Enhanced absorption in organic solar cells using core-shell iron-ZnO nanoparticles: optical and numerical simulations
Source abstract
Abstract
Abstract This paper presents a detailed numerical and optical simulation analysis of iron (Fe) nanoparticles (NPs) with zinc oxide (ZnO) shells embedded in a square periodic array within the active layer of organic solar cells (OSCs). Utilizing the Finite Difference Time Domain (FDTD) method, we first calculate the intrinsic absorption of P3HT:PCBM. Following this, Fe-ZnO NPs are introduced into the active layer, and their absorption properties are analyzed and compared to the intrinsic absorption. The Absorption Enhancement (AE) metric is employed to optimize the period, thickness, and edge length of the rectangular prism Fe NPs to achieve maximum AE. Additionally, AE is compared in similar structures with different core materials, including gold (Au), silver (Ag), and aluminum (Al). The proposed structure, characterized by a thick shell on the top and base faces, demonstrates that Fe NPs can achieve an AE 1.282 times greater than the intrinsic absorption, and 1.13, 1.165, and 1.07 times more than Au, Ag, and Al, respectively. Notably, Al exhibits greater absorption enhancement than Au and Ag, indicating its potential as a future candidate. Furthermore, the electric field and absorption density are investigated, revealing how near-field plasmonics can significantly enhance absorption within the active layer, even in the red part of the spectrum. Iron NPs offer several advantages over traditional noble metal NPs, including cost-effectiveness, guaranteed biodegradability in OSCs, highest AE, and interesting magnetic properties that can influence excitons and electron-hole separation and velocity. These factors make Fe NPs an attractive option for enhancing the efficiency of OSCs.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Organic Electronics and Photovoltaics · Thin-Film Transistor Technologies · Conducting polymers and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (55)
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1. Liu Y, Liu B, Ma CQ, Huang F, Feng G, Chen H, Hou J, Yan L, Wei Q, Luo Q, Bao Q (2022) Recent progress in organic solar cells (Part II device engineering). Sci China Chem 65(8):1457–1497. https://doi.org/10.1007/s11426-022-1256-810.1007/s11426-022-1256-8 ↗
2. Liu Y, Li B, Ma CQ, Huang F, Feng G, Chen H, Hou J, Yan L, Wei Q, Luo Q, Bao Q (2022) Recent progress in organic solar cells (Part I material science). Sci China Chem 1–45. https://doi.org/10.1007/s11426-021-1180-610.1007/s11426-021-1180-6 ↗
3. Li Y, Huang W, Zhao D, Wang L, Jiao Z, Huang Q, Wang P, Sun M, Yuan G (2022) Recent progress in organic solar cells: a review on materials from acceptor to donor. Molecules 27(6):1800. https://doi.org/10.3390/molecules2706180010.3390/molecules27061800 ↗
4. Fernández-Castro M, Truer J, Espindola-Rodriguez M, Andreasen JW (2022) Environmentally friendly and roll-processed flexible organic solar cells based on PM6: Y6. Front Nanotechnol 4:885138. https://doi.org/10.3389/fnano.2022.88513810.3389/fnano.2022.885138 ↗
5. Huang YC, Cha HC, Huang SH, Li CF, Santiago SRM, Tsao CS (2023) Highly efficient flexible roll-to-roll organic photovoltaics based on non-fullerene acceptors. Polymers 15(19):4005. https://doi.org/10.3390/polym1519400510.3390/polym15194005 ↗
