Preparation of hybrid membranes by incorporating hydrophilic UiO-66 nanoparticles for high-performance pervaporation dehydration of aprotic solvents
Source abstract
Abstract
Hydrophilic UiO-66 crystals with superior water adsorption ability were synthesized and incorporated into the polyimide (PI) membrane for efficient aprotic solvent separation via pervaporation. The effect of the different UiO-66 addition in the pyromellitic dianhydride (PMDA)-2, 2-bis[4-(4-amlnophenoxy)phenyl]propane (BAPP)-based PI membrane on the membrane structure, thermal stability, surface hydrophilicity, solvent-resistant, and pervaporation performance was systematically studied. The UiO-66/PI hybrid membranes with small amount content (2 wt%) exhibited high hydrophilicity and excellent swelling resistance due to the superb dispersion benefiting from the excellent complexation of UiO-66 and PI chain. The effects of operational variables such as operating temperature and concentration of feed solution on the pervaporation separation performance of the hybrid membranes with different UiO-66 loadings were investigated. When the mass fraction of UiO-66 was 2 wt%, the hybrid membranes show the permeation flux of 109.7 and 57.1 g/(m2h) and separation factor of 34.1 and 133.9, respectively, for DMF/H2O and DMAc/H2O systems.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Membrane Separation and Gas Transport · Covalent Organic Framework Applications · Metal-Organic Frameworks: Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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