journal article·2019-12

Preparation of Ag@SiO2@NH2 core-shell nanocomposites for the fluorescence enhancement of carbon quantum dots

Qian Wu, Zhulong Zhou, Taohong Zhang, Ming Zhou

Journal of Nanoparticle Research· Volume 21· Issue 12
Publisher page

Abstract

In this paper, the fluorescence enhancement phenomenon of carbon quantum dots (C-QDs) via metal fluorescence effect has been investigated. Firstly, uniform Ag nanoparticles was prepared, which theoretically can supply a strong enhancement effect with a diameter as small as 20 nm. Then SiO2 shell was utilized to control the distance between Ag core and C-QDs while surface charge of as-synthesized Ag@SiO2 was further modified to bond C-QDs via electrostatic effect. Four different kinds of SiO2 shell, with thickness 12 nm, 15 nm, 20 nm, and 27 nm, were synthesized to study the enhancement effect of distance. With the increase of SiO2 shell, the fluorescence of Ag@SiO2@NH2-C-QDs nanocomposites rise first but then fall while the sample with the 20-nm shell obtained the best enhancement effect as high as 3.92-fold. Surface charge vibration of metal particles was used to explain this phenomenon.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Carbon and Quantum Dots Applications · Nanocluster Synthesis and Applications · Quantum Dots Synthesis And Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (25)

