A comparative study of alumina-supported Ni catalysts prepared by photodeposition and impregnation methods on the catalytic ozonation of 2,4-dichlorophenoxyacetic acid
Source abstract
Abstract
The heterogeneous catalytic ozonation on unsupported and supported oxides has been successfully tested for the removal of several refractory compounds in aqueous solution. In this work, alumina-supported nickel catalysts prepared by photodeposition and impregnation methods were compared in the catalytic ozonation of 2,4-dichlorophenoxyacetic acid (2,4-D). The catalysts were characterized by high-resolution electron microscopy and X-ray photoelectron spectroscopy. The photochemical decomposition of Ni acetylacetonate to produce Ni(OH)2, NiO, and traces of Ni° deposited on alumina was achieved in the presence of benzophenone as a sensitizer. A similar surface composition was found with the impregnated catalyst after its reduction with hydrogen at 500 °C and exposed to ambient air. Results indicated a higher initial activity and maleic acid (byproduct) concentration with the photodeposited catalyst (1 wt% Ni) compared to the impregnated catalyst (3 wt% Ni). These findings suggest the use of the photodeposition method as a simple and reliable procedure for the preparation of supported metal oxide/metal catalysts under mild operating conditions.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Catalytic Processes in Materials Science · TiO2 Photocatalysis and Solar Cells · Advanced oxidation water treatment
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References (36)
Show source-provided references
1. Avramescu SM, Bradu C, Udrea I, Mihalache N, Ruta F (2008) Degradation of oxalic acid from aqueous solutions by ozonation in presence of Ni/Al2O3 catalysts. Cat Commun 9:2386–239110.1016/j.catcom.2008.06.001 ↗
2. Biesinger MC, Payne BP, Lau LWM, Gerson A, Smart RSC (2009) X-ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems. Surf Interface Anal 41:324–33210.1002/sia.3026 ↗
3. Crisafulli C, Scirè S, Giuffrida S, Ventimiglia G, Lo Nigro R (2006) An investigation on the use of liquid phase photo-deposition for the preparation of supported Pt catalysts. Appl Catal A 306:51–5710.1016/j.apcata.2006.03.035 ↗
4. Ernst M, Lurot F, Schrotter J-C (2004) Catalytic ozonation of refractory organic model compounds in aqueous solution by aluminum oxide. Appl Catal B 47:15–2510.1016/S0926-3373(03)00290-X ↗
5. Gautam RK, Chattopadhyaya MC (2016) Advanced nanomaterials for wastewater remediation. CRC Press 1st Ed. 33–48
6. Giuffrida S, Condorelli GG, Costanzo LL, Ventimiglia G, Lo Nigro R, Favazza M, Votrico E, Bongiorno C, Fragala IL (2007) Nickel nanostructured materials from liquid phase photodeposition. J Nanopart Res 9:611–61910.1007/s11051-006-9089-2 ↗
7. Guzman-Perez CA, Soltan J, Robertson J (2012) Catalytic ozonation of 2,4-dichlorophenoxyacetic acid using alumina in the presence of a radical scavenger. J Environ Sci Health B 47:544–55210.1080/03601234.2012.665675 ↗
8. Ichikawa S-I, Mahardiani L, Kamiya Y (2014) Catalytic oxidation of ammonium ion in water with ozone over metal oxide catalysts. Cat Today 232:192–19710.1016/j.cattod.2013.09.039 ↗
9. Ikhlaq A, Brown DR, Kasprzyk-Hordern B (2012) Mechanisms of catalytic ozonation on alumina and zeolites in water: formation of hydroxyl radicals. Appl Catal B 123–124:94–10610.1016/j.apcatb.2012.04.015 ↗
10. Ikhlaq A, Brown DR, Kasprzyk-Hordern B (2013) Mechanisms of catalytic ozonation: an investigation into superoxide ion radical and hydrogen peroxide formation during catalytic ozonation on alumina and zeolites in water. Appl Catal B 129:437–44910.1016/j.apcatb.2012.09.038 ↗
11. Karmhag R, Niklasson GA, Nygren M (2001) Oxidation kinetics of nickel nanoparticles. J Appl Phys 89:3012–301710.1063/1.1325002 ↗
12. Kometani N, Doi H, Asami K, Yonezawa Y (2002) Laser flash photolysis study of the photochemical formation of colloidal Ag nanoparticles in the presence of benzophenone. Phys Chem Chem Phys 4:5142–514710.1039/b205829d ↗
13. Krylova GV, Eremenko AM, Smirnova NP, Eustis S (2005) Photogeneration of nanosized gold on the surface of mesoporous silica modified by benzophenone. Theor Exp Chem 41:365–37010.1007/s11237-006-0004-9 ↗
14. Molina R, Poncelet G (1999) α-Alumina-supported nickel catalysts prepared with nickel acetylacetonate. 2. A study of the thermolysis of the metal precursor. J Phys Chem B 103:11290–1129610.1021/jp9907286 ↗
15. Moulder JF, Stickle WF, Sobol PE, Bomben KD (1995) Handbook of x-ray photoelectron spectroscopy: a reference book of standard spectra for identification and interpretation of XPS data. Physical Electronics
