Synthesis and optical properties of doped CsPbCl3 nanocrystals
Source abstract
Abstract
Tb, Mn, and Br ions are introduced to CsPbCl3 to prepare doped CsPbCl3 nanocrystals by hot injection method. The prepared doped CsPbCl3 nanocrystals are characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), and photoluminescence (PL) techniques to study the structural, morphological, and optical properties. The structure is not influenced by doping, which is confirmed by XRD data. Tb doping leads to larger particle sizes compared to undoped CsPbCl3 nanocrystals (8 nm 12 nm). However, the Mn and Br doping does not affect the sizes that much. The optical properties of CsPbCl3 nanocrystals can be controlled by doping. Green emission at 543 nm from Tb is observed for CsPbCl3:Tb nanocrystals. Red emission at 590 nm is obtained for Mn doping. Controlled exciton emission from CsPbCl3 is achieved by Br doping. The influence of Mn doping on the PL of CsPbCl3Br3-x is also investigated.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Perovskite Materials and Applications · Optical properties and cooling technologies in crystalline materials · Solid-state spectroscopy and crystallography
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (60)
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1. Ahmed GH, Yin J, Bakr OM, Mohammed OF (2020) Near-unity photoluminescence quantum yield in inorganic perovskite nanocrystals by metal-ion doping. J Chem Phys 152:020902. https://doi.org/10.1063/1.513180710.1063/1.5131807 ↗
2. Bai LY, Wang SW, Zhang YW, Zhang KX, Yi LX (2020) Influence of annealing process on the stable luminous CsPbCl3 perovskite films by thermal evaporation. J Lumin 227:117592. https://doi.org/10.1016/j.jlumin.2020.11759210.1016/j.jlumin.2020.117592 ↗
3. Baranowski M, Plochocka P, Plochocka P, Su R, Legrand L, Barisien T, Bernardot F, Xiong Q, Testelin C, Chamarro M (2020) Exciton binding energy and effective mass of CsPbCl3: a magneto-optical study. Photonics Res 8:A50–A55. https://doi.org/10.1364/PRJ.40187210.1364/PRJ.401872 ↗
4. Cao Z, Li J, Wang L, Xing K, Yuan X, Zhao J, Gao X, Li H (2020) Enhancing luminescence of intrinsic and Mn doped CsPbCl3 perovskite nanocrystals through Co2+ doping. Mater Res Bull 121:110608. https://doi.org/10.1016/j.materresbull.2019.11060810.1016/j.materresbull.2019.110608 ↗
5. Chen Y, Smock SR, Flintgruber AH, Perras FA, Brutchey RL, Rossini AJ (2020) Surface termination of CsPbBr 3 perovskite quantum dots determined by solid-state NMR spectroscopy. J Am Chem Soc 142:6117–6127. https://doi.org/10.1021/jacs.9b1339610.1021/jacs.9b13396 ↗
6. Cho S, Kim S, Kim J, Jo Y, Ryu I, Hong S, Lee J-J, Cha S, Nam EB, Lee SU, Noh SK, Kim H, Kwak J, Im H (2020) Hybridisation of perovskite nanocrystals with organic molecules for highly efficient liquid scintillators. Light Sci Appl 9:156. https://doi.org/10.1038/s41377-020-00391-810.1038/s41377-020-00391-8 ↗
