Hydrothermally grown nano-manganese oxide on clinoptilolite for low-temperature propane-selective catalytic reduction of NOx
Source abstract
Abstract
A novel nano-size MnxOy/clinoptilolite catalyst of high activity for propane-SCR reaction of NOx at low temperatures has been synthesized by a hydrothermal method in a temperature range of 80–180 °C. The optimum synthesis temperature resulting in maximum NOx conversion was 150 °C. An optimum manganese oxide loading of 0.2 wt.% results in the best catalytic behavior (71% NOx conversion). All catalysts exhibited an optimal propane-SCR reaction temperature of 200 °C. The optimum catalyst produces no detectable CO (GHSV 27,000 h) at 200 °C. Manganese in the optimum catalyst exists as Mn2+ (37.8%), Mn3+ (14.2%), and Mn4+ (48%).
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Research context
OpenAlex topics: Catalytic Processes in Materials Science · Catalysis and Oxidation Reactions · Transition Metal Oxide Nanomaterials
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References (42)
Show source-provided references
1. Bentrup U, Brückner A, Richter M, Fricke R (2001) NOx adsorption on MnO2/NaY composite: an in situ FTIR and EPR study. Appl Catal B Environ 32:229–241. https://doi.org/10.1016/S0926-3373(01)00142-410.1016/S0926-3373(01)00142-4 ↗
2. Čapek L, Dědeček J, Wichterlová B (2004) Co-beta zeolite highly active in propane–SCR-NOx in the presence of water vapor: effect of zeolite preparation and Al distribution in the framework. J Catal 227:352–366. https://doi.org/10.1016/j.jcat.2004.08.00110.1016/j.jcat.2004.08.001 ↗
3. Carreon MA, Guliants VV, Yuan L, Hughett AR, Dozier A, Seisenbaeva GA, Kessler VG (2006) Mesoporous nanocrystalline mixed metal oxides from heterometallic alkoxide precursors: cobalt–nickel oxide spinels for propane oxidation. Eur J Inorg Chem 2006:4983–4988. https://doi.org/10.1002/ejic.20060074710.1002/ejic.200600747 ↗
4. Centi G, Arena GE (2003) NO reduction by C3H6 and O2 over supported noble metals: part I. Role of the support on the nature of NOx adspecies and their relationship with the catalytic behaviour. J Mol Catal A Chem 204-205:663–671. https://doi.org/10.1016/S1381-1169(03)00350-910.1016/S1381-1169(03)00350-9 ↗
5. Ettireddy PR, Ettireddy N, Mamedov S, Boolchand P, Smirniotis PG (2007) Surface characterization studies of TiO2 supported manganese oxide catalysts for low temperature SCR of NO with NH3. Appl Catal B Environ 76:123–134. https://doi.org/10.1016/j.apcatb.2007.05.01010.1016/j.apcatb.2007.05.010 ↗
6. Falamaki C, Afarani MS, Aghaie A (2006) In situ crystallization of highly oriented Silicalite films on porous zircon supports. J Am Ceram Soc 89:408–414. https://doi.org/10.1111/j.1551-2916.2005.00711.x10.1111/j.1551-2916.2005.00711.x ↗
7. Farshadi M, Falamaki C (2018) Ethylbenzene disproportionation and p-xylene selectivity enhancement in xylene isomerization using high crystallinity desilicated H-ZSM-5. Chin J Chem Eng 26:116–126. https://doi.org/10.1016/j.cjche.2017.03.02310.1016/j.cjche.2017.03.023 ↗
8. Fierro G, Moretti G, Ferraris G, Andreozzi GB (2011) A Mössbauer and structural investigation of Fe-ZSM-5 catalysts: influence of Fe oxide nanoparticles size on the catalytic behaviour for the NO-SCR by C3H8. Appl Catal B Environ 102:215–223. https://doi.org/10.1016/j.apcatb.2010.12.00110.1016/j.apcatb.2010.12.001 ↗
9. Gao R et al (2013) Morphology-dependent properties of MNOx/ZrO2–CeO2 nanostructures for the selective catalytic reduction of NO with NH3. J Phys Chem C 117:10502–10511. https://doi.org/10.1021/jp400984z10.1021/jp400984z ↗
10. Ghasemian N, Falamaki C, Kalbasi M (2014a) Clinoptilolite zeolite as a potential catalyst for propane-SCR-NOx: performance investigation and kinetic analysis. Chem Eng J 236:464–470. https://doi.org/10.1016/j.cej.2013.10.06110.1016/j.cej.2013.10.061 ↗
