journal article·2015-12

Temperature stability of AgCu nanoparticles

Jiří Sopoušek, Ondřej Zobač, Vít Vykoukal, Jiří Buršík, Pavla Roupcová, Pavel Brož, Jiří Pinkas, Jan Vřešťál

Journal of Nanoparticle Research· Volume 17· Issue 12
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Abstract

The colloidal solutions of the Ag–Cu nanoparticles (NPs, 10–32 nm) were prepared by solvothermal reactions. The samples of dried AgCu NPs and the resulting microstructures after heat treatment in air were investigated by various methods including electron microscopy (TEM, SEM) and high-temperature X-ray powder diffraction (HTXRD). The AgCu randomly mixed, Cu-rich, and Ag-rich face centred cubic crystal lattices were detected during the experiments. The temperature induced sintering was observed experimentally by HTXRD at 250 °C. The phase transformations at high temperatures were monitored by differential scanning calorimetry. The formation of the Ag-rich grains during heating in air and evolution of copper oxide microstructure were detected.
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Research context

OpenAlex topics: nanoparticles nucleation surface interactions · Advanced Thermodynamics and Statistical Mechanics · Chemical and Physical Properties of Materials

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