Gold nanorods surface modified with poly(acrylic acid) as a template for the synthesis of metallic nanoparticles
Source abstract
Abstract
Poly(acrylic acid) (PAA) surface-modified gold nanorods, contained in deionized ultra filtered (DIUF) water, served as templates for the formation of gold (Au), palladium (Pd), and platinum (Pt) nanoparticles upon reduction with NaBH4. This provided nanoparticles with respective diameters of 7.0 ± 0.7, 4.1 ± 0.4, and 5.1 ± 0.5 nm. Varying amounts of Pt metal salt were used in EG, which acts as both a solvent and a reducing agent, ranging from 0.1, 0.2, and 1.0 mg/mL, to provide control over nanoparticle diameters of 2.0 ± 0.5 nm, to 4.0 ± 0.5 nm, and 6.2 ± 1.9 nm, respectively. Nanoparticle diameter was also controlled in DIUF water by varying the amount of Pt metal salt from 0.1, 0.2, and 1.0 mg/mL, producing Pt particle diameters, respectively, increasing from 2.7 ± 0.3 nm to 4.1 ± 0.5 nm, and 6.0 ± 0.6 nm.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Nanomaterials for catalytic reactions · Gold and Silver Nanoparticles Synthesis and Applications · Electrocatalysts for Energy Conversion
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (42)
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1. Abdelsayed V, Alsharaeh E, El-Shall MS (2006) Catalyzed radical polymerization of styrene vapor on nanoparticle surfaces and the incorporation of metal and metal oxide nanoparticles within polystyrene polymers. Phys Chem Lett B 110:19100–1910310.1021/jp064720p ↗
2. Andreas HA, Kung SKY, McLeod EJ, Young JL, Birss VI (2007) Optimization of synthesis parameters employed during Pt nanoparticle formation by in situ reduction. J Phys Chem C 111:13321–13330. doi: 10.1021/jp073111u10.1021/jp073111u ↗
3. Beecroft LL, Ober CK (1997) Nanocomposite materials for optical applications. Chem Mater 9:1302–1317. doi: 10.1021/cm960441a10.1021/cm960441a ↗
4. Bonet F, Guery C, Guyomard D, Urbina RH, Tekaia-Elhsissen K, Tarascon JM (1999) Electrochemical reduction of nobel metal compounds in ethylene glycol. Int J Inorg Mater 1:47–51. doi: 10.1016/S1463-0176(99)00007-110.1016/S1463-0176(99)00007-1 ↗
5. Boyes SG, Akgun B, Brittain WJ, Foster MD (2003) Synthesis, characterization, and properties of polyelectrolyte block copolymer brushes prepared by atom transfer radical polymerization and their use in the synthesis of metal nanoparticles. Macromolecules 36:9539–9548. doi: 10.1021/ma035029c10.1021/ma035029c ↗
6. Busbee BD, Obare SO, Murphy CJ (2003) An improved synthesis of high-aspect ratio gold nanorods. Adv Mater 15(5):414–416. doi: 10.1002/adma.20039009510.1002/adma.200390095 ↗
7. Chen CW, Serizawa T, Akashi M (2002) In situ formation of Au/Pt bimetallic colloids on polystyrene microspheres: control of particle growth and morphology. Chem Mater 14:2232–2239. doi: 10.1021/cm011634n10.1021/cm011634n ↗
8. Ciebien JF, Cohen RE, Duran A (1999) Membrane catalysts for partial hydrogenation of 1,3-butadiene: catalytic properties of palladium nanoclusters synthesized within diblock copolymer films. Mater Sci Eng C 7:45–50. doi: 10.1016/S0928-4931(98)00076-910.1016/S0928-4931(98)00076-9 ↗
9. Dai J, Bruening ML (2002) Catalytic nanoparticles formed by reduction of metal ions in multilayered polyelectrolyte films. Nano Lett 2(5):497–501. doi: 10.1021/nl025547l10.1021/nl025547l ↗
10. Daniel MC, Astruc D (2004) Gold nanoparticles: assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology. Chem Rev 104:293–346. doi: 10.1021/cr030698+10.1021/cr030698+ ↗