6. Ullah I, Guo J, Wang C, Liu Z, Li X, Jiang L, Yuan J, Ma W (2023) Design and analysis of high-efficiency perovskite solar cell using the controllable photonic structure and plasmonic nanoparticles. J Alloy Compd 960:170994. https://doi.org/10.1016/j.jallcom.2023.17099410.1016/j.jallcom.2023.170994 ↗
7. Ullah I, Ullah MI, Ma W, Yuan J (2024) Nanotextured highly efficient optical and light trapping strategies using efficient hole transport-free structure for perovskite solar cells. Opt Commun 556:130276. https://doi.org/10.1016/j.optcom.2024.13027610.1016/j.optcom.2024.130276 ↗
8. Farooq W, Khan AD, Khan AD, Rauf A, Khan SD, Ali H, Iqbal J, Khan RU, Noman M (2020) Thin-film tandem organic solar cells with improved efficiency. IEEE Access 8:74093–74100. https://doi.org/10.1109/ACCESS.2020.298832510.1109/ACCESS.2020.2988325 ↗
9. Ahmad W, Farooq W, Khan AD, Jan ST, Jasiński M, Leonowicz Z, Gono R, Petrov J (2022) Thin-film carbon nitride (C2N)-based solar cell optimization considering Zn1- xMgxO as a buffer layer. Processes 11(1):91. https://www.mdpi.com/2227-9717/11/1/91#10.3390/pr11010091 ↗
10. Farooq W, Alzahrani A, Ghoneim SS (2023) Computational optimization and optical analysis of thin-film organic solar cells for high efficiency. J Comput Electron 22(3):867–873. https://doi.org/10.1007/s10825-023-02019-710.1007/s10825-023-02019-7 ↗
11. Stratakis E, Kymakis E (2013) Nanoparticle-based plasmonic organic photovoltaic devices. Mater Today 16(4):133–146. https://doi.org/10.1016/j.mattod.2013.04.00610.1016/j.mattod.2013.04.006 ↗
12. Kozanoglu D, Apaydin DH, Cirpan A, Esenturk EN (2013) Power conversion efficiency enhancement of organic solar cells by addition of gold nanostars, nanorods, and nanospheres. Org Electron 14(7):1720–1727. https://doi.org/10.1016/j.orgel.2013.04.00810.1016/j.orgel.2013.04.008 ↗
13. Duche D, Torchio P, Escoubas L, Monestier F, Simon JJ, Flory F, Mathian G (2009) Improving light absorption in organic solar cells by plasmonic contribution. Sol Energy Mater Sol Cells 93(8):1377–1382. https://doi.org/10.1016/j.solmat.2009.02.02810.1016/j.solmat.2009.02.028 ↗
14. Ullah I, Saghaei H, Khan J, Shah SK (2022) The role of plasmonic metal-oxides core-shell nanoparticles on the optical absorption of Perovskite solar cells. Opt Quant Electr 54(10):675. https://link.springer.com/article/10.1007/s11082-022-04051-610.1007/s11082-022-04051-6 ↗
15. Fung DD, Qiao L, Choy WC, Wang C, Wei EI, Xie F, He S (2011) Optical and electrical properties of efficiency enhanced polymer solar cells with Au nanoparticles in a PEDOT-PSS layer. J Mater Chem 21(41):16349–16356. https://doi.org/10.1039/C1JM12820E10.1039/C1JM12820E ↗
16. N’konou, K., Peres, L. and Torchio, P., (2018) Optical absorption modeling of plasmonic organic solar cells embedding silica-coated silver nanospheres. Plasmonics 13:297–303. https://link.springer.com/article/10.1007/s11468-017-0514-410.1007/s11468-017-0514-4 ↗
17. Ullah H, Khan AD, Ullah A, Ullah I, Noman M (2016) Plasmonic perfect absorber for solar cell applications. In 2016 International Conference on Emerging Technologies (ICET) (pp. 1-5). IEEE. https://doi.org/10.1109/ICET.2016.781326810.1109/ICET.2016.7813268 ↗
