β-(p-Carboxyaminophenyl)porphyrin derivatives: new dyes for TiO2 dye-sensitized solar cells
Source abstract
Abstract
New β-(p-carboxyaminophenyl)porphyrin derivatives were efficiently synthesized via palladium-catalysed amination of methyl 4-iodobenzoate with (2-amino-5-10,15,20-tetraphenylporphyrinato)nickel(II), followed by a demetallation/metallation sequence and basic hydrolysis. Optical and electrochemical studies revealed their potentiality for being considered as dyes in DSSCs devices, in which a power conversion efficiency of about 30 % of the more conventional Ru(II)-sensitizer N719 was achieved.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: TiO2 Photocatalysis and Solar Cells · Porphyrin and Phthalocyanine Chemistry · Advanced Photocatalysis Techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (58)
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