Fabrication and characterization of magnetic ferrofluids by the co-precipitation way using diglycolic acid
Source abstract
Abstract
Developing of a simple method for the fabrication of superparamagnetic iron oxide nanoparticles (Nps) is still a challenge for materials scientists. This work reveals a way to fabricate especially stable ferrofluids from spherical Nps of magnetite using the co-precipitation method, for which a new (diglycolic acid) stabilizer was applied. The Nps of the average size of ~7.4–16.5 nm were characterized by means of high resolution transmission electron microscopy (HRTEM), atomic force microscopy (AFM), selective area electron diffraction (SAED), Raman, FTIR and Mossbauer spectroscopy. The stabilization effect of the diglycolic acid for the growth of superparamagnetic Nps growth was discussed on the basis of experimental results.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Iron oxide chemistry and applications · Characterization and Applications of Magnetic Nanoparticles · Nanoparticle-Based Drug Delivery
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (39)
Show source-provided references
1. Battle X, Labarta A (2002) Finite-size effects in fine particles: magnetic and transport properties. J Phys D 35:R1510.1088/0022-3727/35/6/201 ↗
2. Campelj S, Makovec D, Drofenik M (2009) Functionalization of magnetic nanoparticles with 3-aminopropyl silane. J Magn Magn Mater 321(10):1346–135010.1016/j.jmmm.2009.02.036 ↗
3. Colomban Ph, Cherifi S, Despert G (2008) Raman identification of corrosion products on automotive galvanized steel sheets. J Raman Spectrosc 39:881–88610.1002/jrs.1927 ↗
4. Cornell RM, Schwertmann U (1996) The iron oxides. Wiley-VCH, Weinheim Germany
5. Daou TJ, Pourroy G, Begin-Colin S, Ulhaq-Bouillet JM, Legare P, Bernhardt P, Leuvrey C, Rogez G (2006) Hydrothermal synthesis of monodisperse magnetite nanoparticles. Chem Mater 18:4399–440410.1021/cm060805r ↗
6. Duan XF, Huang Y, Cui Y, Wang J, Lieber CM (2001) Indium phosphide nanowires as building blocks for nanoscale electronic and optoelectronic devices. Nature 409(6816):66–9910.1038/35051047 ↗
7. Enpuku K, Tanaka T, Masuda T, Dang F, Enomoto N et al (2007) Properties of magnetic nanoparticles in the Brownian relaxation range for liquid phase immunoassays. J Appl Phys 102:05490110.1063/1.2775882 ↗
8. Fan R, Chen XH, Gui Z, Liu L, Chen ZY (2001) A new simple hydrothermal preparation of nanocrystalline magnetite Fe3O4. Mater Res Bull 36:497–50210.1016/S0025-5408(01)00527-X ↗
9. Faria DLA, Silva SV, Oliveira MT (1997) Raman microscopy of some iron oxides and oxyhydroxides. J Raman Spectrosc 28:873–87810.1002/(SICI)1097-4555(199711)28:11<873::AID-JRS177>3.0.CO;2-B ↗
10. Frenkel J, Dorfman J (1930) Spontaneous and induced magnetization of ferromagnetic bodies. Nature 126:274–27510.1038/126274a0 ↗
11. Gou L, Murphy CJ (2003) Solution-phase synthesis of Cu2O nanocubes. Nano Lett 3:231–23410.1021/nl0258776 ↗
12. Gupta AK, Gupta K (2005) Synthesis and surface engineering of iron oxide nanoparticles for biomedical applications. Biomaterials 26(18):3995–402110.1016/j.biomaterials.2004.10.012 ↗
13. Hu C, Gao Z, Yang X (2006) Fabrication and magnetic properties of Fe3O4 octahedra. Chem Phys Lett 429:513–51710.1016/j.cplett.2006.08.041 ↗
14. Islam T, Harisinghani MG (2009) Overview of nanoparticle use in cancer imaging. Cancer Biomark 5:61–6710.3233/CBM-2009-0578 ↗
15. Kaizer R, Miskolczy G (1970) Magnetic properties of stable dispersions of subdomain magnetite particles. J Appl Phys 41:1064–107210.1063/1.1658812 ↗
16. Kralj S, Makovec D, Čampelj S, Drofenik M (2010) Producing ultra-thin silica coatings on iron oxide nanoparticles to improve their surface reactivity. J Magn Magn Mater 322(13):1847–185310.1016/j.jmmm.2009.12.038 ↗
17. Li M, Schnablegger H, Mann S (1999) Coupled synthesis and self-assembly of nanoparticles to give structures with controlled organization. Nature 402:393–39510.1038/46509 ↗
18. Lind K, Kresse M, Debus NP, Muller RH (2002) A novel formulation for superparamagnetic iron oxide particles enhancing MR lymphography: comparison of physicochemical properties and the in vivo behaviour. Drug J Target 10:221–23010.1080/10611860290022651 ↗
