journal article·2014-06

One-pot, large-scale synthesis silica-encapsulated NIR alloy quantum dots CdSeTe within short time

Cuiling Ren, Haosen Yuan, Yifang Yang, Hongli Chen, Yonglei Chen, Shengda Qi, Xingguo Chen

Journal of Nanoparticle Research· Volume 16· Issue 6
Publisher page

Abstract

Silica-based near-infrared fluorescent materials in biological application have attracted much attention. But the current methods for preparing silica-encapsulated near-infrared radiation (NIR) quantum dots (QDs) are commonly time-consuming and can only obtain a few products in one batch. Herein, we present a fast and facile one-pot aqueous-phase route to prepare NIR-emitting silica-encapsulated CdSeTe QDs at large scale. The influences of various experimental conditions on the luminescent properties of the obtained silica hybrids QDs have been systematically investigated, such as capping agent, reaction time, pH value and so on. The final product has been characterized by X-ray diffraction, transmission electron microscope, photoluminescent spectra and energy dispersive x-ray spectroscopy (EDX). The silica-coated NIR-emitting QDs can be obtained within 10 h under the optimized conditions. The yield is 3.70 g in one batch. The final product is spherical with an average particle size around 15 nm.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Quantum Dots Synthesis And Properties · Chalcogenide Semiconductor Thin Films · Advanced Semiconductor Detectors and Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (33)

