Photocatalytic synthesis of N2/H2O to ammonia on coal based GO/SiO2 supported Ru composite catalyst
Source abstract
Abstract
Graphene oxide/silica (GO/SiO2) containing various inorganic particles is obtained by using the Xinjiang Wucaiwan coal as carbon source and silicon source. The ruthenium/graphene oxide/silica (Ru/GO/SiO2) composite was prepared by loading Ru nanoparticles on the surface of GO/SiO2. Then, the photocatalytic ammonia synthesis performance was investigated while characterizing the structure of Ru/GO/SiO2. On the one hand, the Ru can be sufficiently dispersed to make the surface plasmon resonance (SPR) effect enhance significantly. On the other hand, the quantum confinement effect of the defect structure on the Ru/GO/SiO2 can effectively separate electron and hole, and it can participate in the reducing/oxidizing reaction of photocatalytic ammonia synthesis.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced Photocatalysis Techniques · Caching and Content Delivery · Ammonia Synthesis and Nitrogen Reduction
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (46)
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1. Aika K, Kumasaka M, Oma T, Kato O, Matsuda H, Watanabe N, Yamazaki K, Ozaki A, Onishi T (1986) Support and promoter effect of ruthenium catalyst. III Kinetics of Ammonia Synthesis over Various Ru Catalysts. Appl Catal 28:57–6810.1016/S0166-9834(00)82492-6 ↗
2. Bi Y, Wang Y, Dong X, Zheng N, Ma H, Zhang X (2018) Efficient solar-driven conversion of nitrogen to ammonia in pure water via hydrogenated bismuth Oxybromide. RSC Adv 8(39):21871–2187810.1039/C8RA02483A ↗
3. Bindra G, Schulz M, Paul A, Soman S, Groarke R, Inglis J, Pryce M, Browne W, Rau S, Maclean B, Vos J (2011) The effect of peripheral bipyridine ligands on the photocatalytic hydrogen production activity of Ru/Pd catalysts. Dalton Trans 40:10812–1081410.1039/c1dt11241d ↗
4. Chao D, Zhou Y, Liu X, Jia X (2019) Synthesis and electrochromic properties of graphene oxides/silicon dioxide/oligoaniline interpenetrating network composite. New J Chem 43:3829–383410.1039/C8NJ06282J ↗
5. Chen L, Lei J, Wang F, Wang G, Feng H (2015) Facile synthesis of graphene sheets from fluorinated graphite. RSC Adv 5:40148–4015310.1039/C5RA00910C ↗
6. Choi DJ, Yang OB (2005) Effect of chelating agents on the properties of TiO2–SiO2 mixed oxide for photocatalytic water decomposition. Res Chem Inter 31:483–49110.1163/1568567053956662 ↗
7. Hinrichsen O, Rosowski F, Hornung A, Muhler M, Ertl G (1997) The kinetics of ammonia synthesis over Ru-based catalysts: the dissociative chemisorption and associative desorption of N2. J Catal 165(1):33–4410.1006/jcat.1997.1447 ↗
8. Hirakawa H, Hashimoto M, Shiraishi Y, Hirai T (2017) Photocatalytic conversion of nitrogen to ammonia with water on surface oxygen vacancies of titanium dioxide. J Am Chem Soc 139(31):10929–1093610.1021/jacs.7b06634 ↗
9. Hou Y, Wang XC, Wu L, Chen X, Zhengxin D, Wang X, Fu XZ (2008) N-doped SiO2/TiO2 mesoporous nanoparticles with enhanced photocatalytic activity under visible-light irradiation. Chemosphere. 72:414–42110.1016/j.chemosphere.2008.02.035 ↗
10. Hu JS, Ren LL, Guo YG, Liang HP, Cao AM, Dr LJ, Dr CL (2005) Mass production and high photocatalytic activity of ZnS nanoporous nanoparticles. Angew Chem Int Edit 44:1269–127310.1002/anie.200462057 ↗
11. Hu X, Mu L, Wen J, Zhou Q (2012) Covalently synthesized graphene oxide-aptamer nanosheets for efficient visible-light photocatalysis of nucleic acids and proteins of viruses. Carbon. 50(8):2772–278110.1016/j.carbon.2012.02.038 ↗
12. Huang P, Liu W, He Z, Xiao C, Yao T, Zou Y, Wang C, Qi Z, Tong W, Pan B, Wei S, Xie Y (2018) Single atom accelerates ammonia photosynthesis. Sci China Chem 61(9):1187–119610.1007/s11426-018-9273-1 ↗
