journal article·2013-06

Effects of alkaline precipitating agents on synthesis of magnetite nanomaterials by hydrothermal d-glucose method

Wei Zhang, Shao-yi Jia, Song-hai Wu, Shao-feng Zhang, Yan Liu

Journal of Nanoparticle Research· Volume 15· Issue 6
Publisher page

Abstract

Pure magnetite (Fe3O4) nanoparticles and carbon-coated magnetite (Fe3O4/C) nanocomposites were facilely synthesized in a hydrothermal reaction system by changing sodium hydroxide and sodium acetate as the precipitating agents, respectively. The sizes of pure Fe3O4 nanoparticles and Fe3O4/C nanocomposites with core–shell structure were varied from 10 to 120 nm, and the magnetic properties of these two samples performed as superparamagnetic and ferrimagnetic. A possible formation mechanism for these two types of magnetite nanomaterials was discussed. It was the different alkali environments provided by the precipitating agents that led to the varieties in morphology, structure, and property of the final magnetite nanomaterials.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Nanoparticle-Based Drug Delivery · Iron oxide chemistry and applications · Nanomaterials for catalytic reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (24)

Show source-provided references
1. Akhtar J, Kuang SK, Amin NS (2010) Liquefaction of empty palm fruit bunch (EPFB) in alkaline hot compressed water. Renew Energy 35(6):1220–122710.1016/j.renene.2009.10.003 ↗
2. Cakan RD, Baccile N, Antonietti M, Titirici MM (2009) Carboxylate-rich carbonaceous materials via one-step hydrothermal carbonization of glucose in the presence of acrylic acid. Chem Mater 21(3):484–49010.1021/cm802141h ↗
3. Faria DLA, Silva SV, Oliveira MT (1997) Raman microspectroscopy of some iron oxides and oxyhydroxides. J Raman Spectrosc 28(11):873–87810.1002/(SICI)1097-4555(199711)28:11<873::AID-JRS177>3.0.CO;2-B ↗
4. Kim DK, Mikhaylova M, Zhang Y, Muhammed M (2003) Protective coating of superparamagnetic iron oxide nanoparticles. Chem Mater 15(8):1617–162710.1021/cm021349j ↗
5. Laurent S, Forge D, Port M, Roch A, Robic C, Elst LV, Muller RN (2008) Magnetic iron oxide nanoparticles: synthesis, stabilization, vectorization, physicochemical characterizations, and biological applications. Chem Rev 108(10):2064–211010.1021/cr068445e ↗
6. Lu AH, Salabas EL, Schüth F (2007) Magnetic nanoparticles: synthesis, protection, functionalization and application. Angew Chem Int Ed 46(8):1222–124410.1002/anie.200602866 ↗
7. Lu WS, Shen YH, Xie AJ, Zhang WQ (2010) Green synthesis and characterization of superparamagnetic Fe3O4 nanoparticles. J Magn Magn Mater 322(13):1828–183310.1016/j.jmmm.2009.12.035 ↗
8. Qiao RR, Yang CH, Gao MY (2009) Superparamagnetic iron oxide nanoparticles: from preparations to in vivo MRI applications. J Mater Chem 19(35):6274–629310.1039/b902394a ↗
9. Rossi LM, Parize AL, Rubim JC (2010) Green synthesis and applications of magnetic nanoparticles. In: Anastas PT (ed) Handbook of green chemistry, vol 8. Wiley-VCH, Weinheim, pp 61–78
10. Ryu J, Suh YW, Suh DJ, Ahn DJ (2010) Hydrothermal preparation of carbon microspheres from mono-saccharides and phenolic compounds. Carbon 48(7):1990–199810.1016/j.carbon.2010.02.006 ↗
11. Senthil M, Ramesh C (2012) Biogenic synthesis of Fe3O4 nanoparticles using Tridax procumbens leaf extract and its antibacterial activity on Pseudomonas aeruginosa. Dig J Nanomater Bios 7(3):1655–1661
12. Sevilla M, Fuertes AB (2009) Chemical and structural properties of carbonaceous products obtained by hydrothermal carbonization of saccharides. Chem Eur J 15(16):4195–420310.1002/chem.200802097 ↗
13. Sun XM, Li YD (2004) Colloidal carbon spheres and their core/shell structures with noble-metal nanoparticles. Angew Chem Int Ed 43(5):597–60110.1002/anie.200352386 ↗
14. Sun XH, Zheng CM, Zhang FX, Yang YL, Wu GJ, Yu AM, Guan NJ (2009) Size-controlled synthesis of magnetite (Fe3O4) nanoparticles coated with glucose and gluconic acid from a single Fe(III) precursor by a sucrose bifunctional hydrothermal method. J Phys Chem C 113(36):16002–1600810.1021/jp9038682 ↗
15. Wan J, Cai W, Meng X, Liu E (2007) Monodisperse water-soluble magnetite nanoparticles prepared by polyol process for high-performance magnetic resonance imaging. Chem Commun 47:5004–500610.1039/b712795b ↗
16. Wang Q, Li H, Chen LQ, Huang XJ (2001) Monodispersed hard carbon spherules with uniform nanopores. Carbon 30(14):2211–221410.1016/S0008-6223(01)00040-9 ↗
17. Wei XW, Zhu GX, Xia CJ, Ye Y (2006) A solution phase fabrication of magnetic nanoparticles encapsulated in carbon. Nanotechnology 17(17):4307–431110.1088/0957-4484/17/17/004 ↗
18. Wu W, He QG, Jiang CZ (2008) Magnetic iron oxide nanoparticles: synthesis and surface functionalization strategies. Nanoscale Res Lett 3(11):397–41510.1007/s11671-008-9174-9 ↗
19. Xuan SH, Hao LY, Jiang WQ, Gong XL, Hu Y, Chen ZY (2007) A facile method to fabricate carbon-encapsulated Fe3O4 core/shell composites. Nanotechnology 18(3):03560210.1088/0957-4484/18/3/035602 ↗
20. Yin SD, Mehrotra AK, Tan ZC (2011) Alkaline hydrothermal conversion of cellulose to bio-oil: influence of alkalinity on reaction pathway change. Bioresour Technol 102(11):6605–661010.1016/j.biortech.2011.03.069 ↗
21. Yu LH, Falco C, Weber J, White RJ, Howe JY, Titirici MM (2012) Carbohydrate-derived hydrothermal carbons: a thorough characterization study. Langmuir 28(33):12373–1238310.1021/la3024277 ↗
22. Zhang WM, Wu XL, Hu JS, Guo YG, Wan LJ (2008) Carbon coated Fe3O4 nanospindles as a superior anode material for lithium-ion batteries. Adv Funct Mater 18(24):3941–394610.1002/adfm.200801386 ↗
23. Zheng MT, Liu YL, Xiao Y, Zhu Y, Guan Q, Yuan DS, Zhang JX (2009) An easy catalyst-free hydrothermal method to prepare monodisperse carbon microspheres on a large scale. J Phys Chem C 113(19):8455–845910.1021/jp811356a ↗
24. Zhu T, Chen JS, Wen X, Lou D (2011) Glucose-assisted one-pot synthesis of FeOOH nanorods and their transformation to Fe3O4@ carbon nanorods for application in lithium ion batteries. J Phys Chem C 115(19):9814–982010.1021/jp2013754 ↗