Radiation synthesized poly(n-vinyl-2-pyrrolidone)-stabilized-gold nanoparticles as LSPR-based optical sensor for mercury ions estimation
Source abstract
Abstract
Poly(n-vinyl-2-pyrrolidone)-stabilized-gold nanoparticles (PVP-Au-NPs) have been synthesized via a green-60Co-Gamma radiolytic route and employed as a localized surface plasmon resonance (LSPR)-based optical sensor for estimation of trace quantities of Hg2+ ion in aqueous solutions. The in situ generated PVP-Au-NPs were characterized using UV–vis spectroscopy, transmission electron microscopy, and particle size analysis techniques. Reaction conditions were optimized to obtain uniformly dispersed PVP-Au-NPs with average particle size of 7.1 ± 1.6 nm (±s), which exhibited a narrow LSPR band at ~527 nm. The decrease in LSPR band intensity of PVP-Au-NPs with increase in Hg2+ ion concentration was found to be linear in the Hg2+ ion concentration range of 0–100 nM. The LSPR-based PVP-Au-NPs optical sensor system was found to be selective for Hg2+ and independent of interference from other metal ions such as Ca2+, Cu2+, Cd2+, and Fe2+ up to a concentration of 500 nM.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Gold and Silver Nanoparticles Synthesis and Applications · Advanced biosensing and bioanalysis techniques · Electrochemical Analysis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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