Synthesis of hybrid nanostructures composed of copper ions and poly(p-phenylenediamine) in aqueous solutions
Source abstract
Abstract
A new kind of hybrid nanoparticles composed of copper ions and poly(p-phenylenediamine) has been synthesized in aqueous solution at room temperature. The nanoparticles have been characterized and studied by TEM, AFM, XPS, and UV spectroscopy. The synthesized nanoparticles are prone to connect with each other and form large nanoclusters. The diameters of the nanoparticles are 46 ± 26 nm. It is believed that a porous network structure exists inside the nanoparticles. The UV absorption spectra of the nanoparticles are sensed with pH and can be reversibly changed according to the pH level. This phenomenon of the nanoparticles has some potential applications. Nanosheets and branched rods composed of copper ions and poly(p-phenylenediamine) have also been obtained by using different ratios of copper ions and p-phenylenediamine as the initial reactant.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Conducting polymers and applications · Dendrimers and Hyperbranched Polymers
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (23)
Show source-provided references
1. Barr TL (1990) Auger and X-ray photoelectron spectroscopy. In: Briggs D, Seah MP (eds) Practical surface analysis, vol 1, 2nd edn. Wiley, New York, p 363
2. Bharathi S, Fishelson N, Lev O (1999) Direct synthesis and characterization of gold and other noble metal nanodispersions in sol-gel-derived organically modified silicates. Langmuir 15:1929–193710.1021/la980490x ↗
3. Blake AJ, Champness NR, Chung SSM, Li W, Schroder M (1997) Control of interpenetrating copper(1) adamantoid networks: synthesis and structure of {[Cu(bpe)2]BF4}n. Chem Commun 1005–100610.1039/a700866j ↗
4. Bourne SA, Mangombo Z (2004) Phenylamines as building blocks to layered inorganic-organic structures. Crystengcomm 6:437–44210.1039/B406671E ↗
5. Cataldo F (1996) On the polymerization of p-phenylenediamine. Eur Polym J 32:43–5010.1016/0014-3057(95)00118-2 ↗
6. Eddaoudi M, Moler DB, Li H, Chen B, Reineke MR, O’Keeffe M, Yaghi O, (2001) Modular chemistry: secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks. Accounts Chem Res 34:319–33010.1021/ar000034b ↗
7. Evmiridis NP, Karayannis Ml (1987) Determination of formaldehyde using a kinetic-spectrophotometeric. Method Anal 112:831–835
8. Fukuoka A, Sakamoto Y, Guan S, Inagaki S, Sugimoto N, Yukushima F, Hirahara K, Iijima S, Ichikawa MJ (2001) Novel templating synthesis of necklace-shaped mono- and bimetallic nanowires in hybrid organic-inorganic mesoporous material. J Am Chem Soc 123:3373–337410.1021/ja004067y ↗
9. Hovchin OB (1958) A rapid colerimetric method for the quantitative determination of copper oxidase activity. Clin Chem 4:519–52310.1093/clinchem/4.6.519 ↗
10. Huang WS, MacDiarmid AG (1993) Optical properties of polyaniline. Polymer 34:1833–184510.1016/0032-3861(93)90424-9 ↗
11. James SL (2003) Metal-organic frameworks. Chem Soc Rev 32:276–28810.1039/b200393g ↗
12. Joly S, Garnaud G, Ollitralt R, Bokobza L (2002) Organically modified layered silicates as reinforcing fillers for natural rubber. Chem Mater 14:4202–420810.1021/cm020093e ↗
13. Lu FL, Wudl F, Nowak M, Heeger AJ (1986) Phenyl-capped octaaniline (COA): an excellent model for polyaniline. J Am Chem Soc 108:8311–831310.1021/ja00286a057 ↗
14. Mederos A, Dominguez S, Hernandez-Molina R, Sanchiz J, Brito F (1999) Coordinating ability of phenylenediamines. Coord Chem Rev 193–195:913–93910.1016/S0010-8545(99)00084-3 ↗
15. Pansanel J, Jouaiti A, Ferlay S, Hosseini M (2006) Molecular tectonics:generation of 2-D molecular networks by combination of coordination and hydrogen bonds. New J Chem 30:71–7610.1039/B512569N ↗
16. Rice EW (1962) Standardization of ceruloplasmin activity in terms of international enzyme units oxidative formation of “Bandrowski’s Base” from p-phenylenediamine by ceruloplasmin. Anal Biochem 3:452–45610.1016/0003-2697(62)90076-3 ↗
17. Schubert U, Husing N, Lorenz A (1995) Hybrid inorganic-organic materials by sol-gel processing of organofunctional metal alkoxides. Chem Mater 7:2010–202710.1021/cm00059a007 ↗
18. Seo JS, Whang D, Lee H, Jun SI, Oh J, Jeon YJ, Kim K (2000) A homochiralmetal-organic porous material for enantioselective separation and catalysis. Nature 404:982–98610.1038/35010088 ↗
19. Sun X, Dong S, Wang E (2005) Coordination-induced formation of submicrometer-scale, monodisperse, spherical colloids of organic-inorganic hybrid materials at room. J Am Chem Soc 127:13102–1310310.1021/ja0534809 ↗
20. Sunderman FW Jr, Nomoto S (1970) Measurement of human serum ceruloplasmin by its p-phenylenediamine oxidase activity. Clin Chem 16:903–91010.1093/clinchem/16.11.903 ↗
21. Thompsen JC, Mottola HA (1984) Kinetic studies of the promoting effect of glutaraldehyde on the oxidation of p-phenylenediamine by hydrogen peroxide. Anal Chem 56:2834–283610.1021/ac00278a046 ↗
22. Wen J, Wilkes GL (1996) Organic/inorganic hybrid network materials by the sol-gel approach. Chem Mater 8:1667–168110.1021/cm9601143 ↗
23. Werkman PJ, Wieringa RH, Vorenkamp EJ, Schouten AJ (1998) Langmuir-Blodgett films of metal complexes of 4-(10,12-pentacosadiynamidomethyl)pyridine: a structural investigation. Langmuir 14:2119–212810.1021/la9706429 ↗