journal article·2025-06

Carbon quantum dots (CQDs)-supported CeO2/Al2O3 with tunable band gap for the efficient degradation of plastic waste into porous carbon materials under mild conditions: experiment and DFT

Jessica Jhovana Villalba Arredondo, Cristian Brayan Palacios Cabrera, Carlos Alberto Huerta Aguilar, Jayanthi Narayanan, María del Carmen Durán Domínguez de Bazúa, Pandiyan Thangarasu, Eduardo Daniel Tecuapa Flores, Alan Javier Santiago Cuevas

Journal of Nanoparticle Research· Volume 27· Issue 6
Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Carbon and Quantum Dots Applications · Advanced Photocatalysis Techniques · Advanced Nanomaterials in Catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (66)

Show source-provided references
1. Walker TR, Fequet L (2023) Current trends of unsustainable plastic production and micro(nano)plastic pollution. TrAC Trends Anal Chem 160:11698410.1016/j.trac.2023.116984 ↗
2. Singh N, Walker TR (2024) Plastic recycling: a panacea or environmental pollution problem. npj Mater Sustain 2(1):1710.1038/s44296-024-00024-w ↗
3. NayanatharaThathsaraniPilapitiya PGC, Ratnayake AS (2024) The world of plastic waste: a review. Clean Mater 11:10022010.1016/j.clema.2024.100220 ↗
4. Díez AM, Licciardello N, Kolen´ko YV (2023) Photocatalytic processes as a potential solution for plastic waste management. Polym Degrad Stab 215:11045910.1016/j.polymdegradstab.2023.110459 ↗
5. Zhuo L-G, Liao W, Yu Z-X (2012) A frontier molecular orbital theory approach to understanding the mayr equation and to quantifying nucleophilicity and electrophilicity by using HOMO and LUMO energies. Asian J Org Chem 1(4):336–34510.1002/ajoc.201200103 ↗
6. Szczurek A, Tran TNL, Kubacki J, Gąsiorek A, Startek K, Mazur-Nowacka A, Dell’Anna R, Armellini C, Varas S, Carlotto A, Chiasera A, Łukowiak A, Krzak J, Ferrari M (2023) Polyethylene terephthalate (PET) optical properties deterioration induced by temperature and protective effect of organically modified SiO2–TiO2 coating. Mater Chem Phys 306:12801610.1016/j.matchemphys.2023.128016 ↗
7. Dai L, Karakas O, Cheng Y, Cobb K, Chen P, Ruan R (2023) A review on carbon materials production from plastic wastes. Chem Eng J 453:13972510.1016/j.cej.2022.139725 ↗
8. Kots PA, Xie T, Vance BC, Quinn CM, de Mello MD, Boscoboinik JA, Wang C, Kumar P, Stach EA, Marinkovic NS, Ma L, Ehrlich SN, Vlachos DG (2022) Electronic modulation of metal-support interactions improves polypropylene hydrogenolysis over ruthenium catalysts. Nat Commun 13(1):518610.1038/s41467-022-32934-5 ↗
9. Zhang F, Zeng M, Yappert RD, Sun J, Lee Y-H, LaPointe AM, Peters B, Abu-Omar MM, Scott SL (2020) Polyethylene upcycling to long-chain alkylaromatics by tandem hydrogenolysis/aromatization. Science 370(6515):437–44110.1126/science.abc5441 ↗
10. Kuriakose T, Nair P, Das B (2023) Nanotechnology for plastic degradation, in: J.A. Malik, M.J. Sadiq Mohamed (Eds.), Modern nanotechnology: volume 1: environmental sustainability and remediation, Springer International Publishing, Cham. 361–379.10.1007/978-3-031-31111-6_15 ↗
11. Peng G, Qi X, Qu W, Shao X, Song L, Du P, Xiong J (2023) Photocatalytic degradation of PET microfibers and hydrogen evolution by Ni5P4/TiO2/C NFs. Catal Sci Technol 13(20):5868–587910.1039/D3CY00815K ↗
12. Venkataramana C, Botsa SM, Shyamala P, Muralikrishna R (2021) Photocatalytic degradation of polyethylene plastics by NiAl2O4 spinels-synthesis and characterization. Chemosphere 265:12902110.1016/j.chemosphere.2020.129021 ↗
