journal article·2018-08

Comparison of different types of polypyrimidine/CNTs/Pt hybrids in fuel cell catalysis

Naziermu Dongmulati, Salamaiti Baikeri, Xieraili Maimaitiyiming, Yumaierjiang Maimaiti

Journal of Nanoparticle Research· Volume 20· Issue 8
Publisher page

Abstract

In this paper, we mainly studied the preparation of platinum-containing composite materials with carbon nanotubes wrapped by polypyrimidine-conjugated polymers and the performance of the composites. The polymer-based carbon nanotubes/Pt catalysts were prepared successfully and confirmed by infrared spectroscopy, XPS, XRD, and TEM images. The performance of polypyrimidine/multi-walled carbon nanotubes (MWCNTs)/Pt and polypyrimidine/double-walled carbon nanotubes (DWCNTs)/Pt was compared with the polypyrimidine/single-walled carbon nanotubes (SWCNTs)/Pt. The amount of the loaded Pt on the polypyrimidine/MWCNTs and polypyrimidine/DWCNTs was calculated to be 50.5 wt% and 52.7 wt% respectively. The effective specific surface area of the polypyrimidine/MWCNTs/Pt (45.7 m2/g) and polypyrimidine/DWCNTs/Pt (42.47 m2/g) was observed by electrochemical cyclic voltammetry. These studies strongly imply that the MWCNTs were better candidates than DWCNTs and SWCNTs in the application of polypyrimidine/CNT materials as catalyst for fuel cells.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Carbon Nanotubes in Composites · Conducting polymers and applications · Fuel Cells and Related Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (17)

Show source-provided references
1. Baikeri S, Maimaitiyiming X (2017) Polypyrimidine/SWCNTS composite comprising Pt nanoparticles: possible electrocatalyst for fuel cell polymer science. Series A 59:734–740. https://doi.org/10.1134/s0965545x1705003010.1134/s0965545x17050030 ↗
2. Chen A, Holt-Hindle P (2010) Platinum-based nanostructured materials: synthesis, properties, and applications. Chem Rev 110:376710.1021/cr9003902 ↗
3. Fujigaya T, Okamoto M, Nakashima N (2009) Design of an assembly of pyridine-containing polybenzimidazole, carbon nanotubes and Pt nanoparticles for a fuel cell electrocatalyst with a high electrochemically active surface area. Carbon 47:3227–3232. https://doi.org/10.1016/j.carbon.2009.07.03810.1016/j.carbon.2009.07.038 ↗
4. Hanelt S, Orts-Gil G, Friedrich JF, Meyer-Plath A (2011) Differentiation and quantification of surface acidities on MWCNTs by indirect potentiometric titration Carbon 49:2978–298810.1016/j.carbon.2011.03.016 ↗
5. Hsu R, Chen Z (2009) Platinum/tin oxide - single walled carbon nanotube electrocatalysts for direct ethanol fuel cell: 1169–1176 doi: https://doi.org/10.1149/1.321067110.1149/1.3210671 ↗
6. Li M-M, Wu Z-P, Zhao M, Zhang W-B, Hu Y-Y, Yin Y-H (2015) Preparation of homogeneously dispersed and highly concentrated double-walled carbon nanotubes as catalyst support. Rare Metals 35:337–343. https://doi.org/10.1007/s12598-014-0441-x10.1007/s12598-014-0441-x ↗
7. Perez J, Paganin VA, Antolini E (2011) Particle size effect for ethanol electro-oxidation on Pt/C catalysts in half-cell and in a single direct ethanol fuel cell. J Electroanal Chem 654:108–115. https://doi.org/10.1016/j.jelechem.2011.01.01310.1016/j.jelechem.2011.01.013 ↗
8. Punetha VD, Rana S, Yoo HJ, Chaurasia A, McLeskey JT Jr, Ramasamy MS, Sahoo NG, Cho JW (2017) Functionalization of carbon nanomaterials for advanced polymer nanocomposites: a comparison study between CNT and graphene. Prog Polym Sci 67:1–47. https://doi.org/10.1016/j.progpolymsci.2016.12.01010.1016/j.progpolymsci.2016.12.010 ↗
9. Saha A, Jiang C, Martí AA (2014) Carbon nanotube networks on different platforms. Carbon 79:1–18. https://doi.org/10.1016/j.carbon.2014.07.06010.1016/j.carbon.2014.07.060 ↗
10. Salehi E, Madaeni SS, Rajabi L, Vatanpour V, Derakhshan AA, Zinadini S, Ghorabi S, Ahmadi Monfared H (2012) Novel chitosan/poly(vinyl) alcohol thin adsorptive membranes modified with amino functionalized multi-walled carbon nanotubes for Cu(II) removal from water: preparation, characterization, adsorption kinetics and thermodynamics. Sep Purif Technol 89:309–319. https://doi.org/10.1016/j.seppur.2012.02.00210.1016/j.seppur.2012.02.002 ↗
11. Sanchez DVP, Huynh P, Kozlov ME, Baughman RH, Vidic RD, Yun M (2010) Carbon nanotube/platinum (Pt) sheet as an improved cathode for microbial fuel cells. Energy Fuel 24:5897–5902. https://doi.org/10.1021/ef100825h10.1021/ef100825h ↗
12. Selvaraj V, Alagar M, Kumar K (2007) Synthesis and characterization of metal nanoparticles-decorated PPY–CNT composite and their electrocatalytic oxidation of formic acid and formaldehyde for fuel cell applications. Appl Catal B Environ 75:129–138. https://doi.org/10.1016/j.apcatb.2007.03.01210.1016/j.apcatb.2007.03.012 ↗
13. Sidik S, Mamtimin X (2014) Supramolecular functionalization of single-walled carbon nanotubes with poly(2,5-dihexyl-1,4-phenylene-alt-2-amino-4,6-pyrimidine) and their electrochemical performance. J Mater Res 29:2634–2643. https://doi.org/10.1557/jmr.2014.31810.1557/jmr.2014.318 ↗
14. Su H-Y, Sun K (2014) DFT study of the stability of oxygen vacancy in cubic ABO3 perovskites. J Mater Sci 50:1701–1709. https://doi.org/10.1007/s10853-014-8731-010.1007/s10853-014-8731-0 ↗
15. Tang H, Chen JH, Huang ZP, Wang DZ, Ren ZF, Nie LH, Kuang YF, Yao SZ (2004) High dispersion and electrocatalytic properties of platinum on well-aligned carbon nanotube arrays. Carbon 42:191–19710.1016/j.carbon.2003.10.023 ↗
16. Tao L, Dou S, Ma Z, Wang S (2015) Platinum nanoparticles supported on nitrobenzene-functionalized multiwalled carbon nanotube as efficient electrocatalysts for methanol oxidation reaction. Electrochim Acta 157:46–53. https://doi.org/10.1016/j.electacta.2015.01.05410.1016/j.electacta.2015.01.054 ↗
17. Yang DQ, Sun S, Dodelet JP, Sacher E (2008) A facile route for the self-organized high-density decoration of Pt nanoparticles on carbon nanotubes. J Phys Chem C 112:11717–1172110.1021/jp802371p ↗