11. Feldheim DL, Grabar KC, Natan MJ, Mallouk TE (1996) Electron transfer in self-assembled inorganic polyelectrolyte/metal nanoparticle heterostructures. J Am Chem Soc 118:7640–7641. doi: 10.1021/ja961200710.1021/ja9612007 ↗
12. Gao J, Bender CM, Murphy CJ (2003) Dependence of the gold nanorod aspect ratio on the nature of the directing surfactant in aqueous solution. Langmuir 19:9065–9070. doi: 10.1021/la034919i10.1021/la034919i ↗
13. Garcia-Gutierrez DI, Gutierrez-Wing CE, Giovanetti L, Ramallo-Lopez JM, Requejo FG, Jose-Yacaman M (2005) Temperature effect on the synthesis of Au-Pt bimetallic nanoparticles. J Phys Chem B 109:3813–3821. doi: 10.1021/jp048114a10.1021/jp048114a ↗
14. Gole A, Murphy CJ (2004) Seed-mediated synthesis of gold nanorods: role of the size and nature of the seed. Chem Mater 16:3633–3640. doi: 10.1021/cm049233610.1021/cm0492336 ↗
15. Gole A, Murphy CJ (2005) Polyelectrolyte-coated gold nanorods: synthesis, characterization and immobilization. Chem Mater 17:1325–1330. doi: 10.1021/cm048297d10.1021/cm048297d ↗
16. Gole A, Stone JW, Gemmill WR, zur Loye HC, Murphy CJ (2008) Iron oxide coated gold nanorods: synthesis, characterization, and magnetic manipulation. Langmuir 24:6232–6237. doi: 10.1021/la703975y10.1021/la703975y ↗
17. Guo G, Qin F, Yang D, Wang C, Xu H, Yang S (2008) Synthesis of platinum nanoparticles supported on poly(acrylic acid) grafted MWNTs and their hydrogenation of citral. Chem Mater 20:2291–2297. doi: 10.1021/cm703225p10.1021/cm703225p ↗
18. Gur L, Fromer NA, Chen CP, Kanaras AG, Alivisatos AP (2007) Hybrid solar cells with prescribed nanoscale morphologies based on hyperbranched semiconductor nanocrystals. Nano Lett 7(2):409–414. doi: 10.1021/nl062660t10.1021/nl062660t ↗
19. Hotchkiss JW, Lowe AB, Boyes SG (2007) Surface modification of gold nanorods with polymers synthesized by reversible addition-fragmentation chain transfer polymerization. Chem Mater 19(1):6–13. doi: 10.1021/cm062291210.1021/cm0622912 ↗
20. Hu J, Odom TW, Lieber CM (1999) Chemistry and physics in one dimension: synthesis and properties of nanowires and nanotubes. Acc Chem Res 32:435–445. doi: 10.1021/ar970036510.1021/ar9700365 ↗
21. Huynh WU, Peng X, Alivisatos AP (1999) CdSe nanocrystal rods/poly(3-hexylthiophene) composite photovoltaic devices. Adv Mater 11(11):923–927. doi: 10.1002/(SICI)1521-4095(199908)11:11<923::AID-ADMA923>3.0.CO;2-T10.1002/(SICI)1521-4095(199908)11:11<923::AID-ADMA923>3.0.CO;2-T ↗
22. Huynh WU, Dittmer JJ, Alivisatos AP (2002) Hybrid nanorod-polymer solar cells. Science 295:2425–2427. doi: 10.1126/science.106915610.1126/science.1069156 ↗
23. Huynh WU, Dittmer JJ, Teclemariam N, Milliron DJ, Alivisatos AP (2003) Charge transport in hybrid nanorod-polymer composite photovoltaic cells. Phys Rev B 67(115326):1–12
24. Joly S, Kane R, Radzilowski L, Wang T, Wu A, Cohen RE, Thomas EL, Rubner MF (2000) Multilayer nanoreactors for metallic and semiconducting particles. Langmuir 16:1354–1359. doi: 10.1021/la991089t10.1021/la991089t ↗
25. Lai JT, Filla D, Shea R (2002) Functional polymers from novel carboxyl-terminated trithiocarbonates as highly efficient RAFT agents. Macromolecules 35:6754–6756. doi: 10.1021/ma020362m10.1021/ma020362m ↗
26. Murphy CJ, Sau TK, Gole A, Orendorff CJ, Goa J, Gou L, Hunyadi SE, Li T (2005) Anisotropic metal nanoparticles: synthesis, assembly, and optical applications. J Phys Chem B 109:13857–13870. doi: 10.1021/jp051684610.1021/jp0516846 ↗
