Highly efficient photocatalytic reduction of CO2 on amine-functionalized Ti-MCM-41 zeolite
Source abstract
Abstract
Efficient adsorption and utilization of carbon dioxide play an important role in mitigating the greenhouse effect and developing clean energy. Surface functionalization of photocatalyst is an efficient method to promote the adsorption of CO2 and convert it into hydrocarbon fuels. In this work, tetraethylenepentamine (TEPA) is used to functionalize Ti-MCM-41 molecular sieve photocatalyst to enhance the adsorption and activation of CO2. Ti-MCM-41 molecular sieve was modified without any precious metal additives. When the content of TEPA was 1%, the yield of CH4 was 232 ppm g−1 h−1. Furthermore, the results indicate that high impregnation amount of TEPA causes strong and higher adsorption of CO2 but inefficient for its conversion. This is probably due to the blockage of the channel when the impregnation amount of TEPA exceeds the threshold value, which hinders the further conversion of CO2 molecules. Functionalization Ti-MCM-41 zeolite photocatalyst with amino group is the prime reason for its excellent CO2 adsorption followed by activation capacity. In the future, this proposed composite might come up as a perspective photocatalyst in the field of photocatalysis for the purpose of environment remediation.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Carbon dioxide utilization in catalysis · Advanced Photocatalysis Techniques · Carbon Dioxide Capture Technologies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (28)
Show source-provided references
1. Caskey SR, Wong-Foy AG, Matzger AJ (2008) Dramatic tuning of carbon dioxide uptake via metal substitution in a coordination polymer with cylindrical pores. J Am Chem Soc 130:10870–10871. https://doi.org/10.1021/ja803609610.1021/ja8036096 ↗
2. Chen C, Yang ST, Ahn WS, Ryoo R (2009) Amine-impregnated silica monolith with a hierarchical pore structure: enhancement of CO2 capture capacity. Chem Commun 209:3627–3629. https://doi.org/10.1039/B905589D10.1039/B905589D ↗
3. Chen C, Son WJ, You KS, Ahn JW, Ahn WS (2010) Carbon dioxide capture using amine-impregnated HMS having textural mesoporosity. Chem Eng J 161:46–52. https://doi.org/10.1016/j.cej.2010.04.01910.1016/j.cej.2010.04.019 ↗
4. Dao DS, Yamada H, Yogo K (2015) Response surface optimization of impregnation of blended amines into mesoporous silica for high-performance CO2 capture. Energy Fuel 29:985–992. https://doi.org/10.1021/ef502656t10.1021/ef502656t ↗
5. Dutcher B, Fan M, Russell AG (2015) Amine-based CO2 capture technology development from the beginning of 2013—a review. ACS Appl Mater Inter 7:2137–2148. https://doi.org/10.1021/am507465f10.1021/am507465f ↗
6. Fu Y, Sun D, Chen Y, Huang R, Ding Z, Fu X, Li Z (2012) An amine-functionalized titanium metal-organic framework photocatalyst with visible-light-induced activity for CO2 reduction. Angew Chem Int Ed Engl 51:3364–3367. https://doi.org/10.1002/anie.20110835710.1002/anie.201108357 ↗
7. Goeppert A, Meth S, Prakash GKS, Olah GA (2010) Nanostructured silica as a support for regenerable high-capacity organoamine-based CO2 sorbents. Energy Environ Sci 3:1949–1960. https://doi.org/10.1039/C0EE00136H10.1039/C0EE00136H ↗
8. Goeppert A, Czaun M, Jones JP, Surya PGK, Olah GA (2014) Recycling of carbon dioxide to methanol and derived products – closing the loop. Chem Soc Rev 43:7995–8048. https://doi.org/10.1039/C4CS00122B10.1039/C4CS00122B ↗
9. Habisreutinger SN, Schmidt ML, Stolarczyk JK (2013) Photocatalytic reduction of CO2 on TiO2 and other semiconductors. Angew Chem Int Ed 52:7372–7408. https://doi.org/10.1002/anie.20120719910.1002/anie.201207199 ↗
10. Himeno S, Komatsu T, Fujita S (2005) High-pressure adsorption equilibria of methane and carbon dioxide on several activated carbons. J Chem Eng Data 50:369–376. https://doi.org/10.1021/je049786x10.1021/je049786x ↗