18. Khalil UK, Farooq W, Iqbal J, Ul Abideen Kazmi SZ, Khan AD, Ur Rehman A, Ayub S (2021) Design and optimization of bowtie nanoantenna for electromagnetic field enhancement. Eur Phys J Plus 136:1–13. https://doi.org/10.1140/epjp/s13360-021-01702-710.1140/epjp/s13360-021-01702-7 ↗
19. Jamil S, Farooq W, Ullah N, Daud Khan A, Khalil UK, Mosavi A (2022) Large electromagnetic field enhancement in plasmonic nanoellipse for tunable spaser based applications. PLoS ONE 17(3):e0263630. https://doi.org/10.1371/journal.pone.026363010.1371/journal.pone.0263630 ↗
20. Choi H, Lee JP, Ko SJ, Jung JW, Park H, Yoo S, Park O, Jeong JR, Park S, Kim JY (2013) Multipositional silica-coated silver nanoparticles for high-performance polymer solar cells. Nano Lett 13(5):2204–2208. https://doi.org/10.1021/nl400730z10.1021/nl400730z ↗
21. Jang LW, Park H, Lee SH, Polyakov AY, Khan R, Yang JK, Lee IH (2015) Device performance of inverted polymer solar cells with AgSiO 2 nanoparticles in active layer. Opt Express 23(7):A211–A218. https://doi.org/10.1364/OE.23.00A21110.1364/OE.23.00A211 ↗
22. Jankovic V, Yang Y, You J, Dou L, Liu Y, Cheung P, Chang JP, Yang Y (2013) Active layer-incorporated, spectrally tuned Au/SiO2 core/shell nanorod-based light trapping for organic photovoltaics. ACS Nano 7(5):3815–3822. https://doi.org/10.1021/nn400246q10.1021/nn400246q ↗
23. Lee JY, Peumans P (2010) The origin of enhanced optical absorption in solar cells with metal nanoparticles embedded in the active layer. Opt Express 18(10):10078–10087. https://doi.org/10.1364/OE.18.01007810.1364/OE.18.010078 ↗
24. Ullah I, Hossain MA, Armghan A, Rana MS, Al Asad MA (2023) The optoelectronic enhancement in perovskite solar cells using plasmonic metal-dielectric core-shell and nanorod nanoparticles. Opt Quant Electron 55(11):1018. https://doi.org/10.1007/s11082-023-05252-310.1007/s11082-023-05252-3 ↗
25. Kim T, Kang H, Jeong S, Kang DJ, Lee C, Lee CH, Seo MK, Lee JY, Kim BJ (2014) Au@ polymer core-shell nanoparticles for simultaneously enhancing efficiency and ambient stability of organic optoelectronic devices. ACS Appl Mater Interf 6(19):16956–16965. https://doi.org/10.1021/am504503q10.1021/am504503q ↗
26. West PR, Ishii S, Naik GV, Emani NK, Shalaev VM, Boltasseva A (2010) Searching for better plasmonic materials. Laser Photonics Rev 4(6):795–808. https://doi.org/10.1002/lpor.20090005510.1002/lpor.200900055 ↗
27. Tak YH, Kim KB, Park HG, Lee KH, Lee JR (2002) Criteria for ITO (indium-tin-oxide) thin film as the bottom electrode of an organic light emitting diode. Thin Solid Films 411(1):12–16. https://doi.org/10.1016/S0040-6090(02)00165-710.1016/S0040-6090(02)00165-7 ↗
28. Haldar A, Yambem SD, Liao KS, Alley NJ, Dillon EP, Barron AR, Curran SA (2011) Organic photovoltaics using thin gold film as an alternative anode to indium tin oxide. Thin Solid Films 519(18):6169–6173. https://doi.org/10.1016/j.tsf.2011.04.07110.1016/j.tsf.2011.04.071 ↗
29. Ghazy OA, Ibrahim MM, Abou Elfadl FI, Hosni HM, Shehata EM, Deghiedy NM, Balboul MR (2014) Optimisation of the fabrication conditions of the PEDOT: PSS layer in organic solar cells based on P3HT: PCBM. Int J Nanoparticles 7(3–4):251–260. https://doi.org/10.1504/IJNP.2014.06761210.1504/IJNP.2014.067612 ↗