13. Karteri I, Karatas S, Yakuphanoglu F (2016) Photosensing properties of pentacene thin film transistor with solution-processed silicon dioxide/graphene oxide bilayer insulators. J Mater Sci 27:5284–5293
14. Li Q, Guo B, Yu J, Ran J, Zhang B, Yan H, Gong JR (2011) Highly efficient visible-light-driven photocatalytic hydrogen production of CdS-cluster-decorated graphene nanosheets. J Am Chem Soc 133:10878–1088410.1021/ja2025454 ↗
15. Li H, Shang J, Ai Z, Zhang L (2015) Efficient visible light nitrogen fixation with BiOBr nanosheets of oxygen vacancies on the exposed {001} facets. J Am Chem Soc 137(19):6393–639910.1021/jacs.5b03105 ↗
16. Lin K, Li P, Wu Q, Feng S, Ma J, Yuan D (2018) Automated determination of ammonium in natural waters with reverse flow injection analysis based on the indophenol blue method with O-phenylphenol. Microchem J 138:519–52510.1016/j.microc.2018.02.004 ↗
17. Liu J, Wang Z, Liu L, Chen W (2011) Reduced graphene oxide as capturer of dyes and electrons during photocatalysis: surface wrapping and capture promoted efficiency. Phys Chem Chem Phys 13:13216–1322110.1039/c1cp20504h ↗
18. Ma H, Shi Z, Li Q, Li S (2016) Preparation of graphitic carbon nitride with large specific surface area and outstanding N2 photofixation ability via a dissolve-regrowth process. J Phys Chem Solids 99:51–5810.1016/j.jpcs.2016.08.008 ↗
19. Mi SY, Liu YX, Wang W (2016) Photo-depositing Ru and RuO2 on anatase TiO2 nanosheets as co-catalysts for photocatalytic O2 evolution from water oxidation. Chinese J Chem Phys 29:585–59010.1063/1674-0068/29/cjcp1603057 ↗
20. Miyama H, Fujii N, Nagae Y (1980) Heterogeneous photocatalytic synthesis of ammonia from water and nitrogen. Chem Phys Lett 74(3):523–52410.1016/0009-2614(80)85266-3 ↗
21. Miyazaki A, Balint I, Ki A, Nakano Y (2001) Preparation of Ru nanoparticles supported on γ-Al2O3 and its novel catalytic activity for ammonia synthesis. J Catal 204(2):364–37110.1006/jcat.2001.3418 ↗
22. Mou H, Jinfang W, Zhang D, Yu D, Chen W, Wang D, Mu T (2019) A one-step deep eutectic solvent assisted synthesis of carbon nitride/metal oxide composites for photocatalytic nitrogen fixation. J Mater Chem A 7:5719–572510.1039/C8TA11681D ↗
23. Murakami T, Nishikiori T, Nohira T, Ito Y (2013) Electrolytic synthesis of ammonia in molten salts under atmospheric pressure. ChemInform. 34(18):334–335
24. Nguyen-Phan TD, Pham VH, Shin EW, Pham HD, Kim S, Chung JS, Kim EJ, Hur SH (2011) The role of graphene oxide content on the adsorption-enhanced photocatalysis of titanium dioxide/graphene oxide composites. Chem Engineer J 170(1):226–23210.1016/j.cej.2011.03.060 ↗
25. Niu P, Qiao M, Li Y, Huang L, Zhai T (2018) Distinctive defects engineering in graphitic carbon nitride for greatly extended visible light photocatalytic hydrogen evolution. Nano Energy 44:73–8110.1016/j.nanoen.2017.11.059 ↗
26. Onsgaard J, Godowski P, Li Z (2012) Temperature induced changes in a AgPt Nanofilm on Ru(0001). J Vac Sci Technol A 30:01A111–01A11110.1116/1.3653986 ↗
27. Reddy DA, Ma R, Kim TK (2015) Efficient photocatalytic degradation of methylene blue by heterostructured ZnO–RGO/RuO2 nanocomposite under the simulated sunlight irradiation. Ceram Int 41(5, part B):6999–700910.1016/j.ceramint.2015.01.155 ↗
28. Rosowski F, Hinrichsen O, Muhler M, Ertl G (1996) The temperature-programmed desorption of N2 from a Ru/MgO catalyst used for ammonia synthesis. Catal Lett 36:229–23510.1007/BF00807624 ↗
29. Sasirekha N, Basha SJ, Shanthi K (2006) Photocatalytic performance of Ru doped anatase mounted on silica for reduction of carbon dioxide. Appl Catal B-Environ 62(1):169–18010.1016/j.apcatb.2005.07.009 ↗
