Hierarchical MnO2 nanosheets coated on MnCo2O4.5 nanoneedles as advanced electrode for high-efficient hybrid supercapacitor
Source abstract
Abstract
The MnCo2O4.5@MnO2 composite nanomaterial was successfully designed and synthesized via successive hydrothermal and subsequent calcination methods, in which MnO2 nanosheets coated on MnCo2O4.5 nanoneedle arrays were directly grown on Ni foam. Compared with pristine MnCo2O4.5 nanoneedle electrode, MnCo2O4.5@MnO2 composite electrode exhibits a high specific discharge capacitance of 1155 F g-1 at a current density of 1.43 A g-1, the capacitance retention of 93.4% after 5000 cycles, and low initial internal resistance of 1.9 Ω. The results reveal that the rational design of MnCo2O4.5@MnO2 electrode with such structure and composition is an effective strategy to improve electrochemical performances of MnCo2O4.5. Due to unique nanostructure and brilliant electrochemical properties of MnCo2O4.5@MnO2 electrode, the fabricated hybrid supercapacitor based on MnCo2O4.5@MnO2 positive electrode and activated carbon negative electrode delivers the wide operating voltage window of 1.6 V, a capacitance retention of 87.8% after 8000 continuous charge-discharge cycles at a current density of 1.33 A g-1, the maximum energy density of 40.8 Wh kg-1 at a power density of 263.9 W kg-1, and highest power density of 1336.6 W kg-1 to achieve an energy density of 24.4 Wh kg-1. Herein, the designed MnCo2O4.5@MnO2 composite is a distinguished candidate material for hybrid supercapacitor.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Supercapacitor Materials and Fabrication · Advanced Sensor and Energy Harvesting Materials · Advancements in Battery Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (41)
Show source-provided references
1. Cai N, Fu J, Chan V, Liu M, Chen W, Wang J, Zeng H, Yu F (2019) MnCo2O4@nitrogen-doped carbon nanofiber composites with meso-microporous structure for high-performance symmetric supercapacitors. J Alloys Compd 782:251–262. https://doi.org/10.1016/j.jallcom.2018.12.04410.1016/j.jallcom.2018.12.044 ↗
2. Chen T, Shi R, Zhang Y, Wang Z (2019) A MnCo2O4@NiMoO4 core-shell composite supported on nickel foam as a supercapacitor electrode for energy storage. ChemPlusChem 84:69–77. https://doi.org/10.1002/cplu.20180054910.1002/cplu.201800549 ↗
3. Fu W, Zhao C, Han W, Liu Y, Zhao H, Ma Y, Xie E (2015) Cobalt sulfide nanosheets coated on NiCo2S4 nanotube arrays as electrode materials for high-performance supercapacitors. J Mater Chem A 3:10492–10497. https://doi.org/10.1039/C5TA00742A10.1039/C5TA00742A ↗
4. Fu L, Qu Q, Holze R, Kondratiev VV, Wu Y (2019) Composites of metal oxides and intrinsically conducting polymers as supercapacitor electrode materials: the best of both worlds? J Mater Chem A 7:14937–14970. https://doi.org/10.1039/C8TA10587A10.1039/C8TA10587A ↗
5. Gao Y, Mi L, Wei W, Cui S, Zheng Z, Hou H, Chen W (2015) Double metal ions synergistic effect in hierarchical multiple sulfide microflowers for enhanced supercapacitor performance. ACS Appl Mater Interfaces 7:4311–4319. https://doi.org/10.1021/am508747m10.1021/am508747m ↗
