journal article·2020-07

Experimental investigation on stability and thermal conductivity of dodecanethiol-coated copper nanofluids

Lu Zhou, Yifan Zhao, Honghe Ma

Journal of Nanoparticle Research· Volume 22· Issue 7
Publisher page

Abstract

Nanofluids were prepared by dispersing dodecanethiol-coated copper nanoparticles (~ 50 nm average diameter) in toluene. The stability and thermal conductivity of the nanofluids were investigated for various particle volume concentrations (0.09–1.5 vol%) and temperatures (293–333 K). The amount of dodecanethiol surfactant coated on the nanoparticle surface was determined by thermogravimetric analysis (TGA), and the chemical structure of adsorbed surfactant molecules was characterized by Fourier transform infrared spectroscopy (FT-IR). UV-vis absorbance analysis of the nanofluid was undertaken to determine the optimum ultrasonic vibration time for stability enhancement. The modeling study generated a new semi-practical correlation as a function of particle volume concentration and temperature for an existing Brownian motion–based thermal conductivity model, which demonstrated good compatibility with the present experimental measurements compared with other models.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Nanofluid Flow and Heat Transfer · Rheology and Fluid Dynamics Studies · Fluid Dynamics and Thin Films

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (43)

Show source-provided references
1. Agarwal R, Verma K, Agrawal NK, Singh R (2017) Sensitivity of thermal conductivity for Al2O3 nanofluids. Exp Thermal Fluid Sci 80:19–2610.1016/j.expthermflusci.2016.08.007 ↗
2. Anjani PN, Lior S, Israel F, Ilana P, Aharon G, Yosef Y (2018) Surfactant effect on the thermal and electrical behaviors of sonochemically synthesized Fe and Fe-PVP nanofluids and insight into the magnetism of their in situ oxidized α-Fe2O3 analogues. J Phys Chem C 122(36):20755–2076210.1021/acs.jpcc.8b05433 ↗
3. Asadi A, Asadi M, Siahmargoi M, Asadi T, Andarati MG (2017) The effect of surfactant and sonication time on the stability and thermal conductivity of water-based nanofluid containing Mg(OH)2 nanoparticles: an experimental investigation. Int J Heat Mass Transf 108:191–19810.1016/j.ijheatmasstransfer.2016.12.022 ↗
4. Ahmad SHA, Saidur R, Mahbubul IM, Al-Sulaiman A (2017) Optical properties of various nanofluids used in solar collector: a review. Renew Sust Energ Rev 73:1014–103010.1016/j.rser.2017.01.173 ↗
5. Bhanushali S, Jason NN, Ghosh P, Ganesh A, Simon GP, Cheng WL (2017) Enhanced thermal conductivity of copper nanofluids: the effect of filler geometry. ACS Appl Mater Interfaces 9(22):18925–1893510.1021/acsami.7b03339 ↗
6. Bhattad A, Sarkar J, Ghosh P (2018) Improving the performance of refrigeration systems by using nanofluids: a comprehensive review. Renew Sust Energ Rev 82(3):3656–366910.1016/j.rser.2017.10.097 ↗
7. Das SK, Putra N, Thiesen P, Roetzel W (2003) Temperature dependence of thermal conductivity enhancement for nanofluids. J Heat Transf 125(4):567–57410.1115/1.1571080 ↗
8. Dong TY, Wu HH, Lin MC (2006) Superlattice of octanethiol-protected copper nanoparticles. Langmuir 22(16):6754–675610.1021/la053438r ↗
9. Eastman JA, Choi SUS, Li S, Yu W, Thompson LJ (2001) Anomalously increased effective thermal conductivities of ethylene glycol-based nanofluids containing copper nanoparticles. Appl Phys Lett 78(6):718–72010.1063/1.1341218 ↗
