Silver nanoparticles obtained with a glucose modified siloxane surfactant
Source abstract
Abstract
Silver nanoparticles were obtained in aqueous medium, at room temperature, by redox reactions, with or without glucose, in the presence of a glucose-containing cyclosiloxane. The siloxane surfactant can act as stabilizer when glucose is present in the system, but also as reducing agent and stabilizer when no glucose is added. The kinetics was followed by absorption UV–Vis spectroscopy, and different behaviors were found for the two versions of the redox process: first-order kinetics for the reaction with glucose and a much slower complex reaction with three zero-order steps when no glucose was added. The reactions were also investigated with IR absorption spectroscopy. The resulting nanoparticles were analyzed by dynamic light scattering (DLS), atomic force microscopy (AFM), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX) analysis, and transmision electron microscopy (TEM). All data showed evidence for the formation of silver spherical nanoparticles, with an average diameter of 14 nm (reaction with glucose) and 6.5 nm (reaction without glucose), respectively.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Gold and Silver Nanoparticles Synthesis and Applications · Nanoparticles: synthesis and applications · Nanoparticle-Based Drug Delivery
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (45)
Show source-provided references
1. Burt JL, Gutierrez-Wing C, Miki-Yoshida M, Jose-Yacaman MJ (2004) Noble-metal nanoparticles directly conjugated to globular proteins. Langmuir 20:11778–11783. doi: 10.1021/la048287r10.1021/la048287r ↗
2. Chauhan BPS, Rathore J, Sardar R, Tewari P, Latif U (2003) Synthesis, stabilization, and applications of nanoscopic siloxane-metal particle conjugates. J Organomet Chem 686:24–31. doi: 10.1016/S0022-328X(03)00612-010.1016/S0022-328X(03)00612-0 ↗
3. Crespilho FN, Iost RM, Travain SA, Oliveira ON Jr, Zucolotto V (2009) Enzyme immobilization on Ag nanoparticles/polyaniline nanocomposites. Biosens Bioelectron 24:3073–3077. doi: 10.1016/j.bios.2009.03.02610.1016/j.bios.2009.03.026 ↗
4. Crespy D, Landfester K (2009) Synthesis of polyvinylpyrrolidone/silver nanoparticles hybrid latex in non-aqueous miniemulsion at high temperature. Polymer 50:1616–1620. doi: 10.1016/j.polymer.2009.02.00310.1016/j.polymer.2009.02.003 ↗
5. Durán N, Marcato PD, Alves OL, De Souza GIH, Esposito E (2005) Mechanistic aspects of biosynthesis of silver nanoparticles by several Fusarium oxysporum strains. J Nanobiotechnol 3:8. doi: 10.1186/1477-3155-3-810.1186/1477-3155-3-8 ↗
6. Edington JW (1975) Electron diffraction in the electron microscope. Philips technical library series (2), Monographs in practical electron microscopy in materials science. Macmillan, London, p 11
7. Elechiguerra JL, Burt JL, Morones JR et al (2005) Interaction of silver nanoparticles with HIV-1. J Nanobiotechnol 3:6. doi: 10.1186/1477-3155-3-610.1186/1477-3155-3-6 ↗
8. Granot E, Katz E, Basnar B, Willner I (2005) Enhanced bioelectrocatalysis using Au-nanoparticle/polyaniline hybrid systems in thin films and microstructured rods assembled on electrodes. Chem Mater 17:4600–4609. doi: 10.1021/cm050193v10.1021/cm050193v ↗
9. Haes AJ, Hall WP, Chang L, Klein WL, Van Duyne RP (2004) A localized surface plasmon resonance biosensor: first steps toward an assay for Alzheimer’s disease. Nano Lett 4:1029–1034. doi: 10.1021/nl049670j10.1021/nl049670j ↗
10. Hou G, Zhu L, Chen D, Jiang M (2007) Core–shell reversion of hybrid polymeric micelles containing gold nanoparticles in the core. Macromolecules 40:2134–2140. doi: 10.1021/ma062373b10.1021/ma062373b ↗
