The preparation of nickel nanoparticles through a novel solid-state intramolecular reaction of polynuclear nickel(II) complex
Source abstract
Abstract
A novel solid-state reaction involving [Ni6(N2H4)6(SO4)4(OH)2(H2O)8](SO4)(H2O)10 has been used to prepare nickel nanoparticles. The reaction of [Ni6(N2H4)6(SO4)4(OH)2(H2O)8](SO4)(H2O)10 via NaOH, KOH, and/or Na2CO3 as a reactant was carried out in the solid state. The complex undergoes an intramolecular two-electron oxidation–reduction reaction at room temperature, producing metallic nickel nanoparticles (Ni1, Ni2 and Ni3). The aforementioned complex contains nickel(II) that is an oxidizing agent and also hydrazine ligand as a reducing agent. Other products produced include sodium azide and ammonia gas. The nickel metal nanoparticles were characterized using X-ray powder diffraction, scanning electron microscopy, and vibrating sample magnetometer. The synthesized nickel nanoparticles have similar morphologies; however, their particle size distributions are different.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Nanomaterials for catalytic reactions · Magnetism in coordination complexes · Nanocluster Synthesis and Applications
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References (29)
Show source-provided references
1. Anbar M (1965) Oxidation or reduction of ligands by metal ions in unstable states of oxidation. In: Kleinberg J, Murmann RK, Fraser RTM, Bauman J (eds) Mechanisms of inorganic reactions, vol 49. American Chemical Society, Washington10.1021/ba-1965-0049.ch006 ↗
2. Balaz P (2008) Mechanochemistry in nanoscience and minerals engineering. Springer, Berlin
3. Beyer MK, Schaumann HC (2005) Mechanochemistry: the mechanical activation of covalent bonds. Chem Rev 105:2921–294810.1021/cr030697h ↗
4. Blackman JA (2009) Metallic nanoparticles. In: Misra P (ed) Handbook of metal physics. Elsevier, Amsterdam
5. Boldyre VV, Tkacova K (2000) Mechanochemistry of solids: past, present, and prospects. J Mater Synth Process 8:121–13210.1023/A:1011347706721 ↗
6. Busch DH (1963) Reactions of coordinated ligands and homogeneous catalysis. American Chemical Society, Washington, D. C.
7. Constable ΕC (1996) Metals and ligand reactivity. Wiley-VCH Verlag, New York
8. Cushing BL, Kolesnichenko VL, OConnor CJ (2004) Recent advances in the liquid-phase syntheses of inorganic nanoparticles. Chem Rev 104:3893–394610.1021/cr030027b ↗
9. Dilworth JR (1976) The coordination chemistry of substituted hydrazines. Coord Chem Rev 21:29–6210.1016/S0010-8545(00)82050-0 ↗
10. Fernandez-Bertran JF (1999) Mechanochemistry: an overview. J Pure Appl Chem 71:581–58610.1351/pac199971040581 ↗
11. Gong W, Li H, Zhao Z, Chen J (1991) Ultrafine particles of Fe Co, and Ni ferromagnetic metals. J Appl Phys 69:5119–512110.1063/1.348144 ↗
12. Gubin SP (2009) Magnetic nanoparticles. Wiley-VCH, Verlag10.1002/9783527627561 ↗
13. Guo L, Liu C, Wang R, Xu H, Wu Z, Yang S (2004) Large-scale synthesis of uniform nanotubes of a nickel complex by a solution chemical route. J Am Chem Soc 126:4530–453110.1021/ja039381h ↗
14. Gustafsson M, Fischer A, Llyukhin A, Maliari M, Nordblad P (2010) Novel polynuclear nickel(II) complex: hydrazine, sulfato, and hydroxo bridging in an unusual metal hexamer crystal structure and magnetic properties of [Ni6(N2H4)6(SO4)4(OH)2(H2O)8](SO4)(H2O)10. Inorg Chem 49:5359–536110.1021/ic100648c ↗
15. Herzer G (1990) Grain-size dependence of coercivity and permeability in nanocrystalline ferromagnets. IEEE Trans Magn 26:1397–140210.1109/20.104389 ↗
16. Herzer G (1997) Nanocrystalline soft magnetic alloys. In: Buschow KHJ (ed) Handbook of magnetic materials, vol 10. Elsevier, Amsterdam, pp 415–462
17. House JE Jr (1993) Mechanistic considerations for anation reactions in the solid state. Coord Chem Rev 128:175–19110.1016/0010-8545(93)80029-5 ↗
18. Hysen T, Al-Harthi S, Al-Omari IA, Geetha P, Lisha R, Ramanujan RV, Sakthikumar D, Anantharaman MR (2013) Annealing induced low coercivity, nanocrystalline Co–Fe–Si thin films exhibiting inverse cosine angular variation. J Magn Magn Mater 341:165–17210.1016/j.jmmm.2013.04.032 ↗
19. Kahani SA, Jafari M (2009) A new method for preparation of magnetite from iron oxyhydroxide or iron oxide and ferrous salt in aqueous solution. J Magn Magn Mater 321:1951–195410.1016/j.jmmm.2008.12.026 ↗
20. Kahani SA, Sabeti M (2011) The mechanochemical oxidation of thiocyanate to polythiocyanogen (SCN)n using peroxydisulphate. J Inorg Organomet Polym 21:458–46410.1007/s10904-011-9478-6 ↗
21. Kurzawa J, Janowicz K, Suszka A (2001) Stopped-flow kinetic determination of thiocyanates and thiosulphates with the application of iodine-azide reaction. Anal Chim Acta 431:149–15510.1016/S0003-2670(00)01240-X ↗
22. Liu JP, Fullerton E, Gutfleisch O, Sellmyer DJ (2009) Nanoscale magnetic materials and applications. Springer, Berlin
23. Nakamoto K (1997) Infrared and Raman spectra of inorganic and coordination compounds, part B, 5th edn. Wiley, New York
24. Nicholls D, Swindells R (1968) Hydrazine complexes of nickel(II) chloride. J Inorg Nucl Chem 30:2211–221710.1016/0022-1902(68)80219-2 ↗
25. Papaefthymioua GC (2009) Nanoparticle magnetism. Nano Today 4:438–44710.1016/j.nantod.2009.08.006 ↗
26. Roduner E (2006) Nanoscopic materials size-dependent phenomena. The Royal Society of Chemistry, Cambridge10.1039/9781847557636 ↗
27. Schmidt E (1984) Hydrazine and its derivatives. Wiley, New York
28. Sunagawa I (2005) Crystals growth, morphology, and perfection. Cambridge University Press, Cambridge10.1017/CBO9780511610349 ↗
29. Taube H (1984) Electron transfer between metal complexes-retrospective. Science 226:1028–103610.1126/science.6494920 ↗