10. E XTF, Zhang Y, Zou JJ, Wang L, Zhang XW (2014) Oleylamine-protected metal (Pt, Pd) nanoparticles for pseudohomogeneous catalytic cracking of JP-10 jet fuel. Ind Eng Chem Res 53(31):12312–1231810.1021/ie502311x ↗
11. Ghodselahi T, Vesaghi MA, Shafiekhani A, Baghizadeh A, Lameii M (2008) XPS study of the Cu@Cu2O core-shell nanoparticles. Appl Surf Sci 255(5):2730–273410.1016/j.apsusc.2008.08.110 ↗
12. Gomez-Villarejo R, Navas J, Martin EI, Sanchez-Coronilla A, Aguilar T, Gallardo JJ, Santos DDL, Alcantara R, Fernandez-Lorenzo C, Martin-Calleja J (2017) Preparation of Au nanoparticles in a non-polar medium: obtaining high-efficiency nanofluids for concentrating solar power. An experimental and theoretical perspective. J Mater Chem A 5(24):12483–1249710.1039/C7TA00986K ↗
13. Hamilton RL, Crosser OK (1962) Thermal conductivity of heterogeneous two-component systems. Ind Eng Chem Fundam 1(3):187–19110.1021/i160003a005 ↗
14. Jang SP, Choi SUS (2004) Role of Brownian motion in the enhanced thermal conductivity of nanofluids. Appl Phys Lett 84(21):4316–431810.1063/1.1756684 ↗
15. Jiang HF, Xu QH, Huang C, Shi L (2015) Effect of temperature on the effective thermal conductivity of n-tetradecane-based nanofluids containing copper nanoparticles. Particuology 22:95–9910.1016/j.partic.2014.10.010 ↗
16. Kathiravan R, Kumar R, Gupta A, Chandra R (2012) Preparation and pool boiling characteristics of silver nanofluids over a flat plate heater. Heat Transfer Eng 33(2):69–7810.1080/01457632.2011.589306 ↗
17. Kole M, Dey TK (2013) Enhanced thermophysical properties of copper nanoparticles dispersed in gear oil. Appl Therm Eng 56(1–2):45–5310.1016/j.applthermaleng.2013.03.022 ↗
18. Koo J, Kleinstreuer C (2004) A new thermal conductivity model for nanofluids. J Nanopart Res 6(6):577–58810.1007/s11051-004-3170-5 ↗
19. Kumar A, Thakre GD, Arya PK, Jain AK (2017) Influence of operating parameters on the tribological performance of oleic acid-functionalized Cu nanofluids. Ind Eng Chem Res 56(13):3527–354110.1021/acs.iecr.6b04375 ↗
20. Kumar SA, Meenakshi KS, Narashimhan BRV, Srikanth S, Arthanareeswaran G (2009) Synthesis and characterization of copper nanofluid by a novel one-step method. Mater Chem Phys 113(1):57–6210.1016/j.matchemphys.2008.07.027 ↗
21. Liu LN, Li WP, Xiong ZS, Xia D, Yang CW, Wang W, Sun YF (2019) Synergistic effect of iron and copper oxides on the formation of persistent chlorinated aromatics in iron ore sintering based on in situ XPS analysis. J Hazard Mater 366:202–20910.1016/j.jhazmat.2018.11.105 ↗
22. Lenin R, Dadwal A, Joy P (2018) Thermal conductivity studies on magnetite nanofluids coated with short-chain and long-chain fatty acid surfactants. Bull Mater Sci 41(5):12010.1007/s12034-018-1638-7 ↗
23. Leong KC, Yang C, Murshed SMS (2006) A model for the thermal conductivity of nanofluids-the effect of interfacial layer. J Nanopart Res 8(2):245–25410.1007/s11051-005-9018-9 ↗
24. Li D, Xie WJ, Fang WJ (2011) Preparation and properties of copper-oil-based nanofluids. Nanoscale Res Lett 6(1):37310.1186/1556-276X-6-373 ↗
25. Li D, Fang WJ, Zhang YY, Wang XY, Meng G, Qin XM (2017) Stability and thermal conductivity enhancement of silver nanofluids with gemini surfactants. Ind Eng Chem Res 56(43):12369–1237510.1021/acs.iecr.7b03347 ↗
26. Li YJ, Zhou JE, Tung S, Schneider E, Xi SQ (2009) A review on development of nanofluid preparation and characterization. Powder Technol 196(2):89–10110.1016/j.powtec.2009.07.025 ↗