11. Huang CJ, Shieu FS (2005) Micellization and morphological characterization of Ag-micelles prepared by poly(vinyl acetate)–silver nitrate in solvent/nonsolvent system. Colloid Polym Sci 284:192–202. doi: 10.1007/s00396-005-1360-z10.1007/s00396-005-1360-z ↗
12. Huang YF, Lin YW, Lin ZH, Chang HT (2009) Aptamer-modified gold nanoparticles for targeting breast cancer cells through light scattering. J Nanopart Res 11:775–783. doi: 10.1007/s11051-008-9424-x10.1007/s11051-008-9424-x ↗
13. Hvolbćk B, Janssens TVW, Clausen BS, Falsig H, Christensen CH, Nřrskov JK (2007) Catalytic activity of Au nanoparticles. Nano Today 2(4):14–18. doi: 10.1016/S1748-0132(07)70113-510.1016/S1748-0132(07)70113-5 ↗
14. Ishizu K, Furukawa T, Yamada H (2005) Silver nanoparticles dispersed within amphiphilic star-block copolymers as templates for plasmon band materials. Eur Polym J 41:2853–2860. doi: 10.1016/j.eurpolymj.2005.06.01410.1016/j.eurpolymj.2005.06.014 ↗
15. Jensen TR, Duval Malinsky M, Haynes CL, Van Duyne RP (2000) Nanosphere lithography: tunable localized surface plasmon resonance spectra of silver nanoparticles. J Phys Chem B 104:10549–10556. doi: 10.1021/jp002435e10.1021/jp002435e ↗
16. Kuo PL, Chen CC, Yuen SM (2004) Protection effects of hydrophile-grafted silicone copolymers on the formation of colloidal silver nanoparticles. J Phys Chem B 108:5541–5546. doi: 10.1021/jp031030210.1021/jp0310302 ↗
17. Lyu YY, Yi SH, Shon JK, Chang S, Pu LS, Lee SY, Yie JE, Char K, Stucky GD, Kim JM (2004) Highly stable mesoporous metal oxides using nano-propping hybrid gemini surfactants. J Am Chem Soc 126:2310–2311. doi: 10.1021/ja039034810.1021/ja0390348 ↗
18. Mock JJ, Barbic M, Smith DR, Schultz DA, Schultz S (2002) Shape effects in plasmon resonance of individual colloidal silver nanoparticles. J Chem Phys 116:6755–6759. doi: 10.1063/1.146261010.1063/1.1462610 ↗
19. Patakfalvi R, Diaz D, Velasco-Arias D, Rodriguez-Gattorno G, Santiago-Jacinto P (2008) Synthesis and direct interactions of silver colloidal nanoparticles with pollutant gases. Colloid Polym Sci 286:67–77. doi: 10.1007/s00396-007-1702-010.1007/s00396-007-1702-0 ↗
20. Peng S, Lee Y, Wang C, Yin H, Dai S, Sun S (2008) A facile synthesis of monodisperse Au nanoparticles and their catalysis of CO oxidation. Nano Res 1:229–234. doi: 10.1007/s12274-008-8026-310.1007/s12274-008-8026-3 ↗
21. Peng Z, Zhang J, Sun X, Yang J, Diao J (2009) The thermolysis behavior of Ag/PAMAMs nanocomposites. Colloid Polym Sci 287:609–614. doi: 10.1007/s00396-009-2015-210.1007/s00396-009-2015-2 ↗
22. Petit C, Lixon P, Pileni MP (1993) In situ synthesis of silver nanocluster in AOT reverse micelles. J Phys Chem 97:12974–12983. doi: 10.1021/j100151a05410.1021/j100151a054 ↗
23. Prasad BLV, Stoeva SI, Sorensen CM, Zaikovski V, Klabunde KJ (2003) Gold nanoparticles as catalysts for polymerization of alkylsilanes to siloxane nanowires, filaments, and tubes. J Am Chem Soc 125:10488–10489. doi: 10.1021/ja035046h10.1021/ja035046h ↗
24. Racles C, Hamaide T (2005) Synthesis and characterization of water soluble saccharide functionalized polysiloxanes and their use as polymer surfactants for the stabilization of polycaprolactone nanoparticles. Macromol Chem Phys 206:1757–1768. doi: 10.1002/macp.20050013910.1002/macp.200500139 ↗
25. Racles C, Hamaide T, Ioanid A (2006) Siloxane surfactants in polymer nanoparticles formulation. Appl Organomet Chem 20:235–245. doi: 10.1002/aoc.105110.1002/aoc.1051 ↗
26. Racles C, Cazacu M, Hitruc G, Hamaide T (2009) On the feasibility of chemical reactions in the presence of siloxane-based surfactants. Colloid Polym Sci 287:461–470. doi: 10.1007/s00396-008-1991-y10.1007/s00396-008-1991-y ↗
27. Rodríguez-Abreu C, Lazzari M, Varade D, Kaneko M, Aramaki K, López Quintela MA (2007) Concentrated reverse micelles in a random graft block copolymer system: structure and in situ synthesis of silver nanoparticles. Colloid Polym Sci 285:673–680. doi: 10.1007/s00396-006-1612-610.1007/s00396-006-1612-6 ↗
