Synthesis and performances evaluation of the spindle-shaped calcium hydroxide nanomaterials for thermochemical energy storage
Source abstract
Abstract
Thermochemical energy storage is a promising alternation in heat recovery application and concentrated solar power plants. The present work focuses on the influence of morphology and porosity of Ca(OH)2 nanomaterials on their thermochemical energy storage performances. Firstly, the Ca(OH)2 nanoparticles with the morphologies of spindle and hexagonal structure were synthesized by the deposition-precipitation method, and their performances were evaluated by thermogravimetric analysis together with three kinds of commercial nanoparticles. The BET tests demonstrate that the self-made spindle-shaped Ca(OH)2 has the highest BET-specific surface area and pore volume among these five nanomaterials. Secondly, the thermochemical energy storage performance evaluation of these materials showed that the spindle-shaped Ca(OH)2 exhibited the best heat storage and output capacities (about 1300 kJ/kg), thus bringing a convenient route in production of Ca(OH)2 with higher energy storage density. Finally, after ten dehydration/hydration cycles, the conversions of spindle-shaped Ca(OH)2 remained at above 70%.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Adsorption and Cooling Systems · Layered Double Hydroxides Synthesis and Applications · Phase Change Materials Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (46)
Show source-provided references
1. Afflerbach S, Kappes M, Gipperich A, Trettin R, Krumm W (2017) Semipermeable encapsulation of calcium hydroxide for thermochemical heat storage solutions. Sol Energy 148:1–1110.1016/j.solener.2017.03.074 ↗
2. Alavi MA, Morsali A (2010) Ultrasonic-assisted synthesis of ca(OH)2 and CaO nanostructures. J Exp Nanosci 5:93–10510.1080/17458080903305616 ↗
3. Ambrosi M, Dei L, Giorgi R, Chiara Neto A, Baglioni P (2001) Colloidal particles of ca(OH)2: properties and applications to restoration of frescoes. Langmuir 17:4251–425510.1021/la010269b ↗
4. Chandradass J, Kim H, Momade FWY (2014) Effect of different solvents in the synthesis of LaCoO3 nanopowders prepared by the co-precipitation method. Adv Powder Technol 25:1834–183810.1016/j.apt.2014.07.014 ↗
5. Chen X, Zhang Z, Qi C, Ling X, Peng H (2018) State of the art on the high-temperature thermochemical energy storage systems. Energy Convers Manag 177:792–81510.1016/j.enconman.2018.10.011 ↗
6. Chowdhury S, Saha P (2011) Adsorption thermodynamics and kinetics of malachite green onto ca(OH)2-treated fly ash. J Environ Eng 137:388–39710.1061/(ASCE)EE.1943-7870.0000334 ↗
7. Cot-Gores J, Castell A, Cabeza LF (2012) Thermochemical energy storage and conversion: A-state-of-the-art review of the experimental research under practical conditions. Renew Sust Energ Rev 16:5207–522410.1016/j.rser.2012.04.007 ↗
8. Criado YA, Alonso M, Abanades JC (2014) Kinetics of the CaO/ca(OH)2 hydration/dehydration reaction for thermochemical energy storage applications. Ind Eng Chem Res 53:12594–1260110.1021/ie404246p ↗
9. Dahmen U, Kim MG, Searcy AW (1987) Microstructural evolution during the decomposition of mg(OH)2. Ultramicroscopy 23:365–37010.1016/0304-3991(87)90247-6 ↗
10. Daud FDM, Vignesh K, Sreekantan S, Mohamed AR, Kang M, Kwak BS (2016) Ca(OH)2 nano-pods: investigation on the effect of solvent ratio on morphology and CO2 adsorption capacity. RSC Adv 6:36031–3603810.1039/C5RA27771J ↗
11. Fahim MA, Ford JD (1983) Energy storage using the BaO2-BaO reaction cycle. The Chemical Engineering Journal 27:21–2810.1016/0300-9467(83)80042-2 ↗