30. Zhang Y, Li X, Dai T, Xu D, Xi J, Chen X (2019) Charge transport and extraction of PTB7: PC 71 BM organic solar cells: effect of film thickness and thermal-annealing. RSC Adv 9(43):24895–24903. https://doi.org/10.1039/C9RA02877C10.1039/C9RA02877C ↗
31. Chen M, Zhang Y, Cui Y, Zhang F, Qin W, Zhu F, Hao Y (2017) Profiling light absorption enhancement in two-dimensional photonic-structured perovskite solar cells. IEEE J Photovoltaics 7(5):1324–1328. https://doi.org/10.1109/JPHOTOV.2017.271975910.1109/JPHOTOV.2017.2719759 ↗
32. Tarique WB, Rahaman MH, Dipta SS, Howlader AH, Uddin A (2024) Solution-processed bilayered ZnO electron transport layer for efficient inverted non-fullerene organic solar cells. Nanomanufacturing 4(2):81–98. https://doi.org/10.3390/nanomanufacturing402000610.3390/nanomanufacturing4020006 ↗
33. Gupta SK, Sharma A, Banerjee S, Gahlot R, Aggarwal N, Garg A (2013) Understanding the role of thickness and morphology of the constituent layers on the performance of inverted organic solar cells. Sol Energy Mater Sol Cells 116:135–143. https://doi.org/10.1016/j.solmat.2013.03.02710.1016/j.solmat.2013.03.027 ↗
34. Hao Y, Song J, Yang F, Hao Y, Sun Q, Guo J, Cui Y, Wang H, Zhu F (2015) Improved performance of organic solar cells by incorporating silica-coated silver nanoparticles in the buffer layer. J Mater Chem C 3(5):1082–1090. https://doi.org/10.1039/C4TC01990C10.1039/C4TC01990C ↗
35. Sepahvand N, Bahrami M, Moradpour Z, Dezfuli AG (2023) Numerical study of the effect of aluminum-gold nanorods on the short-circuit current density and the absorption in organic solar cells. Plasmonics 18(4):1337–1350. https://doi.org/10.1007/s11468-023-01850-910.1007/s11468-023-01850-9 ↗
36. Shabani L, Mohammadi A, Jalali T (2023) Performance analysis of polymer bulk heterojunction solar cells with plasmonic nanoparticles embedded into the P3HT: PC61BM active layer using the FDTD method. Polym Bull 80(9):9589–9610. https://doi.org/10.1007/s00289-022-04521-710.1007/s00289-022-04521-7 ↗
37. Shabani L, Mohammadi A, Jalali T (2022) Numerical study of plasmonic effects of Ag nanoparticles embedded in the active layer on performance polymer organic solar cells. Plasmonics 17(2):491–504. https://doi.org/10.1007/s11468-021-01539-x10.1007/s11468-021-01539-x ↗
38. Ansys Lumerical (2024) Organic solar cell with PC structure. [online] Available at: https://optics.ansys.com/hc/en-us/articles/360042157554-Organic-solar-cell-with-PC-structure Accessed on 7 Jul 2024
39. Huber DL (2005) Synthesis, properties, and applications of iron nanoparticles. Small 1(5):482–501. https://doi.org/10.1002/smll.20050000610.1002/smll.200500006 ↗
40. Bhateria R, Mona S, Sharma Y (2021) Green synthesized iron nanoparticles for environmental management: minimizing material and energy inputs. Cost-efficient wastewater treatment technologies: natural systems. pp 129-149. https://doi.org/10.1007/698_2021_78910.1007/698_2021_789 ↗
41. Abuzeid HM, Julien CM, Zhu L, Hashem AM (2023) Green synthesis of nanoparticles and their energy storage, environmental, and biomedical applications. Curr Comput-Aided Drug Des 13(11):1576. https://doi.org/10.3390/cryst1311157610.3390/cryst13111576 ↗