27. Nakashima H, Furukawa K, Kashimura Y, Torimitsu K (2008) Self-Assembly of gold nanorods induced by intermolecular interactions of surface-anchored lipids. Langmuir 24:5654–5658. doi: 10.1021/la800318910.1021/la8003189 ↗
28. Narayanan R, El-Sayed MA (2008) Some aspects of colloidal nanoparticle stability, catalytic activity, and recycling potential. Top Catal 47:15–21. doi: 10.1007/s11244-007-9029-010.1007/s11244-007-9029-0 ↗
29. Sau TK, Murphy CJ (2004) Seeded high yield synthesis of short Au nanorods in aqueous solution. Langmuir 20:6414–6420. doi: 10.1021/la049463z10.1021/la049463z ↗
30. Schmitt J, Decher G, Dressick WJ, Brandow SL, Geer RE, Shashidar R, Calvert JM (1997) Metal nanoparticle/polymer superlattice films: fabrication and control of layer structure. Adv Mater 9(1):61–65. doi: 10.1002/adma.1997009011410.1002/adma.19970090114 ↗
31. Schuetz P, Caruso F (2003) Copper-assisted weak polyelectrolyte multilayer formation on microspheres and subsequent film crosslinking. Adv Funct Mater 13(12):929–937. doi: 10.1002/adfm.20030448310.1002/adfm.200304483 ↗
32. Schuetz P, Caruso F (2004) Semiconductor and metal nanoparticle formation on polymer spheres coated with weak polyelectrolyte multilayers. Chem Mater 16:3066–3073. doi: 10.1021/cm049957h10.1021/cm049957h ↗
33. Shiratori SS, Rubner MF (2000) pH-dependent thickness behavior of sequentially adsorbed layers of weak polyelectrolytes. Macromolecules 33:4213–4219. doi: 10.1021/ma991645q10.1021/ma991645q ↗
34. Spain SG, Albertin L, Cameron NR (2006) Facile in situ preparation of biologically active multivalent glyconanoparticles. Chem Commun (Camb) 40:4198–4200. doi: 10.1039/b608383h10.1039/b608383h ↗
35. Sugimoto T (2000) Fine particles synthesis, characterization, and mechanisms of growth. Marcel Dekker, Basel10.1201/9781482269697 ↗
36. Sun B, Marx E, Greenham NC (2003) Photovoltaic devices using blends of branched CdSe nanoparticles and conjugated polymers. Nano Lett 3(7):961–963. doi: 10.1021/nl034289510.1021/nl0342895 ↗
37. Sun B, Snaith HJ, Dhoot AS, Westenhoff S, Greenham NC (2005) Vertically segregated hybrid blends for photovoltaic devices with improved efficiency. J Appl Phys 97(014914):1–6
38. Thomas KG, Barazzouk S, Ipe BI, Joseph STS, Kamat PV (2004) Uniaxial plasmon coupling through longitudinal self-assembly of gold nanorods. J Phys Chem B 108:13066–13068. doi: 10.1021/jp049167v10.1021/jp049167v ↗
39. Wang TC, Rubner MF, Cohen RE (2002) Polyelectrolyte multilayer nanoreactors for preparing silver nanoparticle composites: controlling metal concentration and nanoparticles size. Langmuir 18:3370–3375. doi: 10.1021/la015725a10.1021/la015725a ↗
40. Wu HY, Chu HC, Kuo TJ, Kuo CL, Huang MH (2005) Seed-mediated synthesis of high aspect ratio gold nanorods with nitric acid. Chem Mater 17:6447–6451. doi: 10.1021/cm051455w10.1021/cm051455w ↗
41. Zhou Y, Itoh H, Uemura T, Naka K, Chujo Y (2002) Synthesis of novel stable nanometer-sized metal (M = Pd, Au, Pt) colloids protected by a π-conjugated polymer. Langmuir 18:277–283. doi: 10.1021/la011323r10.1021/la011323r ↗
42. Ziolo RF, Giannelis EP, Weinstein BA, O’Horo MP, Ganguly BN, Mehrotra V, Russell MW, Huffman DR (1992) Matrix-mediated synthesis of nanocrystalline γ-Fe2O3: a new optically transparent magnetic material. Science 257:219–223. doi: 10.1126/science.257.5067.21910.1126/science.257.5067.219 ↗