journal article·2015-12

Magnetic-field-assisted synthesis of Co3O4 nanoneedles with superior electrochemical capacitance

Tao Zhu, Yan Xie, Guoxiong Zhang, Zhenni He, Yisheng Lu, Haibo Guo, Chuan Lin, Yigang Chen

Journal of Nanoparticle Research· Volume 17· Issue 12
Publisher page

Abstract

Nanostructured Co3O4 films have been deposited on nickel foam in a magnetic-field-assisted hydrothermal process followed by annealing in air. The magnetic field strength is varied to study its relationship with nanostructures, morphology, and electrochemical properties of the Co3O4 electrodes. The Co3O4 films synthesized in the weak magnetic fields consist of dispersed nanoneedles, which are different from clustered nanoneedles when the magnetic field is absent. Moreover, the magnetic fields (of several millitesla) induced substantial changes in the nanostructures and electrochemical properties of the Co3O4 films. A possible formation mechanism of Co3O4 nanoneedles is proposed by comparing the morphologies and nanostructures of the films synthesized with and without the magnetic fields. Among these electrodes, the optimal one has a high specific capacitance (970.8 F g−1 at 0.5 A g−1), good power capability (847.5 F g−1 at 6.0 A g−1), and an excellent retention ratio (93.7 % over 1000 cycles). All these impressive results demonstrate that magnetic fields may be an economic and effective tool in hydrothermal synthesis of Co3O4 electrodes for high-performance supercapacitors.
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Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Advancements in Battery Materials · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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