11. Ghasemian N, Falamaki C, Kalbasi M, Khosravi M (2014b) Enhancement of the catalytic performance of H-clinoptilolite in propane–SCR–NOx process through controlled dealumination. Chem Eng J 252:112–119. https://doi.org/10.1016/j.cej.2014.04.03910.1016/j.cej.2014.04.039 ↗
12. Guliants VV, Carreon MA (2005) Vanadium-phosphorus-oxides: from fundamentals of n-butane oxidation to synthesis of new phases. In: Spivey JJ (ed) Catalysis, vol 18. Royal Society of Chemistry, Cambridge, pp 1–45. https://doi.org/10.1039/9781847553300-0000110.1039/9781847553300-00001 ↗
13. Kim YG, Kim YC, Hong SB, Kim MH, Kim YP, Uh YS (1999) Selective reduction of nitric oxide by methane on cobalt-ion-exchanged synthetic clinoptilolite zeolite in oxygen-rich atmosphere. Catal Lett 57:179–185. https://doi.org/10.1023/a:101903262367410.1023/a:1019032623674 ↗
14. Ko JH et al (2012) Low temperature selective catalytic reduction of NO with NH3 over Mn supported on Ce0.65Zr0.35O2 prepared by supercritical method: effect of Mn precursors on NO reduction. Catal Today 185:290–295. https://doi.org/10.1016/j.cattod.2011.08.00710.1016/j.cattod.2011.08.007 ↗
15. Krivoruchenko DS, Telegina NS, Bokarev DA, Stakheev AY (2015) Mn–Ce/beta “bifunctional” catalyst for the selective catalytic reduction of nitrogen oxides with ammonia. Kinet Catal 56:741–746. https://doi.org/10.1134/s002315841506005110.1134/s0023158415060051 ↗
16. L. S, E. J, R. GM (2008) The effect of Si/Al ratio of ZSM-5 zeolite on its morphology, acidity and crystal size. Cryst Res Technol 43:1300–1306. https://doi.org/10.1002/crat.20080014910.1002/crat.200800149 ↗
17. Li Z, Flytzani-Stephanopoulos M (1997) Selective catalytic reduction of nitric oxide by methane over cerium and silver ion-exchanged ZSM-5 zeolites. Appl Catal A Gen 165:15–34. https://doi.org/10.1016/S0926-860X(97)00187-710.1016/S0926-860X(97)00187-7 ↗
18. Li J, Chen J, Ke R, Luo C, Hao J (2007a) Effects of precursors on the surface Mn species and the activities for NO reduction over MNOx/TiO2 catalysts. Catal Commun 8:1896–1900. https://doi.org/10.1016/j.catcom.2007.03.00710.1016/j.catcom.2007.03.007 ↗
19. Li L, Zhang F, Guan N, Richter M, Fricke R (2007b) Selective catalytic reduction of NO by propane in excess oxygen over IrCu-ZSM-5 catalyst. Catal Commun 8:583–588. https://doi.org/10.1016/j.catcom.2006.08.01310.1016/j.catcom.2006.08.013 ↗
20. Lin Q, Li J, Ma L, Hao J (2010) Selective catalytic reduction of NO with NH3 over Mn–Fe/USY under lean burn conditions. Catal Today 151:251–256. https://doi.org/10.1016/j.cattod.2010.01.02610.1016/j.cattod.2010.01.026 ↗
21. Liu Z, Ihl Woo S (2006) Recent Advances in Catalytic DeNOX. Sci Technol Catal Rev 48:43–89. https://doi.org/10.1080/0161494050043989110.1080/01614940500439891 ↗
22. Liu C, Shi J-W, Gao C, Niu C (2016) Manganese oxide-based catalysts for low-temperature selective catalytic reduction of NOx with NH3: a review. Appl Catal A Gen 522:54–69. https://doi.org/10.1016/j.apcata.2016.04.02310.1016/j.apcata.2016.04.023 ↗
23. Lu X, Song C, Chang C-C, Teng Y, Tong Z, Tang X (2014) Manganese oxides supported on TiO2–graphene nanocomposite catalysts for selective catalytic reduction of NOx with NH3 at low temperature. Ind Eng Chem Res 53:11601–11610. https://doi.org/10.1021/ie501696910.1021/ie5016969 ↗
24. Mahmoudi R, Falamaki C (2016) Ni2+−ion-exchanged dealuminated clinoptilolite: a superior adsorbent for deep desulfurization. fuel 173:277–284. https://doi.org/10.1016/j.fuel.2016.01.04810.1016/j.fuel.2016.01.048 ↗
25. Moreno-Tost R et al (2004) Selective catalytic reduction of nitric oxide by ammonia over cu-exchanged Cuban natural zeolites. Appl Catal B Environ 50:279–288. https://doi.org/10.1016/j.apcatb.2004.01.01910.1016/j.apcatb.2004.01.019 ↗
26. Pan H, Guo Y, Bi HT (2015) NOx adsorption and reduction with C3H6 over Fe/zeolite catalysts: effect of catalyst support. Chem Eng J 280:66–73. https://doi.org/10.1016/j.cej.2015.05.09310.1016/j.cej.2015.05.093 ↗
27. Patel A, Shukla P, Rufford TE, Rudolph V, Zhu Z (2014) Selective catalytic reduction of NO with CO using different metal-oxides incorporated in MCM-41. Chem Eng J 255:437–444. https://doi.org/10.1016/j.cej.2014.06.03210.1016/j.cej.2014.06.032 ↗
