Size effect of gold nanoparticles on the electrocatalytic oxidation of carbon monoxide in alkaline solution
Source abstract
Abstract
This paper describes preliminary findings of Au nanoparticle on glassy carbon (GC) electrodes for electro-oxidation of carbon monoxide in basic conditions. Electrochemical cyclic voltammetric results showed that CO oxidation simultaneously occurred in the anodic and cathodic sweeps during one cycle, and CO electro-oxidation activity was remarkably different in the anode for the different sized Au nanoparticles. The ultrafine catalyst metal particles (2 and 6 nm Au) were more active compared to the larger ones (12, 24 and 41 nm Au). The dependence of the activity on the particle size can be explained in terms of their effect on the number of active sites and the different surface gold oxide species.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Electrocatalysts for Energy Conversion · Catalytic Processes in Materials Science · Electrochemical Analysis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (23)
Show source-provided references
1. Brown K.R., Fox A.P., Natan M.J. 1996 Morphology-dependent electrochemistry of cytochrome c at Au colloid-modified SnO2 electrodes. J. Am. Chem. Soc. 118(5): 1154–115710.1021/ja952951w ↗
2. Burke L.D., Nugent P.F. 1997 The electrochemistry of gold: I The redox behaviour of the metal in aqueous media. Gold Bull. 30(2): 43–5310.1007/BF03214756 ↗
3. Burke L.D., Nugent P.F. 1998 The electrochemistry of gold: II The electrocatalytic behaviour of the metal in aqueous media. Gold Bull. 31(2): 39–5010.1007/BF03214760 ↗
4. Cambell C.T., Parker S.C., Starr D.E. 2002 The effect of size-dependent nanoparticle energetics on catalyst sintering. Science 298: 811–81410.1126/science.1075094 ↗
5. Cherstiouk O.V., Simonov P.A., Savinova E.R. 2003 Model approach to evaluate particle size effects in electrocatalysis: preparation and properties of Pt nanoparticles supported on GC and HOPG. Electrochim. Acta 48(25–26): 3851–386010.1016/S0013-4686(03)00519-X ↗
6. Frelink T., Visscher W., van Veen J.A.R. 1995 Particle size effect of carbon-supported platinum catalysts for the electrooxidation of methanol. J. Electroanal. Chem. 382(1–2): 65–7210.1016/0022-0728(94)03648-M ↗
7. Frens G. 1973 Controlled nucleation for the regulation of the particle size in monodisperse gold suspensions. Nat. Phys. Sci. 241: 20–2210.1038/physci241020a0 ↗
8. Haruta M. 1997 Size- and support-dependency in the catalysis of gold. Catal. Today 36(1): 153–16610.1016/S0920-5861(96)00208-8 ↗
9. Haruta M., Yamada N., Kobayashi T., Iijima S. 1989 Gold catalysts prepared by coprecipitation for low-temperature oxidation of hydrogen and of carbon monoxide. J. Catal. 115(2): 301–30910.1016/0021-9517(89)90034-1 ↗
10. Jaramillo T.F., Baeck S.H., Roldan Cuenya B., Mcfarland E.W. 2003 Catalytic activity of supported Au nanoparticles deposited from block copolymer micelles. J. Am. Chem. Soc. 125(24): 7148–714910.1021/ja029800v ↗
11. Jarvi T.D., Sriramulu S., Stuve E.M. 1997 Potential dependence of the yield of carbon dioxide from electrocatalytic oxidation of methanol on platinum (100). J. Phys. Chem. B. 101(19): 3649–365210.1021/jp9629248 ↗
12. Jin Y., Shen Y., Dong S. 2004 Electrochemical design of ultrathin platinum-coated gold nanoparticle monolayer films as a novel nanostructured electrocatalyst for oxygen reduction. J. Phys. Chem. B. 108(24): 8142–814710.1021/jp0375517 ↗
13. Lou, Y., M.M. Maye, L. Han, J. Luo & C.J. Zhong, 2001. Gold–platinum alloy nanoparticle assembly as catalyst for methanol electrooxidation. Chem. Commun. 5, 473–47410.1039/b008669j ↗
14. Maillard F., Eikerling M., Cherstiouk O.V., Schreier S., Savinova E., Stimming U. 2004 Size effects on reactivity of Pt nanoparticles in CO monolayer oxidation: The role of surface mobility. Faraday Discuss. 125: 357–37710.1039/b303911k ↗
15. Maye M.M., Lou Y., Zhong C.J. 2000 Core-shell gold nanoparticle assembly as novel electrocatalyst of CO oxidation. Langmuir 16(19): 7520–752310.1021/la000503i ↗
16. Min M.-K., Cho J., Cho K., Kim H. 2000 Particle size and alloying effects of Pt-based alloy catalysts for fuel cell applications. Electrochim. Acta 45(25–26): 4211–421710.1016/S0013-4686(00)00553-3 ↗
17. Möller H., Pistorius P.C. 2004 The electrochemistry of gold–platinum alloys. J. Electroanal. Chem. 570(2): 243–25510.1016/j.jelechem.2004.04.003 ↗
18. Roldan Cuenya B., Baeck S.H., Jaramillo T.F., Mcfarland E.W. 2003 Size- and support-dependent electronic and catalytic properties of Au0/Au3+ nanoparticles synthesized from block copolymer micelles. J. Am. Chem. Soc. 125(42): 12928–1293410.1021/ja036468u ↗
19. Sau T.K., Pal A., Pal T. 2001 Size regime dependent catalysis by gold nanoparticles for the reduction of eosin. J. Phys. Chem. B. 105(38): 9266–927210.1021/jp011420t ↗
20. Takasu, Y., H. Itaya, T. Iwazaki, R. Miyoshi, T. Ohnuma, W.␣Sugimoto & Y. Murakami, 2001. Size effects of ultrafine Pt–Ru particles on the electrocatalytic oxidation of methanol. Chem. Commun. 4, 341–34210.1039/b008821h ↗
21. Tateishi N., Nishimura K., Yahikozawa K., Nakagawa M., Yamada M., Takasu Y. 1993 Electrocatalytic properties of ultrafine gold particles towards oxidation of acetaldehyde and ethanol. J. Electroanal. Chem. 352(1–2): 243–25210.1016/0022-0728(93)80267-L ↗
22. Valden M., Lai X., Goodman D.W. 1998 Onset of catalytic activity of gold clusters on titania with the appearance of nonmetallic properties. Science 281: 1647–165010.1126/science.281.5383.1647 ↗
23. Wasmus S., Kuever A. 1999 Methanol oxidation and direct methanol fuel cells: A selective review. J. Electroanal. Chem. 461(1–2): 14–3110.1016/S0022-0728(98)00197-1 ↗