13. Lee QY, Li H (2021) Photocatalytic degradation of plastic waste: a mini review. Micromachines (Basel) 12(8):90710.3390/mi12080907 ↗
14. Zhou D, Luo H, Zhang F, Wu J, Yang J, Wang H (2022) Efficient photocatalytic degradation of the persistent PET fiber-based microplastics over Pt nanoparticles decorated N-doped TiO2 nanoflowers. Adv Fiber Mater 4(5):1094–110710.1007/s42765-022-00149-4 ↗
15. Zhou D, Wang L, Zhang F, Wu J, Wang H, Yang J (2022) Feasible degradation of polyethylene terephthalate fiber-based microplastics in alkaline media with Bi2O3@N-TiO2 Z-scheme photocatalytic system. Adv Sustain Syst 6(5):210051610.1002/adsu.202100516 ↗
16. Wan Y, Wang H, Huo P (2024) Plastic degradation and conversion by photocatalysis, plastic degradation and conversion by photocatalysis (volume 2): from waste to wealth. Am Chem Soc 1–2210.1021/bk-2024-1490.ch001 ↗
17. Uogintė I, Pleskytė S, Skapas M, Stanionytė S, Lujanienė G (2023) Degradation and optimization of microplastic in aqueous solutions with graphene oxide-based nanomaterials. Int J Environ Sci Technol 20(9):9693–970610.1007/s13762-022-04657-z ↗
18. Wan Y, Wang H, Liu J, Li J, Zhou W, Zhang J, Liu X, Song X, Wang H, Huo P (2024) Removal of polyethylene terephthalate plastics waste via Co–CeO2 photocatalyst–activated peroxymonosulfate strategy. Chem Eng J 479:14778110.1016/j.cej.2023.147781 ↗
19. Piazza V, Uheida A, Gambardella C, Garaventa F, Faimali M, Dutta J (2022) Ecosafety screening of photo-fenton process for the degradation of microplastics in water. Front Mar Sci 810.3389/fmars.2021.791431 ↗
20. Bazhukova IN, Sokovnin SY, Ilves VG, Myshkina AV, Vazirov RA, Pizurova N, Kasyanova VV (2019) Luminescence and optical properties of cerium oxide nanoparticles. Opt Mater 92:136–14210.1016/j.optmat.2019.04.021 ↗
21. Skorodumova NV, Simak SI, Lundqvist BI, Abrikosov IA, Johansson B (2002) Quantum origin of the oxygen storage capability of ceria. Phys Rev Lett 89(16):16660110.1103/PhysRevLett.89.166601 ↗
22. Montini T, Melchionna M, Monai M, Fornasiero P (2016) Fundamentals and catalytic applications of CeO2-based materials. Chem Rev 116(10):5987–604110.1021/acs.chemrev.5b00603 ↗
23. Heckert EG, Karakoti AS, Seal S, Self WT (2008) The role of cerium redox state in the SOD mimetic activity of nanoceria. Biomaterials 29(18):2705–270910.1016/j.biomaterials.2008.03.014 ↗
24. Caulfield L, Sauter E, Idriss H, Wöll C (2024) Tracking the redox properties of ceo2 powders by infrared spectroscopy: monitoring the defect states by O2 adsorption and the Ce3+ spin–orbit transition. J Phys Chem C.10.1021/acs.jpcc.4c07816 ↗
25. De Falco G, Mattiello G, Commodo M, Minutolo P, Shi X, D’Anna A, Wang H (2021) Electronic band gap of flame-formed carbon nanoparticles by scanning tunneling spectroscopy. Proc Combust Inst 38(1):1805–181210.1016/j.proci.2020.07.109 ↗
26. Mazarji M, Mahmoodi NM, NabiBidhendi G, Li A, Li M, James A, Mahmoodi B, Pan J (2025) Synthesis, characterization, and enhanced photocatalytic dye degradation: optimizing graphene-based ZnO-CdSe nanocomposites via response surface methodology. J Alloys Compd 1010:17799910.1016/j.jallcom.2024.177999 ↗
27. Zhang B, Liu X, Wang H, Feng L, Yin H (2025) Low contact resistance in carbon nanotube devices: metal-induced gap states. Phys Chem Chem Phys 27(1):463–47010.1039/D4CP02938K ↗