6. González A, Goikolea E, Barrena JA, Mysyk R (2016) Review on supercapacitors: technologies and materials. Renew Sust Energy Rev 58:1189–1206. https://doi.org/10.1016/j.rser.2015.12.24910.1016/j.rser.2015.12.249 ↗
7. Guan C, Liu J, Wang Y, Mao L, Fan Z, Shen Z, Zhang H, Wang J (2015) Iron oxide-decorated carbon for supercapacitor anodes with ultrahigh energy density and outstanding cycling stability. ACS Nano 9:5198–5207. https://doi.org/10.1021/acsnano.5b0058210.1021/acsnano.5b00582 ↗
8. Hao Z, Yang S, Niu J, Fang Z, Liu L, Dong Q, Song S, Zhao Y (2018) A bimetallic oxide Fe1.89Mo4.11O7 electrocatalyst with highly efficient hydrogen evolution reaction activity in alkaline and acidic media. Chem Sci 9:5640–5645. https://doi.org/10.1039/c8sc01710g10.1039/c8sc01710g ↗
9. Huang M, Zhang Y, Li F, Zhang L, Wen Z, Liu Q (2014) Facile synthesis of hierarchical Co3O4@MnO2 core-shell arrays on Ni foam for asymmetric supercapacitors. J Power Sources 252:98–106. https://doi.org/10.1016/j.jpowsour.2013.12.03010.1016/j.jpowsour.2013.12.030 ↗
10. Huang Z, Zhang Z, Qi X, Ren X, Xu G, Wan P, Sun X, Zhang H (2016) Wall-like hierarchical metal oxide nanosheet arrays grown on carbon cloth for excellent supercapacitor electrodes. Nanoscale 8:13273–13279. https://doi.org/10.1039/C6NR04020A10.1039/C6NR04020A ↗
11. Ji F, Jiang D, Xia Q, Pan X, Chen X, Zhang Y (2019) High-performance MoO3 nanoplate electrode for asymmetric supercapacitor with long-term electrochemical stability. J Nanosci Nanotechnol 19:5817–5824. https://doi.org/10.1166/jnn.2019.1655510.1166/jnn.2019.16555 ↗
12. Kasap S, Kaya II, Repp S, Erdem E (2019) Superbat: battery-like supercapacitor utilized by graphene foam and zinc oxide (ZnO) electrodes induced by structural defects. Nanoscale Adv 1:2586–2597. https://doi.org/10.1039/C9NA00199A10.1039/C9NA00199A ↗
13. Krishnan SG, Rahim MHA, Jose R (2016) Synthesis and characterization of MnCo2O4 cuboidal microcrystals as a high performance psuedocapacitor electrode. J Alloys Compd 656:707–713. https://doi.org/10.1016/j.jallcom.2015.10.00710.1016/j.jallcom.2015.10.007 ↗
14. Kuang L, Ji F, Pan X, Wang D, Chen X, Jiang D, Zhang Y, Ding B (2017) Mesoporous MnCo2O4.5 nanoneedle arrays electrode for high-performance asymmetric supercapacitor application. Chem Eng J 315:491–499. https://doi.org/10.1016/j.cej.2017.01.02510.1016/j.cej.2017.01.025 ↗
15. Lian J, Xiong L, Cheng R, Pang D, Tian X, Lei J, He R, Yu X, Duan T, Zhu W (2019) Ultra-high nitrogen content biomass carbon supercapacitors and nitrogen forms analysis. J Alloys Compd 809:151664. https://doi.org/10.1016/j.jallcom.2019.15166410.1016/j.jallcom.2019.151664 ↗
16. Liang M, Zhao M, Wang H, Shen J, Song X (2018) Enhanced cycling stability of hierarchical NiCo2S4@Ni(OH)2@PPy core-shell nanotube arrays for aqueous asymmetric supercapacitors. J Mater Chem A 6:2482–2493. https://doi.org/10.1039/C7TA10413H10.1039/C7TA10413H ↗
17. Liao F, Han X, Zhang Y, Xu C, Chen H (2018) Solvothermal synthesis of porous MnCo2O4.5 spindle-like microstructures as high-performance electrode materials for supercapacitors. Ceram Int 44:22622–22631. https://doi.org/10.1016/j.ceramint.2018.09.03810.1016/j.ceramint.2018.09.038 ↗
