for depositing commercially functionalized carbon nanotubes on the fibers. Carbon N Y 52:109–121. https://doi.org/10.1016/j.carbon.2012.09.01110.1016/j.carbon.2012.09.011 ↗
24. Li Y, Guo LJ, Wang YW et al (2016) A novel multiscale reinforcement by in-situ growing carbon nanotubes on graphene oxide grafted carbon fibers and its reinforced carbon/carbon composites with improved tensile properties. J Mater Sci Technol 32:419–424. https://doi.org/10.1016/j.jmst.2015.12.02210.1016/j.jmst.2015.12.022 ↗
25. Liao WH, Tien HW, Hsiao ST et al (2013) Effects of multiwalled carbon nanotubes functionalization on the morphology and mechanical and thermal properties of carbon fiber/vinyl ester composites. ACS Appl Mater Interfaces. https://doi.org/10.1021/am400811p10.1021/am400811p ↗
26. Ma PC, Siddiqui NA, Marom G, Kim JK (2010) Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: a review. Compos Part A Appl Sci Manuf 41:1345–1367. https://doi.org/10.1016/j.compositesa.2010.07.00310.1016/j.compositesa.2010.07.003 ↗
27. Mathur RB, Chatterjee S, Singh BP (2008) Growth of carbon nanotubes on carbon fibre substrates to produce hybrid/phenolic composites with improved mechanical properties. Compos Sci Technol 68:1608–1615. https://doi.org/10.1016/j.compscitech.2008.02.02010.1016/j.compscitech.2008.02.020 ↗
28. Morales Ibarra R (2017) Recycling of thermosets and their composites. In: Thermosets: structure, properties, and applications: second edition. Elsevier, pp 639–666
29. Morales Ibarra R, Sasaki M, Goto M, Quitain AT, García Montes SM, Aguilar-Garib JA (2015) Carbon fiber recovery using water and benzyl alcohol in subcritical and supercritical conditions for chemical recycling of thermoset composite materials. J Mater Cycles Waste Manag 17:369–379. https://doi.org/10.1007/s10163-014-0252-z10.1007/s10163-014-0252-z ↗
30. Nie J, Jia Y, Qu P, Shi Q (2011) Carbon nanotube/carbon fiber multiscale composite: influence of interfacial strength on mechanical properties. J Inorg Organomet Polym Mater 21:937–940. https://doi.org/10.1007/s10904-011-9565-810.1007/s10904-011-9565-8 ↗
31. Osorio AG, Silveira ICL, Bueno VL, Bergmann CP (2008) H 2 SO 4 /HNO 3 /HCl-functionalization and its effect on dispersion of carbon nanotubes in aqueous media. Appl Surf Sci 255:2485–2489. https://doi.org/10.1016/j.apsusc.2008.07.14410.1016/j.apsusc.2008.07.144 ↗
32. Pozegic TR, Hamerton I, Anguita JV et al (2014) Low temperature growth of carbon nanotubes on carbon fibre to create a highly networked fuzzy fibre reinforced composite with superior electrical conductivity. Carbon N Y 74:319–328. https://doi.org/10.1016/j.carbon.2014.03.03810.1016/j.carbon.2014.03.038 ↗
33. Shah KA, Tali BA (2016) Synthesis of carbon nanotubes by catalytic chemical vapour deposition: a review on carbon sources, catalysts and substrates. Mater Sci Semicond Process 41:67–8210.1016/j.mssp.2015.08.013 ↗
34. Sharma M, Gao S, Mäder E et al (2014) Carbon fiber surfaces and composite interphases. Compos Sci Technol 102:35–5010.1016/j.compscitech.2014.07.005 ↗
35. Sharma SP, Lakkad SC (2015) Impact behavior and fractographic study of carbon nanotubes grafted carbon fiber-reinforced epoxy matrix multi-scale hybrid composites. Compos Part A Appl Sci Manuf 69:124–131. https://doi.org/10.1016/j.compositesa.2014.11.00510.1016/j.compositesa.2014.11.005 ↗
36. Sun J, Li H, Han L, Song Q (2019) Growth of radially aligned porous carbon nanotube arrays on pyrolytic carbon coated carbon fibers. Vacuum. https://doi.org/10.1016/j.vacuum.2019.03.00510.1016/j.vacuum.2019.03.005 ↗
37. Thostenson ET, Ren Z, Chou TW (2001) Advances in the science and technology of carbon nanotubes and their composites: a review. Compos Sci Technol 61:1899–1912. https://doi.org/10.1016/S0266-3538(01)00094-X10.1016/S0266-3538(01)00094-X ↗
38. Yao H, Sui X, Zhao Z et al (2015) Optimization of interfacial microstructure and mechanical properties of carbon fiber/epoxy composites via carbon nanotube sizing. Appl Surf Sci 347:583–590. https://doi.org/10.1016/j.apsusc.2015.04.14610.1016/j.apsusc.2015.04.146 ↗
39. Zhang FH, Wang RG, He XD et al (2009a) Interfacial shearing strength and reinforcing mechanisms of an epoxy composite reinforced using a carbon nanotube/carbon fiber hybrid. J Mater Sci. https://doi.org/10.1007/s10853-009-3484-x10.1007/s10853-009-3484-x ↗
40. Zhang Q, Liu J, Sager R et al (2009b) Hierarchical composites of carbon nanotubes on carbon fiber: influence of growth condition on fiber tensile properties. Compos Sci Technol 69:594–601. https://doi.org/10.1016/j.compscitech.2008.12.00210.1016/j.compscitech.2008.12.002 ↗
41. Zheng L, Wang Y, Qin J et al (2018) Scalable manufacturing of carbon nanotubes on continuous carbon fibers surface from chemical vapor deposition. Vacuum 152:84–90. https://doi.org/10.1016/j.vacuum.2018.03.01110.1016/j.vacuum.2018.03.011 ↗