28. Yang XF, Kuang YW, Liu YS, Zhang DB, Shao ZG, Yu HL, Hong XK, Feng JF, Chen XS, Wang XF (2016) Carbon-based molecular devices: fano effects controlled by the molecule length and the gate voltage. Nanoscale 8(34):15712–1571910.1039/C6NR03451A ↗
29. Nguyen MB, Doan HV, Tan DLH, Lam TD (2025) Enhancement of tetracycline photocatalytic degradation under visible light: unleashing the synergy of Z-scheme Ag3PO4/GCN/FeNi-BTC photocatalyst with carbon quantum dots. J Ind Eng Chem 141:380–39310.1016/j.jiec.2024.07.001 ↗
30. Pradhan AK, Halder S, Chakraborty C (2025) Pt-nanoparticles on ZnO/carbon quantum dots: a trifunctional nanocomposite with superior electrocatalytic activity boosting direct methanol fuel cells and zinc–air batteries. J Mater Chem A 13(1):243–25610.1039/D4TA05630B ↗
31. Backes CW, Reis FB, Strapasson GB, Assis M, Longo E, Weibel DE (2025) Green Synthesis of carbon quantum dots for enhancing photocatalytic activity: hydrogen/oxygen evolution and dye photodegradation. Catal Today 443:11499610.1016/j.cattod.2024.114996 ↗
32. Bajorowicz B, Kobylański MP, Gołąbiewska A, Nadolna J, Zaleska-Medynska A, Malankowska A (2018) Quantum dot-decorated semiconductor micro- and nanoparticles: a review of their synthesis, characterization and application in photocatalysis. Adv Colloid Interface Sci 256:352–37210.1016/j.cis.2018.02.003 ↗
33. Frisch MJ, Trucks GW, Schlegel HB, Scuseria GE, Robb MA, Cheeseman JR, Scalmani G, Barone V, Mennucci B, Petersson GA, Nakatsuji H, Caricato M, Li X, Hratchian HP, Izmaylov AF, Bloino J, Zheng G, Sonnenberg JL, Hada M, Ehara M, Toyota K, Fukuda R, Hasegawa J, Ishida M, Nakajima T, Honda Y, Kitao O, Nakai H, Vreven T, Montgomery Jr JA, Peralta JE, Ogliaro F, Bearpark M, Heyd JJ, Brothers E, Kudin KN, Staroverov VN, Kobayashi R, Normand J, Raghavachari K, Rendell A, Burant JC, Iyengar SS, Tomasi J, Cossi M, Rega N, Millam JM, Klene M, Knox JE, Cross JB, Bakken V, Adamo C, Jaramillo J, Gomperts R, Stratmann RE, Yazyev O, Austin AJ, Cammi R, Pomelli C, Ochterski JW, Martin RL, Morokuma K, Zakrzewski VG, Voth GA, Salvador P, Dannenberg JJ, Dapprich S, Daniels AD, Farkas O, Foresman JB, Ortiz JV, Cioslowski J, Fox DJ (2010) Gaussian Inc., Wallingford., Gaussian 09, Revision B.01.
34. Martin RL (2003) Natural transition orbitals. J Chem Phys 118(11):4775–477710.1063/1.1558471 ↗
35. Dobrowolski JC, Karpińska G (2020) Substituent effect in the first excited triplet state of monosubstituted benzenes. ACS Omega 5(16):9477–949010.1021/acsomega.0c00712 ↗
36. Santiago Cuevas AJ, Palacios Cabrera CB, Huerta Aguilar CA, Padilla-Martínez II, Thangarasu P, Velázquez Contreras EF, Alonzo FR, Narayanan J (2022) Effect of the structural integrity on the size and porosity of gold-implanted mixed-metal oxide nanocomposites: their influence on the photocatalytic degradation of thioanisole. Dalton Trans 51(46):17671–1768710.1039/D2DT01537D ↗
37. Venugopalan P, Vidya N (2023) Microwave-assisted green synthesis of carbon dots derived from wild lemon (Citrus pennivesiculata) leaves as a fluorescent probe for tetracycline sensing in water. Spectrochim Acta A Mol Biomol Spectrosc 286:12202410.1016/j.saa.2022.122024 ↗
38. Sevilla M, Salinas Martínez-de Lecea C, Valdés-Solís T, Morallón E, Fuertes AB (2008) Solid-phase synthesis of graphitic carbon nanostructures from iron and cobalt gluconates and their utilization as electrocatalyst supports. Phys Chem Chem Phys 10(10):1433–144210.1039/b714924g ↗
