journal article·2013-06Open access

Efficient sensitization of Ln3+-doped NaYF4 nanocrystals with organic ligands

N. Gauthier, O. Raccurt, D. Imbert, M. Mazzanti

Journal of Nanoparticle Research· Volume 15· Issue 6

Abstract

Ligand-capped lanthanide-doped fluoride nanocrystals have been prepared and fully characterized. Organic ligands can be used to promote efficient sensitization of lanthanide luminescence in the fluoride matrix up to a 330-fold enhancement in intensity, and to provide sizeable quantum yields of luminescence. The variation of luminescence efficiency in the capped nanocrystal series can be straightforwardly correlated to the energy of the measured ligand triplet states. The intense luminescence emission of most of the systems renders them very attractive for optical applications.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Inorganic Fluorides and Related Compounds · Lanthanide and Transition Metal Complexes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (48)

Show source-provided references
1. Andreiadis ES, Demadrille R, Imbert D, Pecaut J, Mazzanti M (2009) Remarkable tuning of the coordination and photophysical properties of lanthanide ions in a series of tetrazole-based complexes. Chem Eur J 15(37):9458–947610.1002/chem.200900912 ↗
2. Andreiadis ES, Imbert D, Pecaut J, Demadrille R, Mazzanti M (2012) Self-assembly of highly luminescent lanthanide complexes promoted by pyridine-tetrazolate ligands. Dalton Trans 41(4):1268–127710.1039/C1DT11627D ↗
3. Bae SW, Tan W, Hong J-I (2012) Fluorescent dye-doped silica nanoparticles: new tools for bioapplications. Chem Commun 48(17):2270–228210.1039/c2cc16306c ↗
4. Bednarkiewicz A, Mech A, Karbowiak M, Stręk W (2005) Spectral properties of Eu3+ doped NaGdF4 nanocrystals. J Lumin 114(3–4):247–25410.1016/j.jlumin.2005.01.005 ↗
5. Bender CM, Burlitch JM, Barber D, Pollock C (2000) Synthesis and fluorescence of neodymium-doped barium fluoride nanoparticles. Chem Mater 12(7):1969–197610.1021/cm9904741 ↗
6. Binnemans K (2009) Lanthanide-based luminescent hybrid materials. Chem Rev 109(9):4283–437410.1021/cr8003983 ↗
7. Bonacchi S, Genovese D, Juris R, Montalti M, Prodi L, Rampazzo E, Zaccheroni N (2011) Luminescent silica nanoparticles: extending the frontiers of brightness. Angew Chem Int Ed 50(18):4056–406610.1002/anie.201004996 ↗
8. Bouzigues C, Gacoin T, Alexandrou A (2011) Biological applications of rare-earth based nanoparticles. ACS Nano 5(11):8488–850510.1021/nn202378b ↗
9. Boyer J-C, van Veggel FCJM (2010) Absolute quantum yield measurements of colloidal NaYF4:Er3+, Yb3+ upconverting nanoparticles. Nanoscale 2(8):1417–141910.1039/c0nr00253d ↗
10. Bozoklu G, Marchal C, Pecaut J, Imbert D, Mazzanti M (2010) Structural and photophysical properties of trianionic nine-coordinated near-IR emitting 8-hydroxyquinoline-based complexes. Dalton Trans 39(38):9112–912210.1039/c0dt00225a ↗
11. Bunzli JCG (2010) Lanthanide luminescence for biomedical analyses and imaging. Chem Rev 110(5):2729–275510.1021/cr900362e ↗
12. Bunzli JCG, Piguet C (2005) Taking advantage of luminescent lanthanide ions. Chem Soc Rev 34(12):1048–107710.1039/b406082m ↗
13. Carlos LD, Ferreira RAS, Bermudez VD, Julian-Lopez B, Escribano P (2011) Progress on lanthanide-based organic-inorganic hybrid phosphors. Chem Soc Rev 40(2):536–54910.1039/C0CS00069H ↗
