journal article·2026-04

Enhancing EDLC–pseudocapacitive performance of flexible CeO2 electrode via design of Ni-doped CeO2 nanoparticles grafted @ chitosan biopolymer hybrid framework for supercapacitor applications

M. Vanitha, Nitin Kundlik Kamble, P. Vinayagam, T. Muthukumar, M. S. S. Sasikumar, S. Kumaran

Journal of Nanoparticle Research· Volume 28· Issue 4
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OpenAlex topics: Supercapacitor Materials and Fabrication · Catalytic Processes in Materials Science · Aerogels and thermal insulation

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References (61)

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1. Tomy M, Ambika Rajappan A, Vm V, Thankappan Suryabai X (2021) Emergence of novel 2D materials for high-performance supercapacitor electrode applications: a brief review. Energy Fuels 35:19881–19900. https://doi.org/10.1021/acs.energyfuels.1c0274310.1021/acs.energyfuels.1c02743 ↗
2. Portet C, Taberna PL, Simon P, Flahaut E, Laberty-Robert C (2005) High power density electrodes for carbon supercapacitor applications. Electrochim Acta 50:4174–4181. https://doi.org/10.1016/j.electacta.2005.01.03810.1016/j.electacta.2005.01.038 ↗
3. Teli AM, Beknalkar SA, Satale VV, Yewale MA, Amate RU, Morankar PJ et al (2024) Innovations in metal telluride composite materials towards enhancing supercapacitor energy storage. J Alloys Compd 1005:175950. https://doi.org/10.1016/j.jallcom.2024.17595010.1016/j.jallcom.2024.175950 ↗
4. Arunkumar K, Kamalakkannan D, Kamalarajan P, Chanthirasekaran K, Kumaran S, Basha CZ (2026) Boosting the electrochemical performance of cobalt hexacyanoferrate via sulfur-doped reduced graphene oxide hybridization. Ionics 32:1–17. https://doi.org/10.1007/s11581-026-06968-410.1007/s11581-026-06968-4 ↗
5. Yewale MA, Shin DK, Alam MW, Teli AM, Nabi S, Ansari SA et al (2024) Controlled synthesis and electrochemical characterization of Co3V2O8 hexagonal sheets for energy storage applications. Colloids Surf A Physicochem Eng Asp 703:135180. https://doi.org/10.1016/j.colsurfa.2024.13518010.1016/j.colsurfa.2024.135180 ↗
6. Desarada SV, Yewale MA, Vallabhapurapu S, Vallabhapurapu VS, Dhas SD, Al-Kahtani AA et al (2024) Multiwalled carbon nanotube-cobalt vanadium oxide composite for high-performance supercapacitor electrodes with enhanced power density and cycling stability. Diamond Relat Mater 149:111557. https://doi.org/10.1016/j.diamond.2024.11155710.1016/j.diamond.2024.111557 ↗
7. Roy BK, Tahmid I, Rashid TU (2021) Chitosan-based materials for supercapacitor applications: a review. J Mater Chem A 9:17592–17642. https://doi.org/10.1039/d1ta02997e10.1039/d1ta02997e ↗
8. Wang YY, Hou BH, Lü HY, Wan F, Wang J, Wu XL (2015) Porous N-doped carbon material derived from prolific chitosan biomass as a high-performance electrode for energy storage. RSC Adv 5:97427–97434. https://doi.org/10.1039/c5ra20933a10.1039/c5ra20933a ↗
9. Zhang S, Wang Z, Yang S, Hao D, Yu S, Wu Q (2024) Chitosan modified graphene oxide with MnO2 deposition for high energy density flexible supercapacitors. Int J Biol Macromol 259:129223. https://doi.org/10.1016/j.ijbiomac.2024.12922310.1016/j.ijbiomac.2024.129223 ↗
10. Nandi D, Mohan VB, Bhowmick AK, Bhattacharyya D (2020) Metal/metal oxide decorated graphene synthesis and application as supercapacitor: a review. J Mater Sci 55:6375–6400. https://doi.org/10.1007/s10853-020-04475-z10.1007/s10853-020-04475-z ↗
