Sandwich Au/SMSiO2/Ag hybrid substrate: synthesis, characterization, and surface-enhanced Raman scattering performance
Source abstract
Abstract
Surface-enhanced Raman scattering (SERS) has been considered a high sensitivity, specificity, and ultra-fast analytical technique in molecular fingerprint recognition. Herein, a kind of sandwich Au/“star-like” mesoporous SiO2/Ag (Au/MSiO2/Ag) hybrid nanostructure was developed by implementing the electrostatic adsorption and magnetron sputtering technology for SERS application. In the experiment, the decoration density of the MSiO2/Ag nanostructure was conveniently adjusted through tuning the washing times of the silicon wafer in ethanol. The prepared substrate with the optimal geometry structure exhibited an enhancement factor (EF) of 9.2 × 105, a limit of detection (LOD) of 5 × 10−5 M, and a low relative standard deviation value of 5.02%. In the end, the obtained hybrid SERS substrate was used to detect nitrofurazone and an excellent LOD of 1 ppm was achieved. Overall, our novel sandwich Au/MSiO2/Ag hybrid SERS substrate provides a rapid and accurate way of monitoring ultra-low trace antibiotics, which can significantly promote food safety.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Gold and Silver Nanoparticles Synthesis and Applications · Biosensors and Analytical Detection · Advanced biosensing and bioanalysis techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (48)
Show source-provided references
1. Bian WW, Liu Z, Lian G, Wang L, Wang QL, Zhan JH (2017) High reliable and robust ultrathin-layer gold coating porous silver substrate via galvanic-free deposition for solid phase microextraction coupled with surface enhanced Raman spectroscopy. Anal Chim Atca 994:56–6410.1016/j.aca.2017.09.004 ↗
2. Bu YR, Liu K, Hu YX, Kaneti YV, Brioude A, Jiang XC, Wang HT, Yu AB (2017) Bilayer composites consisting of gold nanorods and titanium dioxide as highly sensitive and self-cleaning SERS substrates. Microchim Acta 184:2805–281310.1007/s00604-017-2301-5 ↗
3. Cardinal MF, Vander Ende E, Hackler RA, McAnally MO, Stair PC, Schatz GC, Van Duyne RP (2017) Expanding applications of SERS through versatile nanomaterials engineering. Chem Soc Rev 46:3886–390310.1039/C7CS00207F ↗
4. Cheong Y, Kim YJ, Kang H, Choi S, Lee HJ (2017) Rapid label-free identification of Klebsiella pneumoniae antibiotic resistant strains by the drop-coating deposition surface-enhanced Raman scattering method. Spectrochim Acta A 183:53–5910.1016/j.saa.2017.04.044 ↗
5. Deng Z, Chen M, Wu L (2007) Novel method to fabricate SiO2/Ag composite spheres and their catalytic, surface-enhanced Raman scattering properties. J Phys Chem C 111:11692–1169810.1021/jp073632h ↗
6. Fang JH, Huang YX, Li X, Dou XM (2004) Aggregation and surface-enhanced Raman activity study of dye-coated mixed silver–gold colloids. J Raman Spectrosc 35:914–92010.1002/jrs.1225 ↗
7. Fang H, Zhang CX, Liu L, Zhao YM, Xu HJ (2015) Recyclable three-dimensional Ag nanoparticle-decorated TiO2 nanorod arrays for surface-enhanced Raman scattering. Biosens Bloelectron 64:434–44110.1016/j.bios.2014.09.053 ↗
8. Guo YX, Zhuang ZF, Liu ZM, Fan WD, Zhong HQ, Zhang W, Ni YR, Guo ZY (2019) Facile hot spots assembly on molybdenum oxide nanosheets via in situ decoration with gold nanoparticles. Appl Surf Sci 480:1162–117010.1016/j.apsusc.2019.02.047 ↗
9. Gutés A, Carraro C, Maboudian R (2010) Silver dendrites from galvanic displacement on commercial aluminum foil as an effective SERS substrate. J Am Chem Soc 132:1476–147710.1021/ja909806t ↗
10. He Y, Su S, Xu TT, Zhong YL, Zapien JA, Li J, Fan CH, Lee ST (2011) Silicon nanowires-based highly-efficient SERS-active platform for ultrasensitive DNA detection. Nano Today 6:122–13010.1016/j.nantod.2011.02.004 ↗
11. Herrera GM, Padilla AC, Hernandez-Rivera SP (2013) Surface enhanced Raman scattering (SERS) studies of gold and silver nanoparticles prepared by laser ablation. Nanomaterials 3:158–17210.3390/nano3010158 ↗
12. Hong KY, De Albuquerque CDL, Poppi RJ, Brolo AG (2017) Determination of aqueous antibiotic solutions using SERS nanogratings. Anal Chim Acta 982:148–15510.1016/j.aca.2017.05.025 ↗