19. Lu A, Yin Y, Mayers BT, Xia Y (2002) Modifying the surface properties of superparamagnetic iron oxide nanoparticles through a sol–gel approach. Nano Lett 2:183–18610.1021/nl015681q ↗
20. Martinez B, Obradors X, Balcells L, Rouanet A, Monty C (1998) Low temperature surface spin-glass transition in γ-Fe2O3 nanoparticles. Phys Rev Lett 80:181–18410.1103/PhysRevLett.80.181 ↗
21. Millan A, Urtizberea A, Silva NJO, Palacio F, Amaral VS, Snoeck E, Serin V (2007) Surface effects in maghemite nanoparticles. J Magn Magn Mater 312:L5–L910.1016/j.jmmm.2006.09.011 ↗
22. Monet S, Vasseur S, Grasset F, Duguet E (2004) Magnetic nanoparticle design for medical diagnosis and therapy. J Mater Chem 14:2161–217510.1039/b402025a ↗
23. Moroz P, Jones SK, Gray BN (2002) Magnetically mediated hyperthermia: current status and future directions. Int J Hyperthermia 18:267–28410.1080/02656730110108785 ↗
24. Neuberger T, Schöpf B, Hofmann H, Hofmann M, Rechenber B (2005) Superparamagnetic nanoparticles for biomedical applications: possibilities and limitations of a new drug delivery system. J Magn Magn Mater 293:483–49610.1016/j.jmmm.2005.01.064 ↗
25. Pardoe H, Chua-Anusorn W, Pierre TGS, Dobson J (2001) Structural and magnetic properties of nanoscale iron oxide particles synthesized in the presence of dextran or polyvinyl alcohol. J Magn Magn Mater 225:41–4610.1016/S0304-8853(00)01226-9 ↗
26. Redel E, Thomann R, Janiak C (2008) Use of ionic liquids for the IL-anion size-dependent formation of Cr, Mo and W nanoparticles from novel carbonyl M(CO)8 precursors. Chem Commun 15:1789–179210.1039/b718055a ↗
27. Shafi KVPM, Ulman A, Yan X, Yang N, Estournes C, White H, Rafailovich M (2001) Sonochemical synthesis of functionalized amorphous iron oxide nanoparticles. Langmuir 17:5093–509710.1021/la010421+ ↗
28. Suslick KS, Fang M, Hyeon T (1996) Sonochemical synthesis of iron colloids. J Am Chem Soc 118:11960–1196110.1021/ja961807n ↗
29. Tartaj P, Serna C (2002) Microemulsion-assisted synthesis of tunable superparamagnetic composites. Chem Mater 14(10):4396–440210.1021/cm021214d ↗
30. Tsai Z-T, Wang J-F, Kuo H-Y, Shen CR, Wang J-J, Yen TC (2010) In situ preparation of high relaxivity iron oxide nanoparticles by coating with chitosan: a potential MRI contrast agent useful for cell tracking. J Magn Magn Mater 322:208–21310.1016/j.jmmm.2009.08.049 ↗
31. Unal B, Durmus Z, Kavas H, Baykal A, Toprak MS (2010) Synthesis, conductivity and dielectric characterization of salicylic acid-Fe3O4 nanocomposite. Mater Chem Phys 123:184–19010.1016/j.matchemphys.2010.03.080 ↗
32. Veintemillas Verdaguer S, Morales M, Serna C (1998) Continuous production of γ-Fe2O3 ultrafine powders by laser. Mater Lett 35:227–23010.1016/S0167-577X(97)00251-6 ↗
33. Wang Y, Maksimuk S, Shen R, Yang H (2007) Synthesis of iron nanoparticles using a freshly-made or recycled imidazolium-based ionic liquid. Green Chem 9(10):1051–105610.1039/b618933d ↗
34. Weissleder R, Elizondo G, Wittenberg J, Rabito CA, Bengele HH, Josephson L (1990) Ultrasmall superparamagnetic iron oxide: characterization of a new class of contrast agents for MR imaging. Radiology 175:489–49310.1148/radiology.175.2.2326474 ↗
35. Zhang S (2003) Fabrication of a novel biomaterials through molecular self-assembly. Nat Biotechnol 21:1171–217810.1038/nbt874 ↗
36. Zhang Z, Shao X, Yu H, Wang Y, Han M (2005) Morphosynthesis and ornamentation of 3D dendritic nanoarchitectures. Chem Mater 17(2):332–33610.1021/cm048436r ↗
37. Zhang M, Cushing BL, O’Connor CJ (2008) Synthesis and characterization of monodisperse ultra-thin silica-coated magnetic nanoparticles. Nanotechnology 19(8):08560110.1088/0957-4484/19/8/085601 ↗
38. Zhao DL, Zhang HL, Zeng XW, Xia QS, Tang JT (2006) Inductive heat property of Fe3O4/polymer composite nanoparticles in an ac magnetic field for localized hyperthermia. Biomed Mater 1:198–20110.1088/1748-6041/1/4/004 ↗
39. Zhu A, Yuan L, Liao T (2008) Suspension of Fe3O4 nanoparticles stabilized by chitosan and o-carboxymethylchitosan. Int J Pharm 350:361–36810.1016/j.ijpharm.2007.09.004 ↗