11. Sharma P, Kumar V (2020) Current technology of supercapacitors: a review. J Electron Mater 49:3520–3532. https://doi.org/10.1007/s11664-020-07992-410.1007/s11664-020-07992-4 ↗
12. Maheswari N, Muralidharan G (2015) Supercapacitor behavior of cerium oxide nanoparticles in neutral aqueous electrolytes. Energy Fuels 29:8246–8253. https://doi.org/10.1021/acs.energyfuels.5b0214410.1021/acs.energyfuels.5b02144 ↗
13. Joseph A, Perikkathra S, Thomas T (2023) Novel 2D CeO2 nanoflakes as a high-performance asymmetric supercapacitor electrode material. J Energy Storage 68:107757. https://doi.org/10.1016/j.est.2023.10775710.1016/j.est.2023.107757 ↗
14. Krishnan PH, Sul RD, Murugan MS, Saravanan V (2025) Optimization of La and Ce mixed metal oxide hybrid for enhanced photoresponse in UV–Visible photosensing applications. J Mater Sci Mater Electron 36:1377. https://doi.org/10.1007/s10854-025-15431-510.1007/s10854-025-15431-5 ↗
15. Wang H, Liang M, Zhang X, Duan D, Shi W, Song Y, Sun Z (2018) Novel CeO2 nanorod framework prepared by dealloying for supercapacitors applications. Ionics 24:2063–2072. https://doi.org/10.1007/s11581-018-2443-410.1007/s11581-018-2443-4 ↗
16. Murugadoss G, Ma J, Ning X, Kumar MR (2019) Selective metal ions doped CeO2 nanoparticles for excellent photocatalytic activity under sun light and supercapacitor application. Inorg Chem Commun 109:107577. https://doi.org/10.1016/j.inoche.2019.10757710.1016/j.inoche.2019.107577 ↗
17. Veena B, Pavithra S, Seetha M, Sakunthala A, Masuda Y (2022) Cr doped CeO2 nanoparticles as supercapacitor electrodes. AIP Adv. https://doi.org/10.1063/5.013049910.1063/5.0130499 ↗
18. Ponnar M, Pushpanathan K, Santhi R, Ravichandran S (2020) Enhanced supercapacitor performance and ferromagnetic behavior of Ni-doped CeO2 quantum dots. J Mater Sci Mater Electron 31:12661–12677. https://doi.org/10.1007/s10854-020-03816-710.1007/s10854-020-03816-7 ↗
19. Alex J, Rajkumar S, PrincyMerlin J, Aravind A, Sajan D, Praveen CS (2021) Single step auto-igniting combustion technique grown CeO2 and Ni-doped CeO2 nanostructures for multifunctional applications. J Alloys Compd 882:160409. https://doi.org/10.1016/j.jallcom.2021.16040910.1016/j.jallcom.2021.160409 ↗
20. Farahmandjou M, Zarinkamar M, Firoozabadi TP (2016) Synthesis of cerium oxide (CeO2) nanoparticles using simple co-precipitation method. Rev Mex Fis 62:496–499
21. Kopka R (2017) Estimation of supercapacitor energy storage based on fractional differential equations. Nanoscale Res Lett 12:636. https://doi.org/10.1186/s11671-017-2396-y10.1186/s11671-017-2396-y ↗
22. Hidalgo-Reyes JI, Gómez-Aguilar JF, Escobar-Jimenez RF, Alvarado-Martinez VM, Lopez-Lopez MG (2019) Determination of supercapacitor parameters based on fractional differential equations. Int J Circuit Theory Appl 47:1225–1253. https://doi.org/10.1002/cta.264010.1002/cta.2640 ↗
23. Dos Santos APB, Dantas TCM, Costa JAP, Souza LD, Soares JM, Caldeira VPS et al (2020) Formation of CeO2 nanotubes through different conditions of hydrothermal synthesis. Surf Interfaces 21:100746. https://doi.org/10.1016/j.surfin.2020.10074610.1016/j.surfin.2020.100746 ↗
24. Panahi-Kalamuei M, Alizadeh S, Mousavi-Kamazani M, Salavati-Niasari M (2015) Synthesis and characterization of CeO2 nanoparticles via hydrothermal route. J Ind Eng Chem 21:1301–1305. https://doi.org/10.1016/j.jiec.2014.05.04610.1016/j.jiec.2014.05.046 ↗
