Luminescent composite based on epoxy polymer and silica nanoparticles doped by terbium(III) complex
Source abstract
Abstract
The interaction of the NPEL-128 epoxy oligomer with silica nanoparticles doped with terbium(III) complex with p-sulfonatothiacalix[4]arene was studied for two types of nanoparticles: possessing silanol hydroxyl groups on the non-modified surface of the nanoparticles (SNs) or amino and hydroxyl groups on the amino-modified silica surface (ASNs). The possible reaction schemes of amino and hydroxyl groups on the surface of ASNs with epoxy molecules were revealed using IR spectroscopy and DSC. Based on the obtained data, a method for producing epoxy nanocomposites was developed, and their thermophysical, physicomechanical, and luminescent properties were investigated. The chemical bonding of epoxy with ASNs compared with that of SNs allows one to obtain a higher dispersion and uniform distribution of the nanoparticles in the polymer matrix, as well as to increase the glass transition temperature of the polymer. Due to the presence of terbium(III) complex in silica nanoparticles, the cured epoxyamine polymer filled by ASNs exhibits luminescent properties.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Lanthanide and Transition Metal Complexes · Silicone and Siloxane Chemistry · Luminescence Properties of Advanced Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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