14. Charbonniere LJ, Mameri S, Flot D, Waltz F, Zandanel C, Ziessel RF (2007) A disymmetric terpyridine based ligand for the formation of luminescent di-aquo lanthanide complexes. Dalton Trans 22:2245–225310.1039/B700837F ↗
15. Charbonniere LJ, Rehspringer J-L, Ziessel R, Zimmermann Y (2008) Highly luminescent water-soluble lanthanide nanoparticles through surface coating sensitization. New J Chem 32(6):1055–105910.1039/b719700d ↗
16. Comby S, Bünzli GJ-C (2007) Handbook on the Physics and Chemistry of Rare Earths, vol 37. Handbook on the Physics and Chemistry of Rare Earths. elsevier, Amsterdam
17. Comby S, Imbert D, Vandevyver C, Bunzli JCG (2007) A novel strategy for the design of 8-hydroxyquinolinate-based lanthanide bioprobes that emit in the near infrared range. Chem Eur J 13(3):936–94410.1002/chem.200600964 ↗
18. Cross AM, May PS, van Veggel FCJM, Berry MT (2010) Dipicolinate sensitization of europium luminescence in dispersible 5%Eu:LaF3 nanoparticles. J Phys Chem C 114(35):14740–1474710.1021/jp103366j ↗
19. de Bettencourt-Dias A (2007) Lanthanide-based emitting materials in light-emitting diodes. Dalton Trans 22:2229–224110.1039/b702341c ↗
20. deMello JC, Wittmann HF, Friend RH (1997) An improved experimental determination of external photoluminescence quantum efficiency. Adv Mater 9(3):230–23210.1002/adma.19970090308 ↗
21. Eliseeva SV, Bunzli JCG (2010) Lanthanide luminescence for functional materials and bio-sciences. Chem Soc Rev 39(1):189–22710.1039/B905604C ↗
22. Gao L, Ge X, Chai Z, Xu G, Wang X, Wang C (2009) Shape-controlled synthesis of octahedral α-NaYF4 and its rare earth doped submicrometer particles in acetic acid. Nano Res 2(7):565–57410.1007/s12274-009-9056-1 ↗
23. Geissler D, Charbonniere LJ, Ziessel RF, Butlin NG, Lohmannsroben HG, Hildebrandt N (2010) Quantum dot biosensors for ultrasensitive multiplexed diagnostics. Angew Chem Int Ed 49(8):1396–140110.1002/anie.200906399 ↗
24. Ghosh P, Patra A (2008) Tuning of crystal phase and luminescence properties of Eu3+ doped sodium yttrium fluoride nanocrystals. J Phys Chem C 112(9):3223–323110.1021/jp7099114 ↗
25. Giraud M, Andreiadis ES, Fisyuk AS, Demadrille R, Pecaut J, Imbert D, Mazzanti M (2008) Efficient sensitization of lanthanide luminescence by tetrazole-based polydentate ligands. Inorg Chem 47(10):3952–395410.1021/ic8005663 ↗
26. Hauser CP, Thielemann DT, Adlung M, Wickleder C, Roesky PW, Weiss CK, Landfester K (2011) Luminescent polymeric dispersions and films based on oligonuclear lanthanide clusters. Macromol Chem Phys 212(3):286–29610.1002/macp.201000461 ↗
27. Hemmilä I, Laitala V (2005) Progress in lanthanides as luminescent probes. J Fluoresc 15(4):529–54210.1007/s10895-005-2826-6 ↗
28. Höppe HA (2009) Recent developments in the field of inorganic phosphors. Angew Chem Int Ed 48(20):3572–358210.1002/anie.200804005 ↗
29. Janssens S, Williams GVM, Clarke D (2011) Systematic study of sensitized LaF3:Eu3+ nanoparticles. J Appl Phys 109(2):023506–02350910.1063/1.3531994 ↗
30. Judd BR (1962) Optical absorption intensities of rare-earth ions. Phys Rev 127(3):750–761. doi: 10.1103/PhysRev.127.75010.1103/PhysRev.127.750 ↗
31. Kar A, Patra A (2012) Impacts of core-shell structures on properties of lanthanide-based nanocrystals: crystal phase, lattice strain, downconversion, upconversion and energy transfer. Nanoscale 4(12):3608–361910.1039/c2nr30389b ↗