25. Nisha UM, Meeran MN, Sethupathi R, Subha V, Rajeswaran P, Sivakarthik P (2023) Studies on chitosan modified ZrO2–CeO2 metal oxide and their photocatalytic activity under solar light irradiation for water remediation. J Indian Chem Soc 100:101061. https://doi.org/10.1016/j.jics.2023.10106110.1016/j.jics.2023.101061 ↗
26. Nisha UM, Venkatesh D, Arulmurugan S, Kistan A, Rajeswaran P, Karthik PS (2024) Assessment of solar light sensitive chitosan integrated CeO2-CuO ternary composites for the efficient degradation of Malachite Green, Acid Blue 113 dyes and microbial studies. Inorg Chem Commun 160:111942. https://doi.org/10.1016/j.inoche.2023.11194210.1016/j.inoche.2023.111942 ↗
27. Shalini AS, Shahanaz L, Rajeswaran P, Tamilarasan R, Kumaran S, Karthik PS (2024) Facile green synthesis of gelatin sodium alginate cerium oxide hydrogel nanocomposite and their photocatalytic and its biological applications. Chem Pap 78:3111–3123. https://doi.org/10.1007/s11696-023-03297-y10.1007/s11696-023-03297-y ↗
28. Prabhu Chandran K, Nath SS, Sudha K, Vinod Kumar T, Kumaran S, Sasidevi J (2025) Strategic design of TiO2-SnS hybrid nanostructures: dual-function catalysts for antibiotic removal and solar energy conversion in DSSCs. J Electron Mater 54:10100–10116. https://doi.org/10.1007/s11664-025-12377-610.1007/s11664-025-12377-6 ↗
29. Syamala M, Srivastava D, Khandekar SD, Porselvi T, Patan MK, Balaram A, Kumaran S (2025) Construction of g-C3N4 anchored Cu-ZnS hybrid nanostructures for sustainable energy storage and environmental remediation. Res Chem Intermed 51:5479–5508. https://doi.org/10.1007/s11164-025-05713-210.1007/s11164-025-05713-2 ↗
30. Ahmed EM, Alkathiri AA (2022) Enhanced optical and electrical properties of CeO2NPs/chitosan nanocomposites. Mater Res Express 9:055305. https://doi.org/10.1088/2053-1591/ac6fbb10.1088/2053-1591/ac6fbb ↗
31. Sengeni D, Nadanasabai R, Saravanan V, Sangeetha L, Prakash JU (2024) Development of binary transition metallic selenide (NiSe/Co3Se4) hybrid counter electrode for highly efficient Pt-free dye-sensitized solar cells. Ionics 30:8281–8293. https://doi.org/10.1007/s11581-024-05871-010.1007/s11581-024-05871-0 ↗
32. Arunprasad V, Rapur P, Hemanand D et al (2025) Design and fabrication of nanoarchitectures of rGO-decorated ZnCo2O4 hybrid photocatalyst for high-efficiency solar fuel generation. J Mater Sci Mater Electron 36:192. https://doi.org/10.1007/s10854-025-14285-110.1007/s10854-025-14285-1 ↗
33. Larachi F, Pierre J, Adnot A, Bernis A (2002) Ce 3d XPS study of composite CexMn1−xO2−y wet oxidation catalysts. Appl Surf Sci 195:236–250. https://doi.org/10.1016/s0169-4332(02)00559-710.1016/s0169-4332(02)00559-7 ↗
34. Hemalatha R, Kumar CV, Kumaran N, Kumaran S (2026) Green synthesis of mesoporous TiO2 nanosheets using Rosmarinus officinalis leaf extract for multifunctional applications in DSSCs, photocatalysis, and supercapacitors. J Porous Mater 33:1–14. https://doi.org/10.1007/s10934-025-01914-710.1007/s10934-025-01914-7 ↗
35. Nath SS, Vp SP, Saraswathi M, Sampath K, Rangaree P, Kumaran S (2025) Facile hydrothermal synthesis of rGO@MnCo₂S₄ hybrid electrodes for high-performance asymmetric supercapacitors. J Porous Mater 32:1–13. https://doi.org/10.1007/s10934-025-01903-w10.1007/s10934-025-01903-w ↗
36. Fang Z, Gao L, Chen H, Liang K, Liu Z, Guan Z, Zhang J (2020) XPS study of probing evidence for displacive disorder in Ni-doped bismuth magnesium niobate pyrochlore. Mater Sci Eng B 259:114601. https://doi.org/10.1016/j.mseb.2020.11460110.1016/j.mseb.2020.114601 ↗