28. Rutnakornpituk M, Thompson MS, Harris LA, Farmer KE, Esker AR, Riffle JS, Connolly J, St. Pierre TG (2002) Formation of cobalt nanoparticle dispersions in the presence of polysiloxane block copolymers. Polymer 43:2337–2348. doi: 10.1016/S0032-3861(02)00015-010.1016/S0032-3861(02)00015-0 ↗
29. Schüler T, Steinbrück A, Festag G, Möller R, Fritzsche W (2009) Enzyme-induced growth of silver nanoparticles studied on single particle level. J Nanopart Res 11:939–946. doi: 10.1007/s11051-008-9496-710.1007/s11051-008-9496-7 ↗
30. Silvert PY, Herrera-Urbinab R, Tekaia-Elhsissen K (1997) Preparation of colloidal silver dispersions by the polyol process. Part 2. Mechanism of particle formation. J Mater Chem 7:293–299. doi: 10.1039/a605347e10.1039/a605347e ↗
31. Sinha A, Sharma BP (2005) Preparation of silver powder through glycerol process. Bull Mater Sci 28:213–21710.1007/BF02711250 ↗
32. Sioss JA, Stoermer RL, Sha MY, Keating CD (2007) Silica-coated, Au/Ag striped nanowires for bioanalysis. Langmuir 23:11334–11341. doi: 10.1021/la701984610.1021/la7019846 ↗
33. Sondi I, Salopek-Sondi B (2004) Silver nanoparticles as antimicrobial agent: a case study on E. coli as a model for Gram-negative bacteria. J Colloid Interface Sci 275:177–182. doi: 10.1016/j.jcis.2004.02.01210.1016/j.jcis.2004.02.012 ↗
34. Thompson DT (2007) Using gold nanoparticles for catalysis. Nano Today 2(4):40–4310.1016/S1748-0132(07)70116-0 ↗
35. Vodnik VV, Vuković JV, Nedeljković JM (2009) Synthesis and characterization of silver—poly(methylmethacrylate) nanocomposites. Colloid Polym Sci 287:847–851. doi: 10.1007/s00396-009-2039-710.1007/s00396-009-2039-7 ↗
36. Voronov A, Kohut A, Peukert W (2007) Synthesis of amphiphilic silver nanoparticles in nanoreactors from invertible polyester. Langmuir 23:360–363. doi: 10.1021/la062737t10.1021/la062737t ↗
37. Voronov A, Kohut A, Vasylyev S, Peukert W (2008) Mechanism of silver ion reduction in concentrated solutions of amphiphilic invertible polyesters in nonpolar solvent at room temperature. Langmuir 24:12587–12594. doi: 10.1021/la801769v10.1021/la801769v ↗
38. Wang L, Chen D (2006) A one-pot approach to the preparation of silver-PMMA “shell–core” nanocomposite. Colloid Polym Sci 284:449–454. doi: 10.1007/s00396-005-1401-710.1007/s00396-005-1401-7 ↗
39. Xu AW (2002) Novel surfactants for the synthesis of unusual highly ordered lamellar oxides. J Phys Chem B 106:11713–11715. doi: 10.1021/jp026099910.1021/jp0260999 ↗
40. Xu X, Yang Q, Wang Y, Yu H, Chen X, Jing X (2006) Biodegradable electrospun poly(l-lactide) fibers containing antibacterial silver nanoparticles. Eur Polym J 42:2081–2087. doi: 10.1016/j.eurpolymj.2006.03.03210.1016/j.eurpolymj.2006.03.032 ↗
41. Yang Z, Chiu TC, Chang HT (2007) Preparation and characterization of different shapes of silver nanostructures in aqueous solution. Open Nanosci J 1:5–1210.2174/1874140100701010005 ↗
42. Yang J, Eom K, Lim EK et al (2008) In situ detection of live cancer cells by using bioprobes based on Au nanoparticles. Langmuir 24:12112–12115. doi: 10.1021/la802184m10.1021/la802184m ↗
43. Zhao M, Crooks RM (1999) Intradendrimer exchange of metal nanoparticles. Chem Mater 11:3379–3385. doi: 10.1021/cm990435p10.1021/cm990435p ↗
44. Zhou C, Khlestkin VK, Braeken D, De Keersmaecker K, Laureyn W, Engelborghs Y, Borghs G (2005) Solvent-controlled organization of self-assembled polymeric monolayers on gold: an easy approach for the construction of protein resistant surfaces. Langmuir 21:5988–5996. doi: 10.1021/la047159010.1021/la0471590 ↗
45. Zhu J, Liu S, Palchik O, Koltypin Y, Gedanken A (2000) Shape-controlled synthesis of silver nanoparticles by pulse sonoelectrochemical methods. Langmuir 16:6396–6399. doi: 10.1021/la991507u10.1021/la991507u ↗