39. Negishi R, Wei C, Yao Y, Ogawa Y, Akabori M, Kanai Y, Matsumoto K, Taniyasu Y, Kobayashi Y (2020) Turbostratic stacking effect in multilayer graphene on the electrical transport properties. Phys Status Solidi (B) 257(2):190043710.1002/pssb.201900437 ↗
40. Qiu T, Yang J-G, Bai X-J, Wang Y-L (2019) The preparation of synthetic graphite materials with hierarchical pores from lignite by one-step impregnation and their characterization as dye absorbents. RSC Adv 9(22):12737–1274610.1039/C9RA00343F ↗
41. Stosic D, Bennici S, Pavlovic V, Rakic V, Auroux A (2014) Tuning the acidity of niobia: characterization and catalytic activity of Nb2O5-MeO2 (Me = Ti, Zr, Ce) mesoporous mixed oxides.10.1016/j.matchemphys.2014.03.033 ↗
42. Deori K, Gupta D, Saha B, Awasthi SK, Deka S (2013) Introducing nanocrystalline CeO2 as heterogeneous environmental friendly catalyst for the aerobic oxidation of para-xylene to terephthalic acid in water. J Mater Chem A 1(24):7091–709910.1039/c3ta01590d ↗
43. Khalil KMS (2007) Synthesis and characterization of mesoporous ceria/alumina nanocomposite materials via mixing of the corresponding ceria and alumina gel precursors. J Colloid Interface Sci 307(1):172–18010.1016/j.jcis.2006.11.039 ↗
44. Wang X, Li T, Zhu P, Jin Z (2022) Synergistic effect of the MoO2/CeO2 S-scheme heterojunction on carbon rods for enhanced photocatalytic hydrogen evolution. Dalton Trans 51(7):2912–292210.1039/D1DT03605J ↗
45. Sivagami D, Priyadarshini BG (2022) Role of carbon quantum dot for enhanced performance of photo-absorption in Cu2CoSnS4 superstrate solar cell device. Materials Advances 3(5):2405–241610.1039/D1MA01117K ↗
46. Saputra AMA, Piliang AFR, Dellyansyah, Marpongahtun, Andriayani, Goei R, Risky Ramadhan HTS, Gea S (2024) Synthesis, properties, and utilization of carbon quantum dots as photocatalysts on degradation of organic dyes: a mini review. Catal Commun 187:10691410.1016/j.catcom.2024.106914 ↗
47. Deebasree JP, Maheskumar V, Vidhya B (2022) Investigation on the impact of pH on the photocatalytic activity of sonochemically synthesised BIVO4. Mater Lett 311:13157110.1016/j.matlet.2021.131571 ↗
48. Park S, Thanakkasaranee S, Shin H, Lee Y, Tak G, Seo J (2021) PET/Bio-Based Terpolyester Blends with High Dimensional Thermal Stability. Polymers 13(5):72810.3390/polym13050728 ↗
49. Kanta U-A, Thongpool V, Sangkhun W, Wongyao N, Wootthikanokkhan J (2017) Preparations, Characterizations, and a comparative study on photovoltaic performance of two different types of graphene/TiO2 nanocomposites photoelectrodes. J Nanomater 2017(1):2758294
50. MohdIsha K, Aziz N, Nordin M, Wedianti S, Farehah I, Hashim H, Abdullah A, Ezwan I (2014) Effect of UV treatment on optical properties of low-density polyethylene films doped with Eu(TTA)3phen complex. Adv Mater Res 895:155–16110.4028/www.scientific.net/AMR.895.155 ↗
51. Çiplak Z, Yildiz N, Çalimli A (2015) Investigation of graphene/Ag nanocomposites synthesis parameters for two different synthesis methods. Fullerenes Nanotubes Carbon Nanostruct 23(4):361–37010.1080/1536383X.2014.894025 ↗
52. Fuks L, Herdzik-Koniecko I, Rogowski M (2021) Carbon obtained from waste polyethylene terephthalate (PET) containers as potential sorbent of radionuclides from the contaminated aqueous solutions. Int J Environ Sci Technol 18(11):3527–353810.1007/s13762-020-03102-3 ↗