12. Fedders H, Höhlein B (1982) Operating a pilot plant circuit for energy transport with hydrogen-rich gas. Int J Hydrog Energy 7:793–80010.1016/0360-3199(82)90070-2 ↗
13. Herrmann U, Kearney D (2002) Survey of thermal energy storage for parabolic trough power plants. Journal of Solar Energy Engineering-transactions of The Asme 124:145–15210.1115/1.1467601 ↗
14. Huang C, Xu M, Huai X (2019) Experimental investigation on thermodynamic and kinetic of calcium hydroxide dehydration with hexagonal boron nitride doping for thermochemical energy storage. Chem Eng Sci 206:518–52610.1016/j.ces.2019.06.002 ↗
15. Kee SY, Munusamy Y, Ong KS (2018) Review of solar water heaters incorporating solid-liquid organic phase change materials as thermal storage. Appl Therm Eng 131:455–47110.1016/j.applthermaleng.2017.12.032 ↗
16. Khoza PB, Moloto MJ, Sikhwivhilu LM (2012) The effect of solvents, acetone, water, and ethanol, on the morphological and optical properties of ZnO nanoparticles prepared by microwave. J Nanotechnol 2012:1–610.1155/2012/195106 ↗
17. Kitamura A, Oniduka K, Tanaka K (1996) The hydration characteristics of magnesia. Refractories 48:1499–1506
18. Komabayashi T, Ahn C, Spears R, Qiang Z (2014) Comparison of particle morphology between commercial- and research-grade calcium hydroxide in endodontics. J Oral Sci 56:195–19910.2334/josnusd.56.195 ↗
19. Kugeler K, Niessen HF, Röth-Kamat M, Böcker D, Rüter B, Theis KA (1975) Transport of nuclear heat by means of chemical energy (nuclear long-distance energy). Nucl Eng Des 34:65–7210.1016/0029-5493(75)90156-9 ↗
20. Mamani V, Gutiérrez A, Ushak S (2018) Development of low-cost inorganic salt hydrate as a thermochemical energy storage material. Sol Energy Mater Sol Cells 176:346–35610.1016/j.solmat.2017.10.021 ↗
21. Mastronardo E, Bonaccorsi L, Kato Y, Piperopoulos E, Lanza M, Milone C (2016) Thermochemical performance of carbon nanotubes based hybrid materials for MgO/H2O/mg(OH)2 chemical heat pumps. Appl Energy 181:232–24310.1016/j.apenergy.2016.08.041 ↗
22. Mirghiasi Z, Bakhtiari F, Darezereshki E, Esmaeilzadeh E (2014) Preparation and characterization of CaO nanoparticles from ca(OH)2 by direct thermal decomposition method. J Ind Eng Chem 20:113–11710.1016/j.jiec.2013.04.018 ↗
23. Muroyama AP, Schrader AJ, Loutzenhiser PG (2015) Solar electricity via an air Brayton cycle with an integrated two-step thermochemical cycle for heat storage based on Co3O4/CoO redox reactions II: kinetic analyses. Sol Energy 122:409–41810.1016/j.solener.2015.08.038 ↗
24. Ogura H (1991) Experimental study on heat transfer enhancement of the solid reactant particle bed in a chemical heat pump using ca(OH)2/CaO reaction. Kagaku Kogaku Ronbunshu 17:916–92310.1252/kakoronbunshu.17.916 ↗
25. Ogura H, Miyazaki M, Matsuda H, Hasatani M, Yanadori M, Hiramatsu M (1992) Numerical analysis of heat transfer in particle-bed reactor with fins in chemical heat pump using ca(OH)2/CaO reaction. Kagaku Kōgaku Ronbunshū 18:669–67610.1252/kakoronbunshu.18.669 ↗
26. Pardo P, Anxionnaz-Minvielle Z, Rougé S, Cognet P, Cabassud M (2014a) Ca(OH)2/CaO reversible reaction in a fluidized bed reactor for thermochemical heat storage. Sol Energy 107:605–61610.1016/j.solener.2014.06.010 ↗
27. Pardo P, Deydier A, Anxionnaz-Minvielle Z, Rouge S, Cabassud M, Cognet P (2014b) A review on high temperature thermochemical heat energy storage. Renew Sust Energ Rev 32:591–61010.1016/j.rser.2013.12.014 ↗
28. Ranjha Q, Oztekin A (2017) Numerical analyses of three-dimensional fixed reaction bed for thermochemical energy storage. Renew Energy 111:825–83510.1016/j.renene.2017.04.062 ↗