16. Nawrocki J (2013) Catalytic ozonation in water: controversies and questions. Appl Catal B 142:465–47110.1016/j.apcatb.2013.05.061 ↗
17. Nawrocki J, Kasprizk-Hordern B (2010) The efficiency and mechanisms of catalytic ozonation. Appl Catal B 99:27–4210.1016/j.apcatb.2010.06.033 ↗
18. Nie Y, Hu C, Yang L, Hu J (2013) Inhibition mechanism of BrO3 − formation over MnO x /Al2O3 during the catalytic ozonation of 2,4-dichlorophenoxyacetic acid in water. Sep Purif Tech 117:41–4510.1016/j.seppur.2013.03.045 ↗
19. Pocostales P, Álvarez P, Beltrán FJ (2011) Catalytic ozonation promoted by alumina-based catalysts for the removal of some pharmaceutical compounds from water. Chem Eng J 168:1289–129510.1016/j.cej.2011.02.042 ↗
20. Poznyak T, Chairez I, Poznyak A (2005) Application of a neural observer to phenols ozonation in water: simulation and kinetic parameters identification. Water Res 39:2611–262010.1016/j.watres.2005.04.061 ↗
21. Prieto P, Nistor V, Nouneh K, Oyama M, Abd-Lefdil M, Díaz R (2012) XPS study of silver, nickel and bimetallic silver–nickel nanoparticles prepared by seed-mediated growth. Appl Surf Sci 258:8807–881310.1016/j.apsusc.2012.05.095 ↗
22. Qi F, Chen Z, Xu B, Shen B, Shen J, Ma J, Joll C, Heitz A (2008) Influence of surface texture and acid–base properties on ozone decomposition catalyzed by aluminum (hydroxyl) oxides. Appl Catal B 84:684–69010.1016/j.apcatb.2008.05.027 ↗
23. Qi F, Xu B, Chen Z, Feng L, Zhang L, Sun D (2013) Catalytic ozonation of 2-isopropyl-3-methoxypyrazine in water by γ-AlOOH and γ-Al2O3: comparison of removal efficiency and mechanism. Chem Eng J 219:527–53610.1016/j.cej.2013.01.035 ↗
24. Rodríguez JL, Valenzuela MA, Tiznado H, Pola F, Tiznado H, Poznyak T (2012) Photodeposition of Ni nanoparticles on TiO2 and their application in the catalytic ozonation of 2,4-dichlorophenoxyacetic acid. J Mol Catal A 353:29–3610.1016/j.molcata.2011.11.001 ↗
25. Rodríguez JL, Valenzuela M, Poznyak T, Lartundo L, Chairez I (2013) Reactivity of NiO for 2,4-D degradation with ozone: XPS studies. J Hazard Mat 262:472–48110.1016/j.jhazmat.2013.08.041 ↗
26. Rodríguez JL, Valenzuela M, Tiznado H, Poznyak T, Flores E (2014) Synthesis of nickel oxide nanoparticles supported on SiO2 by sensitized liquid phase photodeposition for applications in catalytic ozonation. J Mol Catal A 392:39–4910.1016/j.molcata.2014.04.028 ↗
27. Rosal R, Gonzalo MS, Rodríguez A, García-Calvo E (2010) Catalytic ozonation of fenofibric acid over alumina-supported manganese oxide. J Hazard Mater 183:271–27810.1016/j.jhazmat.2010.07.021 ↗
28. Sakamoto M, Fujistuka M, Majima T (2009) Light as a construction tool of metal nanoparticles: synthesis and mechanism. J Photochem Photobiol C 10:33–5610.1016/j.jphotochemrev.2008.11.002 ↗
29. Scirè S, Crisafulli C, Giuffrida S, Mazza C, Riccobene PM, Pistone A, Ventimiglio G, Bongiorno C, Spinella C (2009) Supported silver catalysts prepared by deposition in aqueous solution of Ag nanoparticles obtained through a photochemical approach. Appl Cat A 367:138–14510.1016/j.apcata.2009.07.046 ↗
30. Scirè S, Giuffrida S, Crisafulli C, Riccobene PM, Pistone A (2011) Direct and sensitized liquid phase photodeposition for the preparation of alumina supported Pd nanoparticles for applications to heterogeneous catalysis. J Nanopart Res 13:3217–322810.1007/s11051-011-0222-5 ↗
31. Scirè S, Giuffrida S, Crisafulli C, Riccobene PM, Pistone A (2012) Liquid phase photo-deposition in the presence of unmodified β-cyclodextrin: a new approach for the preparation of supported Pd catalysts. J Mol Catal A 353–354:87–9410.1016/j.molcata.2011.11.009 ↗
32. Uchikoshi T, Sakka Y, Yoshitake M, Yoshihara K (1994) A study of the passivating oxide layer on fine nickel particles. Nanostructured Mater 4:199–20610.1016/0965-9773(94)90078-7 ↗
33. Vittenet J, Aboussaoud W, Mendret J, Pic JS, Debeffefontaine H, Lessage N, Faucher K, Manero M-H, Starzyk FT, Leclerc H, Galarneau A, Brosillon S (2015) Catalytic ozonation with γ-Al2O3 to enhance the degradation of refractory organics in water. Appl Catal A 504:519–53210.1016/j.apcata.2014.10.037 ↗
34. Yang L, Hu C, Nie Y, Qu J (2009) Catalytic ozonation of selected pharmaceuticals over mesoporous alumina-supported manganese oxide. Environ Sci Technol 43:2525–252910.1021/es803253c ↗
35. Yang L, Hu C, Nie Y, Qu J (2010) Surface acidity and reactivity of β-FeOOH/Al2O3 for pharmaceuticals degradation with ozone: in situ ATR-FTIR studies. Appl Catal B 97:340–34610.1016/j.apcatb.2010.04.014 ↗
36. Zhang T, Li W, Crové J-P (2012) A non-acid-assisted and non-hydroxyl-radical-related catalytic ozonation with ceria supported copper oxide in efficient oxalate degradation in water. Appl Catal B 121:88–9410.1016/j.apcatb.2012.03.021 ↗