7. Dai J, Xi J, Zu Y, Li L, Xu J, Shi Y, Liu X, Fan Q, Zhang J, Wang S, Yuan F, Dong H, Jiao B, Hou X, Wu Z (2020) Surface mediated ligands addressing bottleneck of room-temperature synthesized inorganic perovskite nanocrystals toward efficient light-emitting diodes. Nano Energy 70:104467. https://doi.org/10.1016/j.nanoen.2020.10446710.1016/j.nanoen.2020.104467 ↗
8. Das Adhikari S, Dutta SK, Dutta A, Guria AK, Pradhan N (2017) Chemically tailoring the dopant emission in manganese-doped CsPbCl3 perovskite nanocrystals Angew. Chem Int Ed 56:8746–8750. https://doi.org/10.1002/anie.20170386310.1002/anie.201703863 ↗
9. Davis AH, Zheng W (2021) Discrete composition control of two-dimensional morphologic all-inorganic metal halide perovskite nanocrystals. J Energy Chem 59:257–275. https://doi.org/10.1016/j.jechem.2020.10.02310.1016/j.jechem.2020.10.023 ↗
10. Ghaithan HM, Alahmed ZA, Qaid SMH, Hezam M, Aldwayyan AS (2020) Density functional study of cubic, tetragonal, and orthorhombic CsPbBr 3 perovskite. ACS Omega 5:7468–7480. https://doi.org/10.1021/acsomega.0c0019710.1021/acsomega.0c00197 ↗
11. Ghosh J, Hossain M, Giri PK (2020) Origin and tunability of dual color emission in highly stable Mn doped CsPbCl3 nanocrystals grown by a solid-state process. J Colloid Interface Sci 564:357–370. https://doi.org/10.1016/j.jcis.2019.12.06610.1016/j.jcis.2019.12.066 ↗
12. Granados del Águila A, Do TTH, Xing J, Jee WJ, Khurgin JB, Xiong Q (2020) Efficient up-conversion photoluminescence in all-inorganic lead halide perovskite nanocrystals. Nano Res 13:1962–1969. https://doi.org/10.1007/s12274-020-2840-710.1007/s12274-020-2840-7 ↗
13. Guo Z, Jena AK, Takei I, Kim GM, Kamarudin MA, Sanehira Y, Ishii A, Numata Y, Hayase S, Miyasaka T (2020) VOC Over 1.4 V for amorphous tin-oxide-based dopant-free CsPbI2Br perovskite solar cells. J Am Chem Soc 142:9725–9734. https://doi.org/10.1021/jacs.0c0222710.1021/jacs.0c02227 ↗
14. He Y, Stoumpos CC, Hadar I, Luo Z, McCall KM, Liu Z, Chung DY, Wessels BW, Kanatzidis MG (2021a) Demonstration of energy-resolved γ-ray detection at room temperature by the CsPbCl3 perovskite semiconductor. J Am Chem Soc. https://doi.org/10.1021/jacs.0c1225410.1021/jacs.0c12254 ↗
15. He Q, Zhang Y, Yu Y, Chen Y, Jin M, Mei E, Liang X, Zhai L, Xiang W (2021b) Ultrastable Gd3+ doped CsPbBr I2 nanocrystals red glass for high efficiency WLEDs. Chem Eng J 411:128530. https://doi.org/10.1016/j.cej.2021.12853010.1016/j.cej.2021.128530 ↗
16. Huo C, Fong CF, Amara M-R, Huang Y, Chen B, Zhang H, Guo L, Li H, Huang W, Diederichs C, Xiong Q (2020) Optical spectroscopy of single colloidal CsPbBr 3 perovskite Nanoplatelets. Nano Lett 20:3673–3680. https://doi.org/10.1021/acs.nanolett.0c0061110.1021/acs.nanolett.0c00611 ↗
17. Jbara AS, Munir J, Haq BU, Saeed MA (2020) Density functional theory study of mixed halide influence on structures and optoelectronic attributes of CsPb(I/Br)3. Appl Opt 59:3751–3759. https://doi.org/10.1364/AO.38910010.1364/AO.389100 ↗