11. Jia W, Liu T, Li Q, Yang J (2019) Highly efficient photocatalytic reduction of CO2 on surface-modified Ti-MCM-41 zeolite. Catal Today 335:221–227. https://doi.org/10.1016/j.cattod.2018.11.04610.1016/j.cattod.2018.11.046 ↗
12. Khatri RA, Chuang SSC, Soong Y, Gray M (2005) Carbon dioxide capture by diamine-grafted SBA-15: a combined fourier transform infrared and mass spectrometry study. Ind Eng Chem Res 44:3702–3708. https://doi.org/10.1021/ie048997s10.1021/ie048997s ↗
13. Khatri RA, Chuang SSC, Soong Y, Gray M (2006) Thermal and chemical stability of regenerable solid amine sorbent for CO2 capture. Energy Fuel 20:1514–1520. https://doi.org/10.1021/ef050402y10.1021/ef050402y ↗
14. Liu Y, Shi J, Chen J, Ye Q, Pan H, Shao Z, Shi Y (2010) Dynamic performance of CO2 adsorption with tetraethylenepentamine-loaded KIT-6. Micropor Mesopor Mat 134:16–21. https://doi.org/10.1016/j.micromeso.2010.05.00210.1016/j.micromeso.2010.05.002 ↗
15. Ma X, Wang X, Song C (2009) “Molecular basket” sorbents for separation of CO2 and H2S from various gas streams. J Am Chem Soc 131:5777–5783. https://doi.org/10.1021/ja807410510.1021/ja8074105 ↗
16. Mikkelsen M, Jørgensen M, Krebs FC (2010) The teraton challenge. A review of fixation and transformation of carbon dioxide. Energy Environ Sci 3:43–81. https://doi.org/10.1039/B912904A10.1039/B912904A ↗
17. Qi G, Wang Y, Estevez L, Duan X, Anako N, Park AHA, Li W, Jones CW (2011) High efficiency nanocomposite sorbents for CO2 capture based on amine-functionalized mesoporous capsules. Energy Environ Sci 4:444–452. https://doi.org/10.1039/C0EE00213E10.1039/C0EE00213E ↗
18. Sanz R, Calleja G, Arencibia A, Sanz PES (2010) CO2 adsorption on branched polyethyleneimine-impregnated mesoporous silica SBA-15. Appl Surf Sci 256:5323–5328. https://doi.org/10.1016/j.apsusc.2009.12.07010.1016/j.apsusc.2009.12.070 ↗
19. Sayari A, Belmabkhout Y (2010) Stabilization of amine-containing CO2 adsorbents: dramatic effect of water vapor. J Am Chem Soc 132:6312–6314. https://doi.org/10.1021/ja101377310.1021/ja1013773 ↗
20. Son WJ, Choi JS, Ahn WS (2008) Adsorptive removal of carbon dioxide using polyethyleneimine-loaded mesoporous silica materials. Micropor Mesopor Mater 113:31–40. https://doi.org/10.1016/j.micromeso.2007.10.04910.1016/j.micromeso.2007.10.049 ↗
21. Sophie B, Mario L (1998) Synthesis and characterization of mesostructured materials. Catal Rev 40:329–407. https://doi.org/10.1080/0161494980800711110.1080/01614949808007111 ↗
22. Tu W, Zhou Y, Zou Z (2014) Photocatalytic conversion of CO2 into renewable hydrocarbon fuels: state-of-the-art accomplishment, challenges, and prospects. Adv Mater 26:4607–4626. https://doi.org/10.1002/adma.20140008710.1002/adma.201400087 ↗
23. Wang XP, Yu JJ, Cheng J, Hao ZP, Xu ZP (2008) High-temperature adsorption of carbon dioxide on mixed oxides derived from hydrotalcite-like compounds. Environ Sci Technol 42:614–618. https://doi.org/10.1021/es072085a10.1021/es072085a ↗
24. Wang Q, Luo J, Zhong Z, Borgna A (2011) CO2 capture by solid adsorbents and their applications: current status and new trends. Energy Environ Sci 4:42–55. https://doi.org/10.1039/C0EE00064G10.1039/C0EE00064G ↗
25. Xie S, Zhang Q, Liu G, Wang Y (2016) Photocatalytic and photoelectrocatalytic reduction of CO2 using heterogeneous catalysts with controlled nanostructures. Chem Commun 52:35–59. https://doi.org/10.1039/C5CC07613G10.1039/C5CC07613G ↗
26. Xu X, Song C, Andresen JM, Miller BG, Scaroni AW (2002) Novel polyethylenimine-modified mesoporous molecular sieve of MCM-41 type as high-capacity adsorbent for CO2 capture. Energy Fuel 16:1463–1469. https://doi.org/10.1021/ef020058u10.1021/ef020058u ↗
27. Yue MB, Chun Y, Cao Y, Dong X, Zhu JH (2006) CO2 capture by as-prepared SBA-15 with an occluded organic template. Adv Funct Mater 16:1717–1722. https://doi.org/10.1002/adfm.20060042710.1002/adfm.200600427 ↗
28. Yue MB, Sun LB, Cao Y, Wang Y, Wang ZJ, Zhu JH (2008) Efficient CO2 capturer derived from as-synthesized MCM-41 modified with amine. Chem Eur J 14:3442–3451. https://doi.org/10.1002/chem.20070146710.1002/chem.200701467 ↗