journal article·2006-02

Optical Properties of Zinc Oxide Nano-particles Embedded in Dielectric Medium for UV region: Numerical Simulation

S. M. Al-Hilli, M. Willander

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Abstract

Zinc oxide nano-particles have been used by cosmetic industry for many years because they are extensively used as agents to attenuate (absorb and/or scatter) the ultraviolet radiation. In the most UV-attenuating agent is formulated in which the metal oxide nano-particles are incorporated into liquid media or polymer media are manufactured, such as sunscreens and skin care cosmetics. In this paper we study the wavelength dependence on the particle size (reff = 10–100 nm) by solving the scattering problem of hexagonal ZnO particle for different shapes (plate, equal ratio, column) using the discrete dipole approximation method to find the absorption, scattering, and extinction efficiencies for the UV region (30–400 nm). A new modified hexagonal shape is introduced to determine the scattering problem and it is assumed in this study that the wavelength is comparable to the particle size. From these results, we conclude that the optimum particle radius to block the UV radiation is between reff = 40–80 nm.
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Research context

OpenAlex topics: ZnO doping and properties · Ferroelectric and Piezoelectric Materials · Nonlinear Optical Materials Research

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References (32)

Show source-provided references
1. Borns M. and Wolf E. (1980). Principle of Optics.. Pergamon Press, Oxford
2. Conway J.H. and Sloane N.J.A. (1999). Sphere Packings, Lattices and Group. Springer-Verlag, New York10.1007/978-1-4757-6568-7 ↗
3. Dakhel A.A. (2001). Optical constants of evaporated gadolinium oxide. J. Opt. A: Pure Appl. Opt. 3: 452–45410.1088/1464-4258/3/6/304 ↗
4. Dakhel A.A. (2003). Structure, refractive index dispersion and optical absorption properties of evaporated Zn–Eu oxide films. Mater. Chem. Phys. 81: 56–6210.1016/S0254-0584(03)00107-X ↗
5. Hopkins T. (1995). The Parallel Iterative Methods (PIM) package for the solution of systems of linear equations on parallel computers. Appl. Num. Maths. 19: 33–5010.1016/0168-9274(95)00017-O ↗
6. Draine B.T. (1998). The discrete-dipole approximation and its application to interstellar graphite grains. Astrophys. J. 333: 848–87210.1086/166795 ↗
7. Dranie B.T. (2000). The discrete-dipole approximation for light scattering by irregular targets. In: Mishchenko, M.I., Hovenier, J.W. and Travis, L.D. (eds) Light scattering by Nonspherical Particles: Theroy, Measurements, and Geophysical Applications, pp 131–145. Academic Press, N.Y.10.1016/B978-012498660-2/50032-X ↗
8. Draine B.T., 2004a. Princeton University Observatory, Princeton NJ, 08544–1001 and Flatau P.J., University of California, San Diego, Scripps Institution of Oceanography, La Jolla, California 92093–0221, USA. Program DDSCAT6.1
9. Draine B.T. & P.J. Flatau, 2004b. User Guide for the Discrete Dipole Approximation Code DDSCAT.6.1. http://arxiv.org/abs/astro-ph/xxx
10. Draine B.T. and Flatau P.J. (1994). The discrete dipole approximation for scattering calculations. J. Opt. Soc. Am. A 11: 1491–149910.1364/JOSAA.11.001491 ↗
11. Draine B.T. and Goodman J. (1993). Beyond Clausius-Mossotti: Wave propagation on a polarizable point lattice and the discrete dipole approximation. Astrophys. J. 405: 685–69710.1086/172396 ↗
12. Dulub O., Boatner L.A. and Diebold U. (2002). STM study of the geometric and electronic structure of ZnO(0001)-Zn, (0001′)-O, (101′0), and (112′0) surfaces. Surf. Sci. 519: 201–21710.1016/S0039-6028(02)02211-2 ↗
13. Fairhurst D. & M.A. Mitchnick, 1997. In: Lowe N.J., Shaath N.A. and Pathak M.A. eds. Sunscreens; Development, Evaluation, and Regulatory Aspects. 2nd edn. Marcel Dekker, New York, p. 313
14. Flatau P.J. (1997). Improvements in the discrete-dipole approximation method of computing scattering and absorption. Opt. Lett. 22: 1205–120710.1364/OL.22.001205 ↗
15. Forouhi A.R. & I. Bloomer, 1991. In: E.D. Palik, ed. Handbook of Optical Constants of Solids II, Calculation of optical constants n and k in the interband region. Academic Press, New York, Chapter 7, pp. 151–17510.1016/B978-0-08-055630-7.50010-9 ↗
16. Heavens O.S. (1991). Optical Properties of Thin Film. Dover, New York
17. Jackson J.D. (1975). Classical Electrodynamics. Wiley, New York, 152
18. Kim S.Y. (1996). Simultaneous determination of refractive index, extinction coefficient and void distribution of titanium dioxide thin film by optical methods. Appl. Opt. 35: 6703–670710.1364/AO.35.006703 ↗
19. Kozasa T., Blum J. and Mukai T. (1992). Optical properties of dust aggregates: I. Wavelength dependence. Astron. Astrophys. 263: 423–432
20. Markel V.A., Shalaev V.A., Stechel E.B., Kim W. and Armstrong R. (1996). Small-particle composites I. Linear optical properties. Phys. Rev. B 53: 2425–243610.1103/PhysRevB.53.2425 ↗
21. Meyer B. and Marx D. (2003). Density-functional study of the structure and stability of ZnO surfaces. Phys. Rev. B67: 03540310.1103/PhysRevB.67.035403 ↗
22. Peterson A.F., S.L. Ray, C.H. Chan, and R. Mittra, 1991. In: Sarkar T.K., ed. Application of Conjugate Gradient Method of Electromagnetics and Signal Analysis, Numerical implementation of the conjugate gradient method and the CG-FFT for electromagnetic scattering. Elsevier, New York, Ch. 510.2528/PIER89103007 ↗
23. Petravic M. and Kuo-Petravic G. (1979). An ILUCG algorithm which minimizes in the euclidean norm. J. Computational Phys. 32: 263–26910.1016/0021-9991(79)90133-5 ↗
24. Press W.H., Flannery B.P., Teukolsky S.A. and Vetterling W.T. (1986). Numerical Recipes. Cambridge University Press, Cambridge
25. Purcell E.M. and Pennypacker C.R. (1973). Scattering and absorption of light by nonspherical dielectric grains. Ap. J. 186: 705–71410.1086/152538 ↗
26. Segelstein D. (1981). The Complex Refractive Index of Water. University of Missouri, Kansas city, USA
27. Shore R.E. (1990). Overview of radiation-induced skin cancer in humans. Int J. Radi. Biol. 57: 809–82710.1080/09553009014550951 ↗
28. Swanepoel R. (1983). J. Phys. D: Appl. Phys. 10: 1214
29. Hulst H.C. (1957). Light scattering by small particles. Wiley, New York
30. (1992). Bi-CGSTAB: A fast and smoothly converging variant of Bi-CG for the solution of nonsymmetric linear systems. SIAM J. Sci. Statist. Comput. 13: 631–64410.1137/0913035 ↗
31. Wood D.M. and Ashcroft N.W. (1982). Quantum size effect in the optical properties of small metallic particles. Phys. Rev. B 25: 6255–627410.1103/PhysRevB.25.6255 ↗
32. Xing Z. and Hanner M.S. (1997). Light scattering by aggregate particles. Astron. Astrophys. 324: 805–820