27. Manasrah AD, Laoui T, Zaidi SJ, Atieh MA (2017) Effect of PEG functionalized carbon nanotubes on the enhancement of thermal and physical properties of nanofluids. Exp Thermal Fluid Sci 84:231–24110.1016/j.expthermflusci.2017.02.018 ↗
28. Patel HE, Das SK, Sundararajan T, Nair AS, George B, Pradeep T (2003) Thermal conductivities of naked and monolayer protected metal nanoparticle based nanofluids: manifestation of anomalous enhancement and chemical effects. Appl Phys Lett 83(14):2931–293310.1063/1.1602578 ↗
29. Peng H, Ding GL, Hu HT (2011) Effect of surfactant additives on nucleate pool boiling heat transfer of refrigerant-based nanofluid. Exp Thermal Fluid Sci 35(6):960–97010.1016/j.expthermflusci.2011.01.016 ↗
30. Prasher R, Bhattacharya P, Phelan PE (2006) Brownian-motion-based convective-conductive model for the effective thermal conductivity of nanofluids. J Heat Transf 128(6):588–59510.1115/1.2188509 ↗
31. Robertis ED, Cosme EHH, Neves RS, Kuznetsov AY, Campos APC, Landi SM, Achete CA (2012) Application of the modulated temperature differential scanning calorimetry technique for the determination of the specific heat of copper nanofluids. Appl Therm Eng 41:10–1710.1016/j.applthermaleng.2012.01.003 ↗
32. Sahai A, Goswami N, Kaushik SD, Tripathi S (2016) Cu/Cu2O/CuO nanoparticles: novel synthesis by exploding wire technique and extensive characterization. Appl Surf Sci 390:974–98310.1016/j.apsusc.2016.09.005 ↗
33. Stocker KM, Neidhart SM, Gezelter JD (2016) Interfacial thermal conductance of thiolate-protected gold nanospheres. J Appl Phys 119:02510610.1063/1.4939956 ↗
34. Vajjha RS, Das DK (2009) Experimental determination of thermal conductivity of three nanofluids and development of new correlations. Int J Heat Mass Transf 52(21–22):4675–468210.1016/j.ijheatmasstransfer.2009.06.027 ↗
35. Vajjha RS, Das DK, Kulkarni DP (2010) Development of new correlations for convective heat transfer and friction factor in turbulent regime for nanofluids. Int J Heat Mass Transf 53(21–22):4607–461810.1016/j.ijheatmasstransfer.2010.06.032 ↗
36. Wang BX, Zhou LP, Peng XF (2003) A fractal model for predicting the effective thermal conductivity of liquid with suspension of nanoparticles. Int J Heat Mass Transf 46(14):2665–267210.1016/S0017-9310(03)00016-4 ↗
37. Wang XJ, Zhu DS, Yang S (2009) Investigation of pH and SDBS on enhancement of thermal conductivity in nanofluids. Chem Phys Lett 470(1–3):107–11110.1016/j.cplett.2009.01.035 ↗
38. Wei XH, Wang LQ (2010) Synthesis and thermal conductivity of microfluidic copper nanofluids. Particuology 8(3):262–27110.1016/j.partic.2010.03.001 ↗
39. Wan ZH, Deng J, Li B, Xu YX, Wang XW, Tang Y (2015) Thermal performance of a miniature loop heat pipe using water–copper nanofluid. Appl Therm Eng 78:712–71910.1016/j.applthermaleng.2014.11.010 ↗
40. Xie HQ, Chen LF (2011) Review on the preparation and thermal performances of carbon nanotube contained nanofluids. J Chem Eng Data 56(4):1030–104110.1021/je101026j ↗
41. Xuan YM, Li Q (2000) Heat transfer enhancement of nanofluids. Int J Heat Fluid Flow 21(1):58–6410.1016/S0142-727X(99)00067-3 ↗
42. Yu F, Chen YY, Liang XB, Xu JL, Lee C, Liang Q, Tao P, Deng T (2017) Dispersion stability of thermal nanofluids. Prog Nat Sci: Materials International 27(5):531–54210.1016/j.pnsc.2017.08.010 ↗
43. Yu W, Choi SUS (2003) The role of interfacial layers in the enhanced thermal conductivity of nanofluids: a renovated Maxwell model. J Nanopart Res 5(1–2):167–17110.1023/A:1024438603801 ↗