Show source-provided references
1. Bhunia SK, Pradhan N, Jana NR (2014) Vitamin B1 derived blue and green fluorescent carbon nanoparticles for cell-imaging application. ACS Appl Mater Interfaces 6:7672–767910.1021/am500964d ↗
2. Cheng H, Zhao Y, Fan Y, Xie X, Qu L, Shi G (2012) Graphene-quantum-dot assembled nanotubes: a new platform for efficient Raman enhancement. ACS Nano 6:2237–224410.1021/nn204289t ↗
3. Corrigan T, Guo S-H, Szmacinski H, Phaneuf R (2006) Systematic study of the size and spacing dependence of Ag nanoparticle enhanced fluorescence using electron-beam lithography. Appl Phys Lett 88:10111210.1063/1.2176862 ↗
4. Cui Q, He F, Wang X, Xia B, Li L (2012) Gold nanoflower@ gelatin core–shell nanoparticles loaded with conjugated polymer applied for cellular imaging. ACS Appl Mater Interfaces 5:213–21910.1021/am302589g ↗
5. Deng Y-L, Xu D-D, Pang D-W, Tang H-W (2017) Target-triggered signal turn-on detection of prostate specific antigen based on metal-enhanced fluorescence of Ag@ SiO2@ SiO2-RuBpy composite nanoparticles. Nanotechnology 28:06550110.1088/1361-6528/28/6/065501 ↗
6. Falco W, Queiroz A, Fernandes J, Botero E, Falcão E, Guimarães F, M’Peko J-C, Oliveira S, Colbeck I, Caires A (2015) Interaction between chlorophyll and silver nanoparticles: a close analysis of chlorophyll fluorescence quenching. J Photochem Photobiol A 299:203–20910.1016/j.jphotochem.2014.12.001 ↗
7. Gao X, Lu Y, Zhang R, He S, Ju J, Liu M, Li L, Chen W (2015) One-pot synthesis of carbon nanodots for fluorescence turn-on detection of Ag+ based on the Ag+-induced enhancement of fluorescence. J Mater Chem C 3:2302–230910.1039/C4TC02582B ↗
8. Guidelli E, Baffa O, Clarke D (2015) Enhanced UV emission from silver/ZnO and gold/ZnO core-shell nanoparticles: photoluminescence, radioluminescence, and optically stimulated luminescence. Sci Rep 5:1400410.1038/srep14004 ↗
9. Hou J-W, Yang X-C, Cui M-M, Huang M, Wang Q-Y (2012) Synthesis of silver particles decorated anodic aluminium oxide substrates for metal-enhanced fluorescence. Micro Nano Lett 7:842–84510.1049/mnl.2012.0407 ↗
10. Kang KA, Wang J, Jasinski JB, Achilefu S (2011) Fluorescence manipulation by gold nanoparticles: from complete quenching to extensive enhancement. J Nanobiotechnol 9:1610.1186/1477-3155-9-16 ↗
11. Kowalska D, Krajnik B, Olejnik M, Twardowska M, Czechowski N, Hofmann E, Mackowski S (2013) Metal-enhanced fluorescence of chlorophylls in light-harvesting complexes coupled to silver nanowires. Sci World J:201310.1155/2013/670412 ↗
12. Lakowicz JR (2001) Radiative decay engineering: biophysical and biomedical applications. Anal Biochem 298:1–2410.1006/abio.2001.5377 ↗
13. Li X, Que L (2014) Fluorescence enhancement enabled by nanomaterials and nanostructured substrates: a brief review. Rev Nanosci Nanotechnol 3:161–17610.1166/rnn.2014.1053 ↗
14. Li C, Zhu Y, Zhang X, Yang X, Li C (2012) Metal-enhanced fluorescence of carbon dots adsorbed Ag@ SiO 2 core-shell nanoparticles. RSC Adv 2:1765–176810.1039/c2ra01032a ↗
15. Lim SY, Shen W, Gao Z (2015) Carbon quantum dots and their applications. Chem Soc Rev 44:362–38110.1039/C4CS00269E ↗
16. Pang Y, Rong Z, Xiao R, Wang S (2015) “Turn on” and label-free core− shell Ag@ SiO 2 nanoparticles-based metal-enhanced fluorescent (MEF) aptasensor for Hg 2+. Sci Rep 5:945110.1038/srep09451 ↗
17. Peng Z, Han X, Li S, Al-Youbi AO, Bashammakh AS, El-Shahawi MS, Leblanc RM (2017) Carbon dots: biomacromolecule interaction, bioimaging and nanomedicine. Coord Chem Rev 343:256–27710.1016/j.ccr.2017.06.001 ↗
18. Qian ZS, Shan XY, Chai LJ, Ma JJ, Chen JR, Feng H (2014) DNA nanosensor based on biocompatible graphene quantum dots and carbon nanotubes. Biosens Bioelectron 60:64–7010.1016/j.bios.2014.04.006 ↗
19. Saboktakin M, Ye X, Chettiar UK, Engheta N, Murray CB, Kagan CR (2013) Plasmonic enhancement of nanophosphor upconversion luminescence in Au nanohole arrays. ACS Nano 7:7186–719210.1021/nn402598e ↗
20. Schneider J, Reckmeier CJ, Xiong Y, von Seckendorff M, Susha AS, Kasák P, Rogach AL (2017) Molecular fluorescence in citric acid-based carbon dots. J Phys Chem C 121:2014–202210.1021/acs.jpcc.6b12519 ↗
21. Theodorou IG, Jawad ZA, Jiang Q, Aboagye EO, Porter AE, Ryan MP, Xie F (2017) Gold nanostar substrates for metal-enhanced fluorescence through the first and second near-infrared windows. Chem Mater 29:6916–692610.1021/acs.chemmater.7b02313 ↗
22. Wang Q, Zhang S, Ge H, Tian G, Cao N, Li Y (2015) A fluorescent turn-off/on method based on carbon dots as fluorescent probes for the sensitive determination of Pb2+ and pyrophosphate in an aqueous solution. Sensors Actuators B Chem 207:25–3310.1016/j.snb.2014.10.096 ↗
23. Xie F, Pang JS, Centeno A, Ryan MP, Riley DJ, Alford NM (2013) Nanoscale control of Ag nanostructures for plasmonic fluorescence enhancement of near-infrared dyes. Nano Res 6:496–51010.1007/s12274-013-0327-5 ↗
24. Ye Z, Tang R, Wu H, Wang B, Tan M, Yuan J (2014) Preparation of europium complex-conjugated carbon dots for ratiometric fluorescence detection of copper (II) ions. New J Chem 38:5721–572610.1039/C4NJ00966E ↗
25. Yuan H, Khatua S, Zijlstra P, Yorulmaz M, Orrit M (2013) Thousand-fold enhancement of single-molecule fluorescence near a single gold nanorod. Angew Chem Int Ed 52:1217–122110.1002/anie.201208125 ↗