13. Jiang T, Li JP, Zhang L, Wang BB, Zhou J (2014a) Microwave assisted in situ synthesis of Ag–NaCMC films and their reproducible surface-enhanced Raman scattering signals. J Alloy Compd 602:94–10010.1016/j.jallcom.2014.03.020 ↗
14. Jiang T, Zhang L, Zhou J (2014b) Silver nanocube-mediated sensitive immunoassay based on surface-enhanced Raman scattering assisted by etched silicon nanowire arrays. Analyst 139:5893–590010.1039/C4AN01293C ↗
15. Jiang T, Wang XL, Tang J (2017) Synthesis and surface enhanced Raman scattering performance of Ag dendritic nanoplates with ultrasmall nanogaps. Optik 150:88–9310.1016/j.ijleo.2017.09.090 ↗
16. Jiang T, Chen G, Tian XL, Tang SW, Zhou J, Feng YH, Chen HY (2018) Construction of long narrow gaps in Ag nanoplates. J Am Chem Soc 140:15560–1556310.1021/jacs.8b06969 ↗
17. Kim KH, Baek YK, Jeon HJ, Srinivasarao M, Jung HT (2012) Cylindrical posts of Ag/SiO2/Au multi-segment layer patterns for highly efficient surface enhanced Raman scattering. Nanotechnology 23:31530210.1088/0957-4484/23/31/315302 ↗
18. Leitner A, Zöllner P, Lindner W (2001) Determination of the metabolites of nitrofuran antibiotics in animal tissue by high-performance liquid chromatography–tandem mass spectrometry. J Chromatogr A 939:49–5810.1016/S0021-9673(01)01331-0 ↗
19. Li J, Fang Y (2007) An investigation of the surface enhanced Raman scattering (SERS) from a new substrate of silver-modified silver electrode by magnetron sputtering. Spectrochim Acta A 66:994–100010.1016/j.saa.2006.05.012 ↗
20. Li P, Ge MH, Lin DY, Yang LB (2019) Functionalized acupuncture needle as a SERS-active platform for rapid and sensitive determination of adenosine triphosphate. Anal Bioanal Chem 411:5669–567910.1007/s00216-019-01945-5 ↗
21. Liao PF, Wokaun A (1982) Lightning rod effect in surface enhanced Raman scattering. J Chem Phys 76:751–75210.1063/1.442690 ↗
22. Liu K, Bai YC, Zhang L, Yang ZB, Fan QK, Zheng HQ, Yin YD, Gao CB (2016) Porous Au–Ag nanospheres with high-density and highly accessible hotspots for SERS analysis. Nano Lett 16:3675–368110.1021/acs.nanolett.6b00868 ↗
23. Long YJ, Wang XL, Chen D, Jiang T, Zhao ZQ, Zhou J (2016) Intense and stable surface-enhanced Raman scattering from Ag@mesoporous SiO2 film. J Lumin 177:387–39310.1016/j.jlumin.2016.05.024 ↗
24. Lu SC, You TT, Yang N, Gao YK, Yin PG (2020) Flexible SERS substrate based on Ag nanodendrite–coated carbon fiber cloth: simultaneous detection for multiple pesticides in liquid droplet. Anal Bioanal Chem 412:1159–116710.1007/s00216-019-02344-6 ↗
25. Ma Y, Du YY, Chen Y, Gu CJ, Jiang T, Wei GD, Zhou J (2020) Intrinsic Raman signal of polymer matrix induced quantitative multiphase SERS analysis based on stretched PDMS film with anchored Ag nanoparticles/Au nanowires. Chem Eng J 381:12271010.1016/j.cej.2019.122710 ↗
26. Malik P, Mukherjee TK (2018) Recent advances in gold and silver nanoparticle based therapies for lung and breast cancers. Int J Pharm 553:483–50910.1016/j.ijpharm.2018.10.048 ↗
27. Mo WY, Chen Z, Leung HM, Leung AOW (2017) Application of veterinary antibiotics in China’s aquaculture industry and their potential human health risks. Environ Sci Pollut R 24:8978–898910.1007/s11356-015-5607-z ↗
28. Pal AK, Pagal S, Prashanth K, Chandra GK, Umapathy S (2019) Ag/ZnO/Au 3D hybrid structured reusable SERS substrate as highly sensitive platform for DNA detection. Sensor Actuat B-Chem 279:157–16910.1016/j.snb.2018.09.085 ↗
29. Petchiappan A, Chatterji D (2017) Antibiotic resistance: current perspectives. ACS Omega 2:7400–740910.1021/acsomega.7b01368 ↗
30. Qiu HW, Wang MQ, Cao MG, Zhang L, Ji SD, Dou JJ, Ji YQ, Kou S, Guo J, Yang Z (2019) Self-cleaning SERS membrane for reusable and ultrasensitive molecular detection via integrating graphitic-carbon-nitride nanosheets and Ag nanospheres into hierarchical graphene layers that covered with graphitic-carbon-nitride quantum-dots. Appl Surf Sci 489:1010–101810.1016/j.apsusc.2019.05.349 ↗