30. Seemaladinne R, Pati S, Kharel K, Bafana A, Wahish A, Wujcik EK, Günaydın-Şen Ö (2017) Ammonia borane with polyvinylpyrrolidone as a hydrogen storage material: comparison of different molecular weights. J Phys Chem Solids 110:394–40010.1016/j.jpcs.2017.05.033 ↗
31. Shifu C, Gengyu C (2005) Photocatalytic degradation of organophosphorus pesticides using floating photocatalyst TiO2·SiO2/beads by sunlight. Sol Energy 79(1):1–910.1016/j.solener.2004.10.006 ↗
32. Tian CS, Liu YT, Sheng WL, Wang GQ, Jiang H, Xiong CR (2016) Preparation of TiO2 nanofibers templated with mesoporous SiO2 spheres and photocatalytic synthesis of ammonia. J Mol Catal A-Chem 30:566–574
33. Wang YG, Zhang XG (2004) Preparation and electrochemical capacitance of RuO /TiO nanotubes composites. Electrochim Acta 49(12):1957–1962
34. Wang Z, Liu J, Chen W (2012) Plasmonic Ag/AgBr nanohybrid: synergistic effect of SPR with photographic sensitivity for enhanced photocatalytic activity and stability. Dalton Trans 41(16):4866–487010.1039/c2dt12089e ↗
35. Wang S, Hai X, Ding X, Chang K, Xiang Y, Meng X, Yang Z, Chen H, Ye J (2017) Light-switchable oxygen vacancies in ultrafine Bi5O7 Br nanotubes for boosting solar-driven nitrogen fixation in pure water. Adv Mater 29(31):170177410.1002/adma.201701774 ↗
36. Wang Y, Wang C, Zou MG, Wang DX, Li QY, Guo WB (2018) Fabrication and photocatalytic properties of CuO/SiO2 heterogeneous hollow cubes. Ferroelectrics. 522:69–7410.1080/00150193.2018.1422665 ↗
37. Williams G, Seger B, Kamat PV (2008) TiO2-graphene nanocomposites. UV-assisted photocatalytic reduction of graphene oxide. ACS Nano 2(7):1487–149110.1021/nn800251f ↗
38. Wu M, Li L, Xue YC, Xu G, Tang L, Liu N, Huang WY (2018) Fabrication of ternary GO/g-C3N4/MoS2 flower-like heterojunctions with enhanced photocatalytic activity for water remediation. Appl Catal B Environ 228:103–11210.1016/j.apcatb.2018.01.063 ↗
39. Xu B, Maimaiti H, Wang SX, Awati A, Wang Y, Zhang J, Chen T (2019) Preparation of coal-based graphene oxide/SiO2 nanosheet and loading ZnO nanorod for photocatalytic Fenton-like reaction. Appl Surf Sci 498:14383510.1016/j.apsusc.2019.143835 ↗
40. Xue X, Chen R, Yan C, Zhao P, Hu Y, Zhang W, Yang S, Jin Z (2018) Review on photocatalytic and electrocatalytic artificial nitrogen fixation for ammonia synthesis at mild conditions: advances, challenges and perspectives. Nano Res 12:1229–124910.1007/s12274-018-2268-5 ↗
41. Ye L, Han C, Ma Z, Leng Y, Li J, Ji X, Bi D, Xie H, Huang Z (2017) Ni2P loading on Cd0.5Zn0.5S solid solution for exceptional photocatalytic nitrogen fixation under visible light. Chem Engineer J 307:311–31810.1016/j.cej.2016.08.102 ↗
42. Yiokari CG, Pitselis GE, Polydoros DG, Katsaounis AD, Vayenas CG (2000) High-pressure electrochemical promotion of ammonia synthesis over an industrial Iron catalyst. J Phys Chem A 104(46):10600–1060210.1021/jp002236v ↗
43. Yong-gang W, Xiao-gang Z (2004) Preparation and electrochemical capacitance of RuO2/TiO2 nanotubes composites. Electrochim Acta 49(12):1957–196210.1016/j.electacta.2003.12.023 ↗
44. Zaikovskii V, Nagabhushana K, Kriventsov V, Loponov K, Cherepanova S, Kvon R, Bönnemann H, Kochubey D, Savinova E (2006) Synthesis and structural characterization of se-modified carbon-supported Ru nanoparticles for the oxygen reduction reaction. J Phys Chem B 110:6881–689010.1021/jp056715b ↗
45. Zhang N, Jalil A, Wu D, Chen S, Liu Y, Gao C, Ye W, Qi Z, Ju H, Wang C, Wu X, Song L, Zhu J, Xiong Y (2018) Refining defect states in W18O49 by Mo doping: a strategy for tuning N2 activation towards solar-driven nitrogen fixation. J Am Chem Soc 140(30):9434–944310.1021/jacs.8b02076 ↗
46. Zhou W, Zhu B, Li Q, Ma T, Hu S, Griffy-Brown C (2010) CO2 emissions and mitigation potential in China’s ammonia industry. Energy Policy 38(7):3701–370910.1016/j.enpol.2010.02.048 ↗