18. Kang CH, Dursun I, Liu G, Sinatra L, Sun X, Kong M, Pan J, Maity P, Ooi E-N, Ng TK, Mohammed OF, Bakr OM, Ooi BS (2019) High-speed colour-converting photodetector with all-inorganic CsPbBr 3 perovskite nanocrystals for ultraviolet light communication. Light Sci Appl 8:94. https://doi.org/10.1038/s41377-019-0204-410.1038/s41377-019-0204-4 ↗
19. Khan J, Zhang X, Yuan J, Wang Y, Shi G, Patterson R, Shi J, Ling X, Hu L, Wu T, Dai S, Ma W (2020) Tuning the surface-passivating ligand anchoring position enables phase robustness in CsPbI3 perovskite quantum dot solar cells. ACS Energy Lett 5:3322–3329. https://doi.org/10.1021/acsenergylett.0c0184910.1021/acsenergylett.0c01849 ↗
20. Kim J, Hu L, Chen H, Guan X, Anandan PR, Li F, Tang J, Lin C-H, Kalantar-Zadeh K, Tricoli A, Wu T (2020) P-type charge transport and selective gas sensing of all-inorganic perovskite nanocrystals. ACS Mater Lett 2:1368–1374. https://doi.org/10.1021/acsmaterialslett.0c0034610.1021/acsmaterialslett.0c00346 ↗
21. Kumar S, Regue M, Isaacs MA, Freeman E, Eslava S (2020) All-inorganic CsPbBr 3 nanocrystals: gram-scale mechanochemical synthesis and selective photocatalytic CO2 reduction to methane. ACS Appl Energy Mater 3:4509–4522. https://doi.org/10.1021/acsaem.0c0019510.1021/acsaem.0c00195 ↗
22. Li Z-J, Hofman E, Davis AH, Khammang A, Wright JT, Dzikovski B, Meulenberg RW, Zheng W (2018) Complete dopant substitution by spinodal decomposition in Mn-doped two-dimensional CsPbCl3 nanoplatelets. Chem Mater 30:6400–6409. https://doi.org/10.1021/acs.chemmater.8b0265710.1021/acs.chemmater.8b02657 ↗
23. Li X, Liu X, Liu X (2020a) Self-assembly of colloidal inorganic nanocrystals: nanoscale forces, emergent properties and applications. Chem Soc Rev. https://doi.org/10.1039/D0CS00436G10.1039/D0CS00436G ↗
24. Li J, Li J, Liu R, Tu Y, Li Y, Cheng J, He T, Zhu X (2020b) Autonomous discovery of optically active chiral inorganic perovskite nanocrystals through an intelligent cloud lab. Nat Commun 11:2046. https://doi.org/10.1038/s41467-020-15728-510.1038/s41467-020-15728-5 ↗
25. Lin CC, Chen W-T, Chu C-I, Huang K-W, Yeh C-W, Cheng B-M, Liu R-S (2016) UV/VUV switch-driven color-reversal effect for Tb-activated phosphors. Light Sci Appl 5:e16066–e16066. https://doi.org/10.1038/lsa.2016.6610.1038/lsa.2016.66 ↗
26. Lin C-C, Huang S-K, Hsu C-E, Huang Y-C, Wei C-Y, Wen C-Y, Li S-S, Chen C-W, Chen C-C (2020a) Exploring the origin of phase-transformation kinetics of CsPbI3 perovskite nanocrystals based on activation energy measurements. J Phys Chem Lett 11:3287–3293. https://doi.org/10.1021/acs.jpclett.0c0044310.1021/acs.jpclett.0c00443 ↗
27. Lin S, Lin H, Ma C, Cheng Y, Ye S, Lin F, Li R, Xu J, Wang Y (2020b) High-security-level multi-dimensional optical storage medium: nanostructured glass embedded with LiGa 5 O 8: Mn 2+ with photostimulated luminescence. Light Sci Appl 9:22. https://doi.org/10.1038/s41377-020-0258-310.1038/s41377-020-0258-3 ↗
28. Liu M, Yan N, Zhang C, Li L (2021) Integrated solar cells with non-toxic inorganic nanocrystals and polymer bulk heterojunction. Appl Surf Sci Adv 3:100052. https://doi.org/10.1016/j.apsadv.2020.10005210.1016/j.apsadv.2020.100052 ↗