31. Saute B, Narayanan R (2011) Solution-based direct readout surface enhanced Raman spectroscopic (SERS) detection of ultra-low levels of thiram with dogbone shaped gold nanoparticles. Analyst 136:527–53210.1039/C0AN00594K ↗
32. Sprigg K, Pietrangeli CE (2019) Bacterial antibiotic resistance: on the cusp of a post-antibiotic world. Curr Treat Option On 11:42–57
33. Su QQ, Ma XY, Dong J, Jiang CY, Qian WP (2011) A reproducible SERS substrate based on electrostatically assisted APTES-functionalized surface-assembly of gold nanostars. ACS Appl Mater Inter 3:1873–187910.1021/am200057f ↗
34. Su LJ, Xiong YH, Chen ZY, Duan ZH, Luo YH, Zhu DJ, Ma XH (2019) MoO3 nanosheet-assisted photochemical reduction synthesis of Au nanoparticles for surface-enhanced Raman scattering substrates. Sensor Actuat B-Chem 279:320–32610.1016/j.snb.2018.10.008 ↗
35. Tian YR, Liu HM, Chen Y, Zhou CL, Jiang Y, Gu CJ, Jiang T, Zhou J (2019) Seedless one-spot synthesis of 3D and 2D Ag nanoflowers for multiple phase SERS-based molecule detection. Sensor Actuat B-Chem 301:12714210.1016/j.snb.2019.127142 ↗
36. Wang CY, Behrens BC, Ichikawa M, Bryan GT (1974) Nitroreduction of 5-nitrofuran derivatives by rat liver xanthine oxidase and reduced nicotinamide adenine dinucleotide phosphate-cytochrome c reductase. Biochem Pharmacol 23:3395–340410.1016/0006-2952(74)90342-6 ↗
37. Wang XS, Yang DP, Huang P, Li M, Li C, Chen D, Cui DX (2012) Hierarchically assembled Au microspheres and sea urchin-like architectures: formation mechanism and SERS study. Nanoscale 4:7766–777210.1039/c2nr32405a ↗
38. Wang XL, Zhou L, Wei GD, Jiang T, Zhou J (2015) SERS-based immunoassay using a core-shell SiO2@Ag immune probe and Ag-decorated NiCo2O4 nanorods immune substrate. J Lumin 6:708–715
39. Wang CW, Wang JF, Li P, Rong Z, Jia XF, Ma QL, Xiao R, Wang SQ (2016) Sonochemical synthesis of highly branched flower-like Fe3O4@SiO2@Ag microcomposites and their application as versatile SERS substrates. Nanoscale 8:19816–1982810.1039/C6NR07295J ↗
40. Wang GL, Yi RH, Zhai XT, Bian RJ, Gao YQ, Cai DY, Liu JQ, Huang X, Lu G, Li H, Huang W (2018) A flexible SERS-active film for studying the effect of non-metallic nanostructures on Raman enhancement. Nanoscale 10:16895–1690110.1039/C8NR04971H ↗
41. Wang WE, Sang QQ, Yang M, Du J, Yang LB, Jiang X, Han XX, Zhao B (2020) Detection of several quinolone antibiotic residues in water based on Ag-TiO2 SERS strategy. Sci Total Environ 702:13495610.1016/j.scitotenv.2019.134956 ↗
42. Wei G, Zhou HL, Liu ZG, Li Z (2005) A simple method for the preparation of ultrahigh sensitivity surface enhanced Raman scattering (SERS) active substrate. Appl Surf Sci 240:260–26710.1016/j.apsusc.2004.06.116 ↗
43. Xie YF, Zhu XY, Sun YY, Wang HY, Qian H, Yao WR (2012) Rapid detection method for nitrofuran antibiotic residues by surface-enhanced Raman spectroscopy. Eur Food Res Technol 235:555–56110.1007/s00217-012-1752-5 ↗
44. Yang ZY, Liu HM, Tian YR, Chen Y, Niu ZQ, Zhou CL, Wang FY, Gu CJ, Tang SW, Jiang T, Zhou J (2020) Synergistic effect of a “stellate” mesoporous SiO2@Au nanoprobe and coffee-ring-free hydrophilic-hydrophobic substrate assembly in an ultrasensitive SERS-based immunoassay for a tumor marker. J Mater Chem C 8:2142–215410.1039/C9TC05646G ↗
45. Yu WS, Huang YQ, Pei L, Fan YX, Wang XH, Lai KQ (2014) Magnetic Fe3O4/Ag hybrid nanoparticles as surface-enhanced Raman scattering substrate for trace analysis of furazolidone in fish feeds. J Nanomater 103
46. Zhang LS, Zhang PX, Fang Y (2007) Magnetron sputtering of silver nanowires using anodic aluminum oxide template: a new active substrate of surface enhanced Raman scattering and an investigation of its enhanced mechanism. Anal Chim Acta 591:214–21810.1016/j.aca.2007.03.069 ↗
47. Zhang HJ, Li ZY, Xu PP, Wu RF, Jiao Z (2010) A facile two step synthesis of novel chrysanthemum-like mesoporous silica nanoparticles for controlled pyrene release. Chem Commun 46:6783–678510.1039/c0cc01673j ↗
48. Zheng YH, Rosa L, Thai T, Ng SH, Gómez DE, Ohshima H, Bach U (2015) Asymmetric gold nanodimer arrays: electrostatic self-assembly and SERS activity. J Mater Chem A 3:240–24910.1039/C4TA05307A ↗