Show source-provided references
1. Altınoğlu Eİ, Adair JH (2010) Near infrared imaging with nanoparticles. Wiley Interdiscip Rev Nanomed Nanobiotechnol 2:461–47710.1002/wnan.77 ↗
2. Chen H, Cui S, Tu Z, Gu Y, Chi X (2012a) In vivo monitoring of organ-selective distribution of CdHgTe/SiO2 nanoparticles in mouse model. J Fluoresc 22:699–70610.1007/s10895-011-1005-1 ↗
3. Chen LN, Wang J, Li WT, Han HY (2012b) Aqueous one-pot synthesis of bright and ultrasmall CdTe/CdS near-infrared-emitting quantum dots and their application for tumor targeting in vivo. Chem Commun 48:4971–497310.1039/c2cc31259j ↗
4. Darbandi M, Lu W, Fang J, Nann T (2006) Silica encapsulation of hydrophobically ligated PbSe nanocrystals. Langmuir 22:4371–437510.1021/la0529658 ↗
5. Foda MF, Huang L, Shao F, Han HY (2014) Biocompatible and Highly luminescent near-infrared CuInS2/ZnS quantum dots embedded silica beads for cancer cell imaging. ACS Appl Mater Interfaces 6:2011–201710.1021/am4050772 ↗
6. Gerion D, Pinaud F, Williams SC, Parak WJ, Zanchet D, Weiss S, Alivisatos AP (2001) Synthesis and properties of biocompatible water-soluble silica-coated CdSe/ZnS semiconductor quantum dots. J Phys Chem B 105:8861–887110.1021/jp0105488 ↗
7. Guerrero-Martínez A, Pérez-Juste J, Liz-Marzán LM (2010) Recent progress on silica coating of nanoparticles and related nanomaterials. Adv Mater 22:1182–119510.1002/adma.200901263 ↗
8. Guével XL, Hötzer B, Jung G, Schneider M (2011) NIR-emitting fluorescent gold nanoclusters doped in silica nanoparticles. J Mater Chem 21:2974–298110.1039/c0jm02660c ↗
9. Han L, Lv Y, Asiri AM, Al-Youbi AO, Tu B, Zhao D (2012) Novel preparation and near-infrared photoluminescence of uniform core-shell silver sulfide nanoparticle@mesoporous silica nanospheres. J Mater Chem 22:7274–727910.1039/c2jm16168k ↗
10. Hao X, Zhou M, Zhang X, Yu J, Jie J, Yu C, Zhang X (2014) Highly luminescent and photostable core–shell dye nanoparticles for high efficiency bioimaging. Chem Commun 50:737–73910.1039/C3CC47961G ↗
11. Herz E, Ow H, Bonner D, Burns A, Wiesner U (2009) Dye structure–optical property correlations in near-infrared fluorescent core-shell silica nanoparticles. J Mater Chem 19:6341–634710.1039/b902286d ↗
12. Hu XG, Gao XH (2010) Silica–polymer dual layer-encapsulated quantum dots with remarkable stability. ACS Nano 4:6080–608610.1021/nn1017044 ↗
13. Liang GX, Gu MM, Zhang JR, Zhu JJ (2009) Preparation and bioapplication of high-quality, water-soluble, biocompatible, and near-infrared-emitting CdSeTe alloyed quantum dots. Nanotechnology 20:41510310.1088/0957-4484/20/41/415103 ↗
14. Lin Z, Fei X, Ma Q, Gao X, Su X (2014) CuInS2 quantum dots@silica near-infrared fluorescent nanoprobe for cell imaging. New J Chem 38:90–9610.1039/C3NJ00957B ↗
15. Liu YS, Sun Y, Vernier PT, Liang CH, Chong SYC, Gundersen MA (2007) pH-Sensitive photoluminescence of CdSe/ZnSe/ZnS quantum dots in human ovarian cancer cells. J Phys Chem C 111:2872–287810.1021/jp0654718 ↗
16. Liu S, Zhang H, Qiao Y, Su X (2012) One-pot synthesis of ternary CuInS2 quantum dots with near-infrared fluorescence in aqueous solution. RSC Adv 2:819–82510.1039/C1RA00802A ↗
17. Ma Q, Su X (2010) Near-infrared quantum dots: synthesis, functionalization and analytical applications. Analyst 135:1867–187710.1039/c0an00233j ↗
18. Ma K, Sai H, Wiesner U (2012) Ultrasmall Sub-10 nm near-infrared fluorescent mesoporous silica nanoparticles. J Am Chem Soc 134:13180–1318310.1021/ja3049783 ↗
19. Mandal A, Tamai N (2008) Influence of acid on luminescence properties of thioglycolic acid-capped CdTe quantum dots. J Phys Chem C 112:8244–825010.1021/jp801043e ↗
20. Nooney RI, McCahey CMN, Stranik O, Guevel XL, McDonagh C, MacCraith BD (2009) Experimental and theoretical studies of the optimisation of fluorescence from near-infrared dye-doped silica nanoparticles. Anal Bioanal Chem 393:1143–114910.1007/s00216-008-2418-9 ↗
21. Ribeiro T, Raja S, Rodrigues AS, Fernandes F, Farinha JPS, Baleizão C (2013) High performance NIR fluorescent silica nanoparticles for bioimaging. RSC Adv 3:9171–917410.1039/c3ra41199k ↗
22. Sharma P, Bengtsson NE, Walter GA, Sohn HB, Zhou G, Iwakuma N, Zeng H, Grobmyer SR, Scott EW, Moudgil BM (2012) Gadolinium-doped silica nanoparticles encapsulating indocyanine green for near infrared and magnetic resonance imaging. Small 8:2856–286810.1002/smll.201200258 ↗
23. Tan TT, Selvan ST, Zhao L, Gao S, Ying JY (2007) Size control, shape evolution, and silica coating of near-infrared-emitting PbSe quantum dots. Chem Mater 19:3112–311710.1021/cm061974e ↗
24. Vivero-Escoto JL, Huxford-Phillips RC, Lin W (2012) Silica-based nanoprobes for biomedical imaging and theranostic applications. Chem Soc Rev 41:2673–268510.1039/c2cs15229k ↗
25. Wang R, Zhang F (2014) NIR luminescent nanomaterials for biomedical imaging. J Mater Chem B. doi: 10.1039/c3tb21447h
26. Wang X, Morales AR, Urakami T, Zhang L, Bondar MV, Komatsu M, Belfield KD (2011) Folate receptor-targeted aggregation-enhanced near-IR emitting silica nanoprobe for one-photon in vivo and two-photon ex vivo fluorescence bioimaging. Bioconjug Chem 22:1438–145010.1021/bc2002506 ↗
27. Wang D, Qian J, Cai F, He S, Han S, Mu Y (2012) “Green”-synthesized near-infrared PbS quantum dots with silica–PEG dual-layer coating: ultrastable and biocompatible optical probes for in vivo animal imaging. Nanotechnology 23:24570110.1088/0957-4484/23/24/245701 ↗
28. Wu X, Chang S, Sun X, Guo Z, Li Y, Tang J, Shen Y, Shi J, Tian H, Zhu W (2013) Constructing NIR silica–cyanine hybrid nanocomposite for bioimaging in vivo: a breakthrough in photostability and bright fluorescence with large Stokes shift. Chem Sci 4:1221–122810.1039/c2sc22035k ↗
29. Yu XF, Chen LD, Li M, Xie MY, Zhou L, Li Y, Wang QQ (2008) Highly efficient fluorescence of NdF3/SiO2 core/shell nanoparticles and the applications for in vivo NIR detection. Adv Mater 20:4118–412310.1002/adma.200801224 ↗
30. Yuan Z, Zhang A, Cao Y, Yang J, Zhu Y, Yang P (2012) Effect of mercaptocarboxylic acids on luminescent properties of CdTe quantum dots. J Fluoresc 22:121–12710.1007/s10895-011-0937-9 ↗
31. Zhang Y, Clapp A (2011) Overview of stabilizing ligands for biocompatible quantum dot nanocrystals. Sensors 11:11036–1105510.3390/s111211036 ↗
32. Zhang R, Yang P, Wang Yi (2013) Facile synthesis of CuInS2/ZnS quantum dots with highly near-infrared photoluminescence via phosphor-free process. J Nanopart Res 15:1910–191910.1007/s11051-013-1910-0 ↗
33. Zhou L, Gao C, Hu X, Xu W (2010) One-pot large-scale synthesis of robust ultrafine silica-hybridized CdTe quantum dots. ACS Appl Mater Interfaces 2:1211–121910.1021/am9009296 ↗