29. Lv W, Xu M, Ge L, Zhu X, Hong J, Huang W, Chen R (2020) Two-phase anion exchange synthesis: multiple passivation for highly efficient and stable CsPbCl3 nanocrystals. J Mater Chem C 8(1399):16083–16091. https://doi.org/10.1039/D0TC03602A10.1039/D0TC03602A ↗
30. Ma J-P, Chen J-K, Yin J, Zhang B-B, Zhao Q, Kuroiwa Y, Moriyoshi C, Hu L, Bakr OM, Mohammed OF, Sun H-T (2020) Doping induces structural phase transitions in all-inorganic lead halide perovskite nanocrystals. ACS Mater Lett 2:367–375. https://doi.org/10.1021/acsmaterialslett.0c0005910.1021/acsmaterialslett.0c00059 ↗
31. Mahato S, Ghorai A, Srivastava SK, Modak M, Singh S, Ray SK (2020) Highly air-stable single-crystalline β-CsPbI3 nanorods: a platform for inverted perovskite solar cells. Adv Energy Mater 10:2001305. https://doi.org/10.1002/aenm.20200130510.1002/aenm.202001305 ↗
32. Miao Y, Cheng L, Zou W, Gu L, Zhang J, Guo Q, Peng Q, Xu M, He Y, Zhang S, Cao Y, Li R, Wang N, Huang W, Wang J (2020) Microcavity top-emission perovskite light-emitting diodes. Light Sci Appl 9:89. https://doi.org/10.1038/s41377-020-0328-610.1038/s41377-020-0328-6 ↗
33. Naseri M, Hoat DM, Ponce-Pérez R, Rivas-Silva JF, Cocoletzi GH (2020) Examining the uniform strain effect on elastic, electronic and optical properties of CsPbCl3 through FP-LAPW calculations. Chem Phys 531:110654. https://doi.org/10.1016/j.chemphys.2019.11065410.1016/j.chemphys.2019.110654 ↗
34. Pan G, Bai X, Xu W, Chen X, Zhai Y, Zhu J, Shao H, Ding N, Xu L, Dong B, Mao Y, Song H (2020) Bright blue light emission of Ni2+ ion-doped CsPbClxBr 3–x perovskite quantum dots enabling efficient light-emitting devices. ACS Appl Mater Interfaces 12:14195–14202. https://doi.org/10.1021/acsami.0c0107410.1021/acsami.0c01074 ↗
35. Parobek D, Dong Y, Qiao T, Son DH (2018) Direct hot-injection synthesis of Mn-doped CsPbBr 3 nanocrystals. Chem Mater 30:2939–2944. https://doi.org/10.1021/acs.chemmater.8b0031010.1021/acs.chemmater.8b00310 ↗
36. Rao Z, Rao Z, Rao Z, Liang W, Liang W, Liang W, Huang H, Huang H, Ge J, Ge J, Ge J, Wang W, Pan S, Pan S, Pan S (2020) High sensitivity and rapid response ultraviolet photodetector of a tetragonal CsPbCl3 perovskite single crystal. Opt Mater Express 10:1374–1382. https://doi.org/10.1364/OME.38842910.1364/OME.388429 ↗
37. Reversible Color Switching in dual-emitting Mn(II)-doped CsPbBr3 perovskite nanorods: dilution versus evaporation | ACS Energy Letters, (n.d.). https://pubs.acs.org/doi/https://doi.org/10.1021/acsenergylett.9b01702 (accessed 30 Jan 2021)10.1021/acsenergylett.9b01702 ↗
38. Shamsi J, Kubicki D, Anaya M, Liu Y, Ji K, Frohna K, Grey CP, Friend RH, Stranks SD (2020) Stable hexylphosphonate-capped blue-emitting quantum-confined CsPbBr 3 nanoplatelets. ACS Energy Lett 5:1900–1907. https://doi.org/10.1021/acsenergylett.0c0093510.1021/acsenergylett.0c00935 ↗
39. Shen K, Xu H, Li X, Guo J, Sathasivam S, Wang M, Ren A, Choy KL, Parkin IP, Guo Z, Wu J (2020) Flexible and self-powered photodetector arrays based on all-inorganic CsPbBr 3 quantum dots. Adv Mater 32:2000004. https://doi.org/10.1002/adma.20200000410.1002/adma.202000004 ↗