53. Ehi-Eromosele CO, Onwucha CN, Ajayi SO, Melinte G, Hansen A-L, Indris S, Ehrenberg H (2022) Ionothermal synthesis of activated carbon from waste PET bottles as anode materials for lithium-ion batteries. RSC Adv 12(53):34670–3468410.1039/D2RA06786B ↗
54. Ningsih LA, Lu P-Y, Ashimura S, Yoshida M, Chen W-C, Chiu Y-C, Hu C (2024) Highly effective photocatalytic degradation of plastic film (LDPE) using ruthenium-incorporated g-C3N4 via the Norrish mechanism. Chem Eng J 480:14808910.1016/j.cej.2023.148089 ↗
55. Rew Y, Baranikumar A, Tamashausky AV, El-Tawil S, Park P (2017) Electrical and mechanical properties of asphaltic composites containing carbon based fillers. Constr Build Mater 135:394–40410.1016/j.conbuildmat.2016.12.221 ↗
56. Farah AM, Thema FT, Dikio ED (2012) Electrochemical detection of hydrogen peroxide based on graphene oxide/prussian blue modified glassy carbon electrode. Int J Electrochem Sci 7(6):5069–508310.1016/S1452-3981(23)19604-0 ↗
57. Blanco-Gutiérrez V, Li P, Berzal-Cabetas R, Dos Santos-García AJ (2022) Exploring the photocatalytic activity of nanometric magnetite for PET materials degradation under UV light. J Solid State Chem 316:12350910.1016/j.jssc.2022.123509 ↗
58. Khandare SD, Agrawal D, Mehru N, Chaudhary DR (2022) Marine bacterial based enzymatic degradation of low-density polyethylene (LDPE) plastic. J Environ Chem Eng 10(3):10743710.1016/j.jece.2022.107437 ↗
59. Kaewkam P, Kanchanapaetnukul A, Khamyan J, Phadmanee N, Lin K-YA, Kobwittaya K, Sirivithayapakorn S (2022) UV-assisted TiO2 photocatalytic degradation of virgin LDPE films: effect of UV-A, UV-C, and TiO2. J Environ Chem Eng 10(4):10813110.1016/j.jece.2022.108131 ↗
60. Thomsen TB, Hunt CJ, Meyer AS (2022) Influence of substrate crystallinity and glass transition temperature on enzymatic degradation of polyethylene terephthalate (PET). New Biotechnol 69:28–3510.1016/j.nbt.2022.02.006 ↗
61. Kasuske ZA, Arole K, Green MJ, Anderson TA, Cañas-Carrell JE (2025) Photo-induced degradation of single-use polyethylene terephthalate (PET) microplastics under laboratory and outdoor environmental conditions. Environ Toxicol Chem vgaf08410.1093/etojnl/vgaf084 ↗
62. Camacho-González MA, Hernández-Reyes A, Garrido-Hernández A, Olivares-Xometl O, Likhanova NV, Lijanova IV (2025) TPA and PET photo-degradation by heterogeneous catalysis using a (Al2O3)0.75TiO2 coating, Preprints, Preprints.10.3390/surfaces8020034 ↗
63. Sajad S, Allam BK, Sillanpää M, Al-Farraj S, Singh PK, Banerjee S (2024) Visible-light driven photodegradation of low-density polyethylene (LDPE) using BiOCl–ZrO2 nanocomposite: a sustainable strategy for mitigating plastic pollution. Nano-Struct Nano-Objects 38:10114910.1016/j.nanoso.2024.101149 ↗
64. Andrady AL, Lavender Law K, Donohue J, Koongolla B (2022) Accelerated degradation of low-density polyethylene in air and in sea water. Sci Total Environ 811:15136810.1016/j.scitotenv.2021.151368 ↗
65. Olajire AA, Mohammed AA (2021) Bio-directed synthesis of gold nanoparticles using Ananas comosus aqueous leaf extract and their photocatalytic activity for LDPE degradation. Adv Powder Technol 32(2):600–61010.1016/j.apt.2021.01.009 ↗
66. Ariza-Tarazona MC, Siligardi C, Carreón-López HA, Valdéz-Cerda JE, Pozzi P, Kaushik G, Villarreal-Chiu JF, Cedillo-González EI (2023) Low environmental impact remediation of microplastics: visible-light photocatalytic degradation of PET microplastics using bio-inspired C, N-TiO2/SiO2 photocatalysts. Mar Pollut Bull 193:11520610.1016/j.marpolbul.2023.115206 ↗