18. Liu SP, Pan XX (2020) An aqueous hybrid supercapacitor employing honeycomb-shaped MoS2 nanosheets as anode. J Nanosci Nanotechnol 20:1020–1027. https://doi.org/10.1166/jnn.2020.1690710.1166/jnn.2020.16907 ↗
19. Liu S, Hui KS, Hui KN (2015) 1 D Hierarchical MnCo2O4 Nanowire@MnO2 Sheet core-shell arrays on graphite paper as superior electrodes for asymmetric supercapacitors. ChemNanoMat 1:593–602. https://doi.org/10.1002/cnma.20150010510.1002/cnma.201500105 ↗
20. Mai LQ, Minhas-Khan A, Tian X, Hercule KM, Zhao YL, Lin X, Xu X (2013) Synergistic interaction between redox-active electrolyte and binder-free functionalized carbon for ultrahigh supercapacitor performance. Nat Commun 4:1–7. https://doi.org/10.1038/ncomms392310.1038/ncomms3923 ↗
21. Moradlou O, Sharifpour H (2020) Interconnected NiCo2S4 - coated NiO nanosheet arrays as electrode materials for high-performance supercapacitors. J Energy Storage 32:101886. https://doi.org/10.1016/j.est.2020.10188610.1016/j.est.2020.101886 ↗
22. Najib S, Erdem E (2019) Current progress achieved in novel materials for supercapacitor electrodes: mini review. Nanoscale Adv 1:2817–2827. https://doi.org/10.1039/c9na00345b10.1039/c9na00345b ↗
23. Najib S, Bakan F, Abdullayeva N, Bahariqushchi R, Kasap S, Franzò G, Sankir M, Sankir ND, Mirabella S, Erdem E (2020) Tailoring morphology to control defect structures in ZnO electrodes for high-performance supercapacitor devices. Nanoscale 12:16162–16172. https://doi.org/10.1039/d0nr03921g10.1039/d0nr03921g ↗
24. Nandi D, Mohan VB, Bhowmick AK, Bhattacharyya D (2020) Metal/metal oxide decorated graphene synthesis and application as supercapacitor: a review. J Mater Sci 55:6375–6400. https://doi.org/10.1007/s10853-020-04475-z10.1007/s10853-020-04475-z ↗
25. Nie G, Lu X, Chi M, Zhu Y, Yang Z, Song N, Wang C (2017) Hierarchical α-Fe2O3@MnO2 core-shell nanotubes as electrode materials for high-performance supercapacitors. Electrochim Acta 231:36–43. https://doi.org/10.1016/j.electacta.2017.02.03710.1016/j.electacta.2017.02.037 ↗
26. Orazem ME, Tribollet B (2008) An integrated approach to electrochemical impedance spectroscopy. Electrochim Acta 53:7360–7366. https://doi.org/10.1016/j.electacta.2007.10.07510.1016/j.electacta.2007.10.075 ↗
27. Pan X, Ji F, Kuang L, Liu F, Zhang Y, Chen X, Alameh K, Ding B (2016) Synergetic effect of three-dimensional Co3O4@Co(OH)2 hybrid nanostructure for electrochemical energy storage. Electrochim Acta 215:298–304. https://doi.org/10.1016/j.electacta.2016.08.10210.1016/j.electacta.2016.08.102 ↗
28. Pan X, Ji F, Xia Q, Chen X, Pan H, Khisro SN, Luo S, Chen M, Zhang Y (2018) High-performance supercapacitors based on superior Co3O4 nanorods electrode for integrated energy harvesting-storage system. Electrochim Acta 282:905–912. https://doi.org/10.1016/j.electacta.2018.06.12710.1016/j.electacta.2018.06.127 ↗
29. Pettong T, Iamprasertkun P, Krittayavathananon A, Sukha P, Sirisinudomkit P, Seubsai A, Chareonpanich M, Kongkachuichay P, Limtrakul J, Sawangphruk M (2016) High-performance asymmetric supercapacitors of MnCo2O4 nanofibers and N-doped reduced graphene oxide aerogel. ACS Appl Mater Interfaces 8:34045–34053. https://doi.org/10.1021/acsami.6b0944010.1021/acsami.6b09440 ↗