37. Suganthi V, Uthayakumar B, Kumaran S, Sukandhiya S, Sasidevi J, Srinivasan P et al (2025) Synergistic bandgap engineering of Nd2O3/Sr0.5Zn0.5Cr2O4 heterostructures for enhanced photoanode performance in dye-sensitized solar cells. J Mater Sci Mater Electron 36:2213. https://doi.org/10.1007/s10854-025-16298-210.1007/s10854-025-16298-2 ↗
38. Yumitori S (2000) Correlation of C1s chemical state intensities with the O1s intensity in the XPS analysis of anodically oxidized glass-like carbon samples. J Mater Sci 35:139–146. https://doi.org/10.1023/a:100476110391910.1023/a:1004761103919 ↗
39. Li Y, Zhu L, Shi J, Dou Y, Li S, You R et al (2021) Super-hydrophilic microporous biochar from biowaste for supercapacitor application. Appl Surf Sci 561:150076. https://doi.org/10.1016/j.apsusc.2021.15007610.1016/j.apsusc.2021.150076 ↗
40. Nath SS, Chanthirasekaran K, Priya SS, Bharathirja N, Gupta D, Kumaran S (2025) Boosting electrochemical behavior of biomass-derived porous carbon via N, S, and N, S co-doping for enhanced supercapacitor performance. Diamond Relat Mater 149:112850. https://doi.org/10.1016/j.diamond.2025.11285010.1016/j.diamond.2025.112850 ↗
41. Dayanithy M, Sekhar GC, Thivyarathi RC, Divyabharathi P, Maguluri LP, Saravanan V (2025) Synergistic integration of NiCo2O4 and NiWO4 nanosheets on Ni foam for advanced supercapacitor applications. J Porous Mater 32:2127–2137. https://doi.org/10.1007/s10934-025-01829-310.1007/s10934-025-01829-3 ↗
42. Saravanan V, Arthy M, Jayakar SA, Suganya S, Archana T, Thirumalai M (2025) Hierarchical ZnCo₂O₄/MoS₂@rGO nanocomposite on nickel foam: a promising electrode for advanced energy storage. Ionics 31:8749–8761. https://doi.org/10.1007/s11581-025-06399-710.1007/s11581-025-06399-7 ↗
43. Simsek UB, Çolak SG, Güngör A, Çolak MÖA, Alturk RG, Erdem E, Demir M (2026) Facile synthesis of bimetallic metal-organic frameworks for enhanced supercapacitor performance. J Power Sources 663:238832. https://doi.org/10.1016/j.jpowsour.2025.23883210.1016/j.jpowsour.2025.238832 ↗
44. Teli AM, Beknalkar SA, Satale VV, Morankar PJ, Yewale MA, Shin JC (2023) Exploring the synergistic effect of palladium-doped molybdenum phosphate as an electrode material for high-performance asymmetric supercapacitor device. Surf Interfaces 40:103149. https://doi.org/10.1016/j.surfin.2023.10314910.1016/j.surfin.2023.103149 ↗
45. Hassan MM, Alharbi FF, Abo-Dief HM, Alzahrani E, Kumar A (2025) Design and synthesis of nanostructured cerium oxide anchored on polyaniline electrode for supercapacitors. J Organomet Chem 1005:123852. https://doi.org/10.1016/j.jorganchem.2025.12385210.1016/j.jorganchem.2025.123852 ↗
46. Asghar MA, Ahmad S, Alanazi AK, Demir M, Mansoor MA, Iqbal M (2025) Synergistic integration of reduced graphene oxide with Ti3CN MXene for superior electrochemical energy storage. Mater Today Commun 35:114273. https://doi.org/10.1016/j.mtcomm.2025.11427310.1016/j.mtcomm.2025.114273 ↗
47. Yewale MA, Morankar PJ, Kumar V, Teli AM, Beknalkar SA, Dhas SD, Shin DK (2024) Ni3V2O8 marigold structures with rGO coating for enhanced supercapacitor performance. Micromachines 15:930. https://doi.org/10.3390/mi1507093010.3390/mi15070930 ↗
48. Kenesi AG, Ghorbani M, Lashkenari MS (2022) High electrochemical performance of PANI/CdO nanocomposite based on graphene oxide as a hybrid electrode materials for supercapacitor application. Int J Hydrogen Energy 47:38849–38861. https://doi.org/10.1016/j.ijhydene.2022.09.04710.1016/j.ijhydene.2022.09.047 ↗