32. Larson DR, Ow H, Vishwasrao HD, Heikal AA, Wiesner U, Webb WW (2008) Silica nanoparticle architecture determines radiative properties of encapsulated fluorophores. Chem Mater 20(8):2677–268410.1021/cm7026866 ↗
33. Li SW, Zhang X, Hou ZY, Cheng ZY, Ma PA, Lin J (2012) Enhanced emission of ultra-small-sized LaF3:RE3+(RE = Eu, Tb) nanoparticles through 1,2,4,5-benzenetetracarboxylic acid sensitization. Nanoscale 4(18):5619–562610.1039/c2nr31206a ↗
34. Liu G, Chen X (2007) Spectroscopic properties of lanthanides in nanomaterials. In: Gschneidner KA, Bunzli J-CG, Vitalij KP (eds) Handbook on the physics and chemistry of rare earths, vol 37. Elsevier, Amsterdam, pp 99–169
35. Mader HS, Kele P, Saleh SM, Wolfbeis OS (2010) Upconverting luminescent nanoparticles for use in bioconjugation and bioimaging. Curr Opin Chem Biol 14(5):582–59610.1016/j.cbpa.2010.08.014 ↗
36. Nonat A, Gateau C, Fries PH, Mazzanti M (2006) Lanthanide complexes of a picolinate ligand derived from 1,4,7-triazacyclononane with potential application in magnetic resonance imaging and time-resolved luminescence imaging. Chem Eur J 12(27):7133–715010.1002/chem.200501390 ↗
37. Ofelt GS (1962) Intensities of crystal spectra or rare-earth ions. J Chem Phys 37(3):511–52010.1063/1.1701366 ↗
38. Origin 7.5 (2008) OriginLab Corp, Northampton10.1016/S1365-6937(08)70246-6 ↗
39. Parker D (2000) Responsive lanthanides complexes. Coord Chem Rev 205:109–13010.1016/S0010-8545(00)00241-1 ↗
40. Schwarzenbach G (1957) Complexometric Titrations. Chapman & Hall, London
41. Shavaleev NM, Scopelliti R, Gumy F, Bunzli JCG (2009) Surprisingly bright near-infrared luminescence and short radiative lifetimes of ytterbium in hetero-binuclear Yb–Na chelates. Inorg Chem 48(16):7937–794610.1021/ic900888m ↗
42. Tallant DR, Seager CH, Simpson RL (2002) Energy transfer and relaxation in europium-activated Y2O3 after excitation by ultraviolet photons. J Appl Phys 91(7):4053–406410.1063/1.1452770 ↗
43. Vetrone F, Naccache R, Mahalingam V, Morgan CG, Capobianco JA (2009) The active-core/active-shell approach: a strategy to enhance the upconversion luminescence in lanthanide-doped nanoparticles. Adv Funct Mater 19(18):2924–292910.1002/adfm.200900234 ↗
44. Wang F, Han Y, Lim CS, Lu Y, Wang J, Xu J, Chen H, Zhang C, Hong M, Liu X (2010) Simultaneous phase and size control of upconversion nanocrystals through lanthanide doping. Nature 463(7284):1061–106510.1038/nature08777 ↗
45. Wong HT, Vetrone F, Naccache R, Chan HLW, Hao JH, Capobianco JA (2011) Water dispersible ultra-small multifunctional KGdF4:Tm3+, Yb3+ nanoparticles with near-infrared to near-infrared upconversion. J Mater Chem 21(41):16589–1659610.1039/c1jm12796a ↗
46. Wu J, Wang GL, Jin DY, Yuan JL, Guan YF, Piper J (2008) Luminescent europium nanoparticles with a wide excitation range from UV to visible light for biolabeling and time-gated luminescence bioimaging. Chem Commun 3:365–36710.1039/B715054G ↗
47. Zhang J, Shade CM, Chengelis DA, Petoud S (2007) A strategy to protect and sensitize near-infrared luminescent Nd3+ and Yb3+: organic tropolonate ligands for the sensitization of Ln3+-doped NaYF4 nanocrystals. J Am Chem Soc 129(48):14834–1483510.1021/ja074564f ↗
48. Zhao J, Lu Z, Yin Y, McRae C, Piper J, Dawes J, Jin D, Goldys EM (2013) Upconversion luminescence with tunable lifetime in NaYF4:Yb, Er nanocrystals: role of nanocrystal size. Nanoscale 5(3):944–95210.1039/C2NR32482B ↗