40. Sui F, Pan M, Wang Z, Chen M, Li W, Shao Y, Li W, Yang C (2020) Quantum yield enhancement of Mn-doped CsPbCl3 perovskite nanocrystals as luminescent down-shifting layer for CIGS solar cells. Sol Energy 206:473–478. https://doi.org/10.1016/j.solener.2020.05.07010.1016/j.solener.2020.05.070 ↗
41. Sun R, Zhou D, Wang Y, Xu W, Ding N, Zi L, Zhuang X, Bai X, Song H (2020) Highly efficient ligand-modified manganese ion doped CsPbCl3 perovskite quantum dots for photon energy conversion in silicon solar cells. Nanoscale 12:18621–18628. https://doi.org/10.1039/D0NR04885B10.1039/D0NR04885B ↗
42. Thermal and photo stability of all inorganic lead halide perovskite nanocrystals - Physical Chemistry Chemical Physics (RSC Publishing), (n.d.). https://pubs.rsc.org/en/content/articlelanding/2021/cp/d1cp02119b/unauth (accessed 17 Aug 2021)
43. Uddin MA, Glover JD, Park SM, Pham JT, Graham KR (2020) Growth of Highly Stable and Luminescent CsPbX3 (X = Cl, Br, and I) Nanoplates via ligand mediated anion exchange of CsPbCl3 nanocubes with AlX3. Chem Mater 32:5217–5225. https://doi.org/10.1021/acs.chemmater.0c0132510.1021/acs.chemmater.0c01325 ↗
44. Vila-Liarte D, Feil MW, Manzi A, Garcia-Pomar JL, Huang H, Döblinger M, Liz-Marzán LM, Feldmann J, Polavarapu L, Mihi A (2020) Templated-assembly of CsPbBr 3 perovskite nanocrystals into 2D photonic supercrystals with amplified spontaneous emission. Angew Chem Int Ed 59:17750–17756. https://doi.org/10.1002/anie.20200615210.1002/anie.202006152 ↗
45. Wang T, Yang Z, Yang L, Yu X, Sun L, Qiu J, Zhou D, Lu W, Yu SF, Lin Y, Xu X (2020a) Atomic-scale insights into the dynamics of growth and degradation of all-inorganic perovskite nanocrystals. J Phys Chem Lett 11:4618–4624. https://doi.org/10.1021/acs.jpclett.0c0122010.1021/acs.jpclett.0c01220 ↗
46. Wang Y, Chen Y, Zhang T, Wang X, Zhao Y (2020b) Chemically stable black phase CsPbI3 inorganic perovskites for high-efficiency photovoltaics. Adv Mater 32:2001025. https://doi.org/10.1002/adma.20200102510.1002/adma.202001025 ↗
47. Wang S, Bi C, Portniagin A, Yuan J, Ning J, Xiao X, Zhang X, Li YY, Kershaw SV, Tian J, Rogach AL (2020c) CsPbI3/PbSe heterostructured nanocrystals for high-efficiency solar cells. ACS Energy Lett 5:2401–2410. https://doi.org/10.1021/acsenergylett.0c0122210.1021/acsenergylett.0c01222 ↗
48. Wang Y, Chen G, Ouyang D, He X, Li C, Ma R, Yin W-J, Choy WCH (2020d) High phase stability in CsPbI3 enabled by Pb–I octahedra anchors for efficient inorganic perovskite photovoltaics. Adv Mater 32:2000186. https://doi.org/10.1002/adma.20200018610.1002/adma.202000186 ↗
49. Wang H, Zhang P, Zang Z (2020e) High performance CsPbBr 3 quantum dots photodetectors by using zinc oxide nanorods arrays as an electron-transport layer. Appl Phys Lett 116:162103. https://doi.org/10.1063/5.000546410.1063/5.0005464 ↗
