journal article·2013-03

Decoration of cesium iodide nano particles on patterned carbon nanotube emitter arrays to improve their field emission

Monika Shahi, S. Gautam, P. V. Shah, J. S. Rawat, P. K. Chaudhury, Harsh, R. P. Tandon

Journal of Nanoparticle Research· Volume 15· Issue 3
Publisher page

Abstract

Arrays of aligned carbon nanotube (CNT) bundles were synthesized on the pre-patterned silicon substrate using thermal chemical vapor deposition. Silicon substrate was patterned with square arrays of 10 × 10 μm iron catalyst using photolithography, iron sputtering, and a lift-off process. After field emission (FE) measurement in diode configuration, CNT emitter arrays (CEAs) were decorated with cesium iodide (CsI) nano particles (NPs) using thermal evaporation with substrate heating at 300 °C. FE of pristine CEAs and CsI NPs decorated CEAs were carried out under same vacuum condition and constant inter-electrode separation. Pristine CEAs and CsI NPs decorated CEAs were characterized using scanning electron microscope, transmission electron microscope, energy-dispersive X-ray spectroscopy, X-ray diffraction, and Raman characterization. From FE comparison plots, it was observed that CsI NPs decoration on the CEAs had significantly lowered the turn-on electric field from 3.00 to 2.13 V/μm. A remarkable improvement of more than 50 % in the current density, from 11.02 to 17.33 mA/cm2, was also observed at a constant applied electric field of 5 V/μm.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Carbon Nanotubes in Composites · Nanopore and Nanochannel Transport Studies · Ion-surface interactions and analysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (18)

Show source-provided references
1. Chen Y, Jiang H, Li D, Song H, Li Z, Sun X, Miao G, Zhao H (2011) Improved field emission performance of carbon nanotube by introducing copper metallic particles. Nanoscale Res Lett C7–537 6(1):1–8
2. Fairchild SB, Back TC, Murray PT, Cahay MM, Shiffler DA (2011) Low work function CsI coatings for enhanced field emission properties. J Vac Sci Technol A 29(3):03140210.1116/1.3581058 ↗
3. Huang ZP, Tu Y, Carnahan DL, Ren ZF (2004) In: Nalwa HS (ed) Encyclopedia of nanoscience and nanotechnology, vol 3. American Scientific Publisher, pp 401–416
4. Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354(6348):56–5810.1038/354056a0 ↗
5. Jihua Z, Chuanren Y, Yongjin W, Tao F, Weidong Y, Jun J, Xi W, Xianghuai L (2006) Improvement of the field emission of carbon nanotubes by hafnium coating and annealing. Nanotechnology 17(1):25710.1088/0957-4484/17/1/043 ↗
6. Jin F, Liu Y, Day CM, Little SA (2007) Enhanced electron emission from functionalized carbon nanotubes with a barium strontium oxide coating produced by magnetron sputtering. Carbon 45(3):587–59310.1016/j.carbon.2006.10.014 ↗
7. Khazaei M, Kawazoe Y (2007) Effects of Cs treatment on field emission properties of capped carbon nanotubes. Surf Sci 601(6):1501–150610.1016/j.susc.2007.01.009 ↗
8. Kumari M, Gautam S, Kumar P, Rawat JS, Pal S, Khaneja M, Kumar P, Kumar A, Aggrawal AK, Chaudhury PK, Harsh (2009) Analysis of work-function of CNTs using active device area in diode configuration. Proceedings of the XV international workshop on the physics of semiconductor devices, vol 2. p 963–966
9. Kumari M, Gautam S, Shah PV, Pal S, Ojha US, Kumar A, Naik AA, Rawat JS, Chaudhury PK, Harsh, Tandon RP (2012) Improving the field emission of carbon nanotubes by lanthanum-hexaboride nano-particles decoration. Appl Phys Lett 101(12):12311610.1063/1.4754110 ↗
10. Saito R, Dresselhaus G, Dresselhaus MS (1998) Physical properties of carbon nanotubes. Imperial College Press, London10.1142/p080 ↗
11. Shiffler D (2008) Materials characteristics and surface morphology of a cesium iodide coated carbon velvet cathode. J Appl Phys 103(1):01330210.1063/1.2821152 ↗
12. Shiffler D, LaCour M, Golby K, Sena M, Mithcell M, Haworth M, Hendricks K, Spencer T (2001) Comparison of velvet- and cesium iodide-coated carbon fiber cathodes. IEEE Trans Plasma Sci 29(3):445–45110.1109/27.928942 ↗
13. Teo KBK, Minoux E, Hudanski L, Peauger F, Schnell JP, Gangloff L, Legagneux P, Dieumegard D, Amaratunga GAJ, Milne WI (2005) Microwave devices: carbon nanotubes as cold cathodes. Nature 437(7061):96810.1038/437968a ↗
14. Thostenson ET, Ren Z, Chou TW (2001) Advances in the science and technology of carbon nanotubes and their composites: a review. Compos Sci Technol 61(13):1899–191210.1016/S0266-3538(01)00094-X ↗
15. Verma P, Gautam S, Kumar P, Chaturvedi P, Rawat JS, Pal S, Chaubey R, Harsh, Vyas HP, Bhatnagar PK (2007) Carbon nanotube tip melting with vacuum breakdown in cold cathode. J Vac Sci Technol B 25(5):1584–158710.1116/1.2770744 ↗
16. Vlahos V, Booske JH, Morgan D (2007) Ab initio study of the effects of thin CsI coatings on the work function of graphite cathodes. Appl Phys Lett 91(14):14410210.1063/1.2794762 ↗
17. Wadhawan A, Stallcup II RE, Perez JM (2001) Effects of Cs deposition on the field-emission properties of single-walled carbon-nanotube bundles. Appl Phys Lett 78(1):108–11010.1063/1.1338493 ↗
18. Wei W, Kaili J, Yang W, Peng L, Kai L, Lina Z, Qunqing L, Shoushan F (2006) LaB6 tip-modified multiwalled carbon nanotube as high quality field emission electron source. Appl Phys Lett 89(20):20311210.1063/1.2388862 ↗