49. Iqbal J, Ansari MO, Numan A, Wageh S, Al-Ghamdi A, Alam MG et al (2020) Hydrothermally assisted synthesis of porous polyaniline@carbon nanotubes–manganese dioxide ternary composite for potential application in supercapattery. Polymers 12:2918. https://doi.org/10.3390/polym1212291810.3390/polym12122918 ↗
50. Aghamohammadi P, Üstün B, Akgül E, Altıncı OC, Kurtan Ü, Koç SN et al (2025) CrB MBene: synthesis, structural insights, and electrochemical performance assessment. J Alloys Compd 1040:183679. https://doi.org/10.1016/j.jallcom.2025.18367910.1016/j.jallcom.2025.183679 ↗
51. Teli AM, Beknalkar SA, Burungale VV, Amte RU, Morankar PJ, Satale VV et al (2024) Investigating the synergistic effects of NbCo-oxide composite electrodes in supercapacitor and water splitting applications via hydrothermal synthesis. J Energy Storage 86:111155. https://doi.org/10.1016/j.est.2024.11115510.1016/j.est.2024.111155 ↗
52. Relekar BP, Fulari AV, Rath MC, Fulari VJ, Lohar GM (2020) Modification in porous MnO2/PANI composite using high-energy electron irradiation for electrochemical supercapacitor. J Mater Sci Mater Electron 31:11741–11747. https://doi.org/10.1007/s10854-020-03725-910.1007/s10854-020-03725-9 ↗
53. Maheswari N, Muralidharan G (2016) Hexagonal CeO2 nanostructures: an efficient electrode material for supercapacitors. Dalton Trans 45:14352–14362. https://doi.org/10.1039/c6dt03032g10.1039/c6dt03032g ↗
54. Pandit B, Sankapal BR, Koinkar PM (2019) Novel chemical route for CeO2/MWCNTs composite towards highly bendable solid-state supercapacitor device. Sci Rep 9:5892. https://doi.org/10.1038/s41598-019-42301-y10.1038/s41598-019-42301-y ↗
55. Yoon JH, Jinsoo B, Cho I, Vinodh R, Pollet BG, Babu RS et al (2022) Novel supercapacitor electrode derived from one dimensional cerium hydrogen phosphate (1D-Ce(HPO4)2·xH2O). Molecules 27:7691. https://doi.org/10.3390/molecules2722769110.3390/molecules27227691 ↗
56. Padmanathan N, Selladurai S (2014) Shape controlled synthesis of CeO2 nanostructures for high performance supercapacitor electrodes. RSC Adv 4:6527–6534. https://doi.org/10.1039/c3ra43339k10.1039/c3ra43339k ↗
57. Ahmad N, Alghamdi AA, AL-Abdulkarim HA, Mustafa GM, Baghdadi N, Alharthi FA (2021) Structural, morphological, and electrochemical performance of CeO2/NiO nanocomposite for supercapacitor applications. Appl Sci 11:411. https://doi.org/10.3390/app1101041110.3390/app11010411 ↗
58. Liu Y, Chen J, Cui B, Yin P, Zhang C (2018) Design and preparation of biomass-derived carbon materials for supercapacitors: a review. C 4:53. https://doi.org/10.3390/c404005310.3390/c4040053 ↗
59. Hassan S, Suzuki M, Abd El-Moneim A (2014) Synthesis of MnO2–chitosan nanocomposite by one-step electrodeposition for electrochemical energy storage application. J Power Sources 246:68–73. https://doi.org/10.1016/j.jpowsour.2013.06.08510.1016/j.jpowsour.2013.06.085 ↗
60. Murugan R, Ravi G, Vijayaprasath G, Rajendran S, Thaiyan M, Nallappan M et al (2017) Ni–CeO2 spherical nanostructures for magnetic and electrochemical supercapacitor applications. Phys Chem Chem Phys 19:4396–4404. https://doi.org/10.1039/c6cp08281e10.1039/c6cp08281e ↗
61. Wang X, Wang T, Liu D, Guo J, Liu P (2016) Synthesis and electrochemical performance of CeO2/PPy nanocomposites: interfacial effect. Ind Eng Chem Res 55:866–874. https://doi.org/10.1021/acs.iecr.5b0389110.1021/acs.iecr.5b03891 ↗