50. Wang W, Li J, Duan G, Zhou H, Lu Y, Yan T, Cao B, Liu Z (2020f) Study on the Mn-doped CsPbCl3 perovskite nanocrystals with controllable dual-color emission via energy transfer. J Alloys Compd 821:153568. https://doi.org/10.1016/j.jallcom.2019.15356810.1016/j.jallcom.2019.153568 ↗
51. Yan L, Wang M, Zhai C, Zhao L, Lin S (2020) Symmetry breaking induced anisotropic carrier transport and remarkable thermoelectric performance in mixed halide perovskites CsPb(I1–xBrx)3. ACS Appl Mater Interfaces 12:40453–40464. https://doi.org/10.1021/acsami.0c0750110.1021/acsami.0c07501 ↗
52. Yang J, Yuan X, Fan L, Zheng Y, Ma F, Li H, Zhao J, Liu H (2021) Enhancing Mn emission of CsPbCl3 perovskite nanocrystals via incorporation of rubidium ions. Mater Res Bull 133:111080. https://doi.org/10.1016/j.materresbull.2020.11108010.1016/j.materresbull.2020.111080 ↗
53. Zhang J, Wang Q, Zhang X, Jiang J, Gao Z, Jin Z (2017) Shengzhong (Frank) Liu, High-performance transparent ultraviolet photodetectors based on inorganic perovskite CsPbCl 3 nanocrystals. RSC Adv 7:36722–36727. https://doi.org/10.1039/C7RA06597C10.1039/C7RA06597C ↗
54. Zhang X, Qian Y, Ling X, Wang Y, Zhang Y, Shi J, Shi Y, Yuan J, Ma W (2020) α-CsPbBr 3 Perovskite quantum dots for application in semitransparent photovoltaics. ACS Appl Mater Interfaces 12:27307–27315. https://doi.org/10.1021/acsami.0c0766710.1021/acsami.0c07667 ↗
55. Zhao H, Hu Z, Wei L, Zeng P, Kuang C, Liu X, Bai S, Gao F, Liu M (2020a) Efficient and high-luminance perovskite light-emitting diodes based on CsPbBr 3 Nanocrystals synthesized from a dual-purpose organic lead source. Small 16:2003939. https://doi.org/10.1002/smll.20200393910.1002/smll.202003939 ↗
56. Zhao Y, Zhang X, Xie C, Shi W, Yang P, Jiang SP (2020b) Controlling Mn Emission in CsPbCl3 Nanocrystals via ion exchange toward enhanced and tunable white photoluminescence. J Phys Chem C 124:27032–27039. https://doi.org/10.1021/acs.jpcc.0c0837810.1021/acs.jpcc.0c08378 ↗
57. Zhou D, Tao L, Yu Z, Jiao J, Xu W (2020) Efficient chromium ion passivated CsPbCl3: Mn perovskite quantum dots for photon energy conversion in perovskite solar cells. J Mater Chem c 8:12323–12329. https://doi.org/10.1039/D0TC03115A10.1039/D0TC03115A ↗
58. Zhu J, Zhu Y, Huang J, Hou L, Shen J, Li C (2020a) Synthesis of monodisperse water-stable surface Pb-rich CsPbCl3 nanocrystals for efficient photocatalytic CO2 reduction. Nanoscale 12:11842–11846. https://doi.org/10.1039/D0NR02917C10.1039/D0NR02917C ↗
59. Zhu W, Deng M, Chen D, Zhang Z, Chai W, Chen D, Xi H, Zhang J, Zhang C, Hao Y (2020b) Dual-phase CsPbCl3–Cs4PbCl6 perovskite films for self-powered, visible-blind uv photodetectors with fast response. ACS Appl Mater Interfaces 12:32961–32969. https://doi.org/10.1021/acsami.0c0991010.1021/acsami.0c09910 ↗
60. Zou S, Liu Y, Li J, Liu C, Feng R, Jiang F, Li Y, Song J, Zeng H, Hong M, Chen X (2017) Stabilizing cesium lead halide perovskite lattice through Mn(II) substitution for air-stable light-emitting diodes. J Am Chem Soc 139:11443–11450. https://doi.org/10.1021/jacs.7b0400010.1021/jacs.7b04000 ↗