42. Kumar B (2021) Green synthesis of gold, silver, and iron nanoparticles for the degradation of organic pollutants in wastewater. J Comp Sci 5(8):219. https://doi.org/10.3390/jcs508021910.3390/jcs5080219 ↗
43. Maksymov IS (2016) Magneto-plasmonic nanoantennas: basics and applications. Rev Phys 1:36–51. https://doi.org/10.1016/j.revip.2016.03.00210.1016/j.revip.2016.03.002 ↗
44. Bhatia P, Verma SS, Sinha MM (2019) Optical properties simulation of magneto-plasmonic alloys nanostructures. Plasmonics 14:611–622. https://doi.org/10.1007/s11468-018-0839-710.1007/s11468-018-0839-7 ↗
45. Bohren CF, Huffman DR (2008) Absorption and scattering of light by small particles. John Wiley & Sons
46. Hasheminassab SMS, Imanieh M, Kamali A, Emamghorashi SA, Hassanhosseini S (2021) Influence of the shape and size of Ag nanoparticles on the performance enhancement of CIGS solar cells: the role of surface plasmons. Plasmonics 16(1):273–282. https://doi.org/10.1007/s11468-020-01280-x10.1007/s11468-020-01280-x ↗
47. Ren W, Zhang G, Wu Y, Ding H, Shen Q, Zhang K, Li J, Pan N, Wang X (2011) Broadband absorption enhancement achieved by optical layer mediated plasmonic solar cell. Opt Express 19(27):26536–26550. https://doi.org/10.1364/OE.19.02653610.1364/OE.19.026536 ↗
48. Sobhani F, Heidarzadeh H, Bahador H (2020) Efficiency enhancement of an ultra-thin film silicon solar cell using conical-shaped nanoparticles: similar to superposition (top, middle, and bottom). Opt Quant Electron 52(9):387. https://doi.org/10.1007/s11082-020-02487-210.1007/s11082-020-02487-2 ↗
49. Stelling C, Singh CR, Karg M, König TA, Thelakkat M, Retsch M (2017) Plasmonic nanomeshes: their ambivalent role as transparent electrodes in organic solar cells. Sci Rep 7(1):42530. https://doi.org/10.1038/srep4253010.1038/srep42530 ↗
50. Konig TA, Ledin PA, Kerszulis J, Mahmoud MA, El-Sayed MA, Reynolds JR, Tsukruk VV (2014) Electrically tunable plasmonic behavior of nanocube-polymer nanomaterials induced by a redox-active electrochromic polymer. ACS Nano 8(6):6182–6192. https://doi.org/10.1021/nn501601e10.1021/nn501601e ↗
51. Chen CW, Hsiao SY, Chen CY, Kang HW, Huang ZY, Lin HW (2015) Optical properties of organometal halide perovskite thin films and general device structure design rules for perovskite single and tandem solar cells. J Mater Chem A 3(17):9152–9159. https://doi.org/10.1039/C4TA05237D10.1039/C4TA05237D ↗
52. Monestier F, Simon JJ, Torchio P, Escoubas L, Flory F, Bailly S, de Bettignies R, Guillerez S, Defranoux C (2007) Modeling the short-circuit current density of polymer solar cells based on P3HT: PCBM blend. Sol Energy Mater Sol Cells 91(5):405–410. https://doi.org/10.1016/j.solmat.2006.10.01910.1016/j.solmat.2006.10.019 ↗
53. Tumbleston JR, Ko DH, Lopez R, Samulski ET (2008) Characterizing enhanced performance of nanopatterned bulk heterojunction organic photovoltaics. In: Nanoscale photonic and cell technologies for photovoltaics (Vol. 7047). SPIE, pp 118-126. https://doi.org/10.1117/12.79482310.1117/12.794823 ↗
54. Palik ED (ed.) (1998) Handbook of optical constants of solids (Vol. 3). Academic Press10.1016/B978-0-08-055630-7.50004-3 ↗
55. Bazzari HH, Abushgair KN, Hamdan MA, Alkhaldi HS (2020) Cooling solar cells using ZnO nanoparticles as a down-shifter. Thermal Sci 24(2 Part A):809–814. https://doi.org/10.2298/TSCI180324004B10.2298/TSCI180324004B ↗