journal article·2016-07

Photoactive nanocomplex formed from chlorophyll assembly on TMA-coated iron oxide nanoparticles

Sibel Barbaros, Zeynep Meray, Tuğba Tecim, Rükan Genç

Journal of Nanoparticle Research· Volume 18· Issue 7
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Abstract

In this study, hierarchical self-assembly of photocatalytic nanodisks through non-covalent interactions between spinach-extracted chlorophyll molecules and trimethylammonium hydroxide-coated magnetic iron oxide nanoparticles was discussed. Combination of chlorophyll molecules with iron oxide nanoparticles generated an alteration in light absorption at both visible and near-IR region with accompanying enhancement in fluorescence emission. Further, photocatalytic role of resulting molecular assembly was studied by means of the photoinduced degradation of methylene blue dye under UV light and direct sun irradiation at neutral pH. In order to enhance the long-term stability of the hybrid nanocatalyst, commercially available cellulose membrane was used as a support and magnetic recovery and reusability was achieved where the nanocatalyst retained more than 90 % of its efficiency even after four cycles. This simple strategy could initiate the development of new materials for wastewater treatment including membrane-based technologies. On the other hand, their sunlight-induced photocatalytic activity could easily be conducted to dye-synthesized solar cells or their enhanced photoluminescence can provide a strong basis for future bioimaging tools.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Algal biology and biofuel production · Photosynthetic Processes and Mechanisms · Porphyrin and Phthalocyanine Chemistry

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