28. Peña DA, Uphade BS, Smirniotis PG (2004) TiO2-supported metal oxide catalysts for low-temperature selective catalytic reduction of NO with NH3: I. Evaluation and characterization of first row transition metals. J Catal 221:421–431. https://doi.org/10.1016/j.jcat.2003.09.00310.1016/j.jcat.2003.09.003 ↗
29. Qi G, Yang RT, Chang R (2003) Low-temperature SCR of NO with NH3 over USY-supported manganese oxide-based catalysts. Catal Lett 87:67–71. https://doi.org/10.1023/a:102280932808710.1023/a:1022809328087 ↗
30. Richter M et al (2002) Selective catalytic reduction of nitric oxide by ammonia over egg-shell MNOx/NaY composite catalysts. J Catal 206:98–113. https://doi.org/10.1006/jcat.2001.346810.1006/jcat.2001.3468 ↗
31. Singoredjo L, Korver R, Kapteijn F, Moulijn J (1992) Alumina supported manganese oxides for the low-temperature selective catalytic reduction of nitric oxide with ammonia. Appl Catal B Environ 1:297–316. https://doi.org/10.1016/0926-3373(92)80055-510.1016/0926-3373(92)80055-5 ↗
32. Spasova I, Nikolov P, Mehandjiev D (2005) Adsorption of NO on alumina-supported oxides and oxide–hydroxides of manganese. J Colloid Interface Sci 290:343–349. https://doi.org/10.1016/j.jcis.2005.04.04310.1016/j.jcis.2005.04.043 ↗
33. Sreekanth PM, Smirniotis PG (2008) Selective Reduction of NO with CO Over Titania Supported Transition Metal Oxide Catalysts. Catal Lett 122:37–42. https://doi.org/10.1007/s10562-007-9365-510.1007/s10562-007-9365-5 ↗
34. Tian W, Yang H, Fan X, Zhang X (2011) Catalytic reduction of NOx with NH3 over different-shaped MnO2 at low temperature. J Hazard Mater 188:105–109. https://doi.org/10.1016/j.jhazmat.2011.01.07810.1016/j.jhazmat.2011.01.078 ↗
35. Wang L, Huang B, Su Y, Zhou G, Wang K, Luo H, Ye D (2012a) Manganese oxides supported on multi-walled carbon nanotubes for selective catalytic reduction of NO with NH3: catalytic activity and characterization. Chem Eng J 192:232–241. https://doi.org/10.1016/j.cej.2012.04.01210.1016/j.cej.2012.04.012 ↗
36. Wang Y, Ge C, Zhan L, Li C, Qiao W, Ling L (2012b) MNOx–CeO2/activated carbon honeycomb catalyst for selective catalytic reduction of NO with NH3 at low temperatures. Ind Eng Chem Res 51:11667–11673. https://doi.org/10.1021/ie300555f10.1021/ie300555f ↗
37. Wang X, Zheng Y, Xu Z, Wang X, Chen X (2013) Amorphous MnO2 supported on carbon nanotubes as a superior catalyst for low temperature NO reduction with NH3. RSC Adv 3:11539–11542. https://doi.org/10.1039/C3RA41512K10.1039/C3RA41512K ↗
38. Wu Z, Jiang B, Liu Y (2008) Effect of transition metals addition on the catalyst of manganese/titania for low-temperature selective catalytic reduction of nitric oxide with ammonia. Appl Catal B Environ 79:347–355. https://doi.org/10.1016/j.apcatb.2007.09.03910.1016/j.apcatb.2007.09.039 ↗
39. Xu H, Zhang Q, Qiu C, Lin T, Gong M, Chen Y (2012) Tungsten modified MNOx–CeO2/ZrO2 monolith catalysts for selective catalytic reduction of NOx with ammonia. Chem Eng Sci 76:120–128. https://doi.org/10.1016/j.ces.2012.04.01210.1016/j.ces.2012.04.012 ↗
40. Yao Y, Zhang S-L, Zhong Q, Liu X-X (2011) Low-temperature selective catalytic reduction of NO over manganese supported on TiO2 nanotubes. J Fuel Chem Technol 39:694–701. https://doi.org/10.1016/S1872-5813(11)60042-X10.1016/S1872-5813(11)60042-X ↗
41. Yu C, Dong L, Chen F, Liu X, Huang B (2017) Low-temperature SCR of NOx by NH3 over MNOx/SAPO-34 prepared by two different methods: a comparative study. Environ Technol 38:1030–1042. https://doi.org/10.1080/09593330.2016.121617010.1080/09593330.2016.1216170 ↗
42. Yue Y, Liu H, Yuan P, Yu C, Bao X (2015) One-pot synthesis of hierarchical FeZSM-5 zeolites from natural aluminosilicates for selective catalytic reduction of NO by NH3. Sci Rep 5:9270. https://doi.org/10.1038/srep09270 https://www.nature.com/articles/srep09270#supplementary-information10.1038/srep09270 ↗