29. Reiser A, Bogdanovic B, Schlichte K (2000) The application of mg-based metal-hydrides as heat energy storage systems. Int J Hydrog Energy 25:425–43010.1016/S0360-3199(99)00057-9 ↗
30. Rodrigueznavarro C, Suzuki A, Ruizagudo E (2013) Alcohol dispersions of calcium hydroxide nanoparticles for stone conservation. Langmuir 29:11457–1147010.1021/la4017728 ↗
31. Rougé S, Criado YA, Soriano O, Abanades JC (2017) Continuous CaO/ca(OH)2 fluidized bed reactor for energy storage: first experimental results and reactor model validation. Ind Eng Chem Res 5610.1021/acs.iecr.6b04105 ↗
32. Schaube F, Worner A, Tamme R (2011) High temperature thermochemical heat storage for concentrated solar power using gas–solid reactions. J Sol Energy Eng 133:1006–101210.1115/1.4004245 ↗
33. Schaube F, Koch L, Wörner A, Müller-Steinhagen H (2012) A thermodynamic and kinetic study of the de- and rehydration of ca(OH)2 at high H2O partial pressures for thermo-chemical heat storage. Thermochim Acta 538:9–2010.1016/j.tca.2012.03.003 ↗
34. Schaube F, Kohzer A, Schütz J, Wörner A, Müller-Steinhagen H (2013) De- and rehydration of ca(OH) 2 in a reactor with direct heat transfer for thermo-chemical heat storage. Part A: Experimental results Chem Eng Res Des 91:856–864
35. Schmidt M, Gutierrez A, Linder M (2017) Thermochemical energy storage with CaO/ca(OH)2–experimental investigation of the thermal capability at low vapor pressures in a lab scale reactor. Appl Energy 188:672–68110.1016/j.apenergy.2016.11.023 ↗
36. Shkatulov A, Ryu J, Kato Y, Aristov Y (2012) Composite material “mg(OH)2/vermiculite”: a promising new candidate for storage of middle temperature heat. Energy 44:1028–103410.1016/j.energy.2012.04.045 ↗
37. Taglieri G, Daniele V, Re GD, Volpe R (2015) A new and original method to produce ca(OH)2 nanoparticles by using an anion exchange resin. Adv Nanopart 4:17–2410.4236/anp.2015.42003 ↗
38. Thaker S, Oni AO, Kumar A, Thaker S (2017) Techno-economic evaluation of solar-based thermal energy storage systems. Energy Convers Manag 153:423–43410.1016/j.enconman.2017.10.004 ↗
39. Wang Y, Xia TD, Feng HX, Zhang H (2011) Stearic acid/polymethylmethacrylate composite as form-stable phase change materials for latent heat thermal energy storage. Renew Energy 36:1814–182010.1016/j.renene.2010.12.022 ↗
40. Xu M, Huai X, Cai J (2017) Agglomeration behavior of calcium hydroxide/calcium oxide as thermochemical heat storage material: a reactive molecular dynamics study. J Phys Chem C 121:3025–303310.1021/acs.jpcc.6b08615 ↗
41. Yan J, Zhao CY (2015) Thermodynamic and kinetic study of the dehydration process of CaO/ca(OH)2 thermochemical heat storage system with li doping. Chem Eng Sci 138:86–9210.1016/j.ces.2015.07.053 ↗
42. Yan J, Zhao CY (2016) Experimental study of CaO/ca(OH)2 in a fixed-bed reactor for thermochemical heat storage. Appl Energy 175:277–28410.1016/j.apenergy.2016.05.038 ↗
43. Zamengo M, Ryu J, Kato Y (2014) Thermochemical performance of magnesium hydroxide–expanded graphite pellets for chemical heat pump. Appl Therm Eng 64:339–34710.1016/j.applthermaleng.2013.12.036 ↗
44. Zamengo M, Ryu J, Kato Y (2015) Chemical heat storage of thermal energy from a nuclear reactor by using a magnesium hydroxide/expanded graphite composite material. Energy Procedia 71:293–30510.1016/j.egypro.2014.11.882 ↗
45. Zhang H, Wang H, Xun Z, Qiu YJ, Kai L, Rong C, Qiang L (2013) A review of waste heat recovery technologies towards molten slag in steel industry. Appl Energy 112:956–96610.1016/j.apenergy.2013.02.019 ↗
46. Zhu Y, Wu S, Wang X (2011) Nano CaO grain characteristics and growth model under calcination. Chem Eng J 175:512–51810.1016/j.cej.2011.09.084 ↗