30. Sumboja A, Liu J, Zheng WG, Zong Y, Zhang H, Liu Z (2018) Electrochemical energy storage devices for wearable technology: a rationale for materials selection and cell design. Chem Soc Rev 47:5919–5945. https://doi.org/10.1039/c8cs00237a10.1039/c8cs00237a ↗
31. Toufani M, Kasap S, Tufani A, Bakan F, Weber S, Erdem E (2020) Synergy of nano-ZnO and 3D-graphene foam electrodes for asymmetric supercapacitor devices. Nanoscale 12:12790–12800. https://doi.org/10.1039/d0nr02028a10.1039/d0nr02028a ↗
32. Tuncer M, Bakan F, Gocmez H, Erdem E (2019) Capacitive behaviour of nanocrystalline octacalcium phosphate (OCP) (Ca8H2(PO4)6·5H2O) as an electrode material for supercapacitors: biosupercaps. Nanoscale 11:18375–18381. https://doi.org/10.1039/C9NR90235J10.1039/C9NR90235J ↗
33. Wang L, Ouyang Y, Jiao X, Xia X, Lei W, Hao Q (2018) Polyaniline-assisted growth of MnO2 ultrathin nanosheets on graphene and porous graphene for asymmetric supercapacitor with enhanced energy density. Chem Eng J 334:1–9. https://doi.org/10.1016/j.cej.2017.10.00510.1016/j.cej.2017.10.005 ↗
34. Wang P, Zhou H, Meng C, Wang Z, Akhtar K, Yuan A (2019a) Cyanometallic framework-derived hierarchical Co3O4-NiO/graphene foam as high-performance binder-free electrodes for supercapacitors. Chem Eng J 369:57–63. https://doi.org/10.1016/j.cej.2019.03.08010.1016/j.cej.2019.03.080 ↗
35. Wang Q, Ma Y, Liang X, Zhang D, Miao M (2019b) Flexible supercapacitors based on carbon nanotube-MnO2 nanocomposite film electrode. Chem Eng J 371:145–153. https://doi.org/10.1016/j.cej.2019.04.02110.1016/j.cej.2019.04.021 ↗
36. Xu K, Li W, Liu Q, Li B, Liu X, An L, Chen Z, Zou R, Hu J (2014) Hierarchical mesoporous NiCo2O4@MnO2 core-shell nanowire arrays on nickel foam for aqueous asymmetric supercapacitors. J Mater Chem A 2:4795–4802. https://doi.org/10.1039/C3TA14647B10.1039/C3TA14647B ↗
37. Xu K, Yang X, Yang J, Hu J (2017) Synthesis of hierarchical Co3O4@NiCo2O4 core-shell nanosheets as electrode materials for supercapacitor application. J Alloys Compd 700:247–251. https://doi.org/10.1016/j.jallcom.2017.01.07110.1016/j.jallcom.2017.01.071 ↗
38. Xu R, Lin J, Wu J, Huang M, Fan L, Xu Z, Song Z (2019) A high-performance pseudocapacitive electrode material for supercapacitors based on the unique NiMoO4/NiO nanoflowers. Appl Surf Sci 463:721–731. https://doi.org/10.1016/j.apsusc.2018.08.17210.1016/j.apsusc.2018.08.172 ↗
39. Zhai T, Lu X, Ling Y, Yu M, Wang G, Liu T, Liang C, Tong Y, Li Y (2014) A new benchmark capacitance for supercapacitor anodes by mixed-valence sulfur-doped V6O13 − x. Adv Mater 26:5869–5875. https://doi.org/10.1002/adma.20140204110.1002/adma.201402041 ↗
40. Zhao L, Yang M, Zhang Z, Ji Y, Teng Y, Feng Y, Liu X (2018) Hierarchical micro/nanostructured Co3O4@MnCo2O4 core-shell nanowire arrays on Ni foam for electrochemical energy storage. Inorg Chem Commun 89:22–26. https://doi.org/10.1016/j.inoche.2018.01.00310.1016/j.inoche.2018.01.003 ↗
41. Zou Y, Wang Y, Fang Z, Wu D, Yang S, Hao Z, Lang J, Dong Q (2018) Sulfur powder as a reducing agent to synthesize the Ni@Ni(OH)2 flower-like material for electrochemical capacitors. J Nanosci Nanotechnol 18:7732–7738. https://doi.org/10.1166/jnn.